terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 A sensometabolomic approach to understand wine mouthfeel percepts

A sensometabolomic approach to understand wine mouthfeel percepts

Abstract

Targeted analytical methods can overlook compounds that are a priori unknown to play a role in the mouthfeel sensations. This limitation can be overcome with the information provided by untargeted metabolomic analysis using UPLCQTOF-MS. To this end, an untargeted metabolomic approach applied to 42 red wines has allowed development of a model with predictive capacity by cross-validation for the “dry”, “oily” and “unctuous” sensations perceived by a sensory panel. The optimal PLS model for “dry” retained compounds with positive regression coefficients (≥ 0.17) including a trimer procyanidin, a peptide, and four anthocyanins. The compounds with negative contribution were flavonols, hydroxycinnamic acids, and malvidin-ethyl-flavan-3-ol, which agreed with the results of the PLS model obtained from targeted analysis. The relevance of phenolics to the “dry” sensation was sensible, but the predictive models obtained for “unctuous” and “oily” also showed that the chemical composition analyzed was involved in both mouthfeel sensations. The UPLCQTOF-MS has allowed to identify a tripeptide with important implication in “dry”, develop “oily” and “unctuous” models and confirm again the involvement of anthocyanins in mouthfeel perception of red wines. This sensometabolomic approach has found strong correlations between some perceived sensations and the chemical compounds analyzed. The role of the key compounds identified will need to be confirmed in future studies.

Acknowledgements: MICIN (AGL-2017-87373-C3-3-R & PID2021-126031OB-C22 FEDER, UE). SFT: University of La Rioja (predoctoral fellowship, UR-CAR-2018). MPSN: MICIN (RYC2019-027995-I/AEI/10.13039/501100011033 & CAS21/00221). PA & FM: (AdP 2019 by the Autonomous Province of Trento, Italy).

DOI:

Publication date: October 13, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Sara Ferrero-del-Teso1, Panagiotis Arapitsas2,3, David W. Jeffery4, Chelo Ferreira5, Fulvio Mattivi2, Purificación Fernández-Zurbano1*, María-Pilar Sáenz-Navajas1

1Instituto de Ciencias de la Vid y del Vino (UR-CSIC-GR) Department of Enology, Logroño, La Rioja, Spain

2Unit of Metabolomics, Research and Innovation Centre, Fondazione Edmund Mach, via E. Mach 1, 38010 San Michele all’Adige, Italy.

3Department of Wine, Vine and Beverage Sciences, School of Food Science, University of West Attica, Ag. Spyridonos 28, Egaleo, 12243 Athens, Greece.

4School of Agriculture, Food and Wine, and Waite Research Institute, The University of Adelaide, PMB 1, Glen Osmond, South Australia 5064, Australia.

5Laboratorio de Análisis del Aroma y Enología (LAAE), Instituto Universitario de Matemáticas y Aplicaciones (IUMA-UNIZAR), Universidad de Zaragoza, c/ Pedro Cerbuna 12, 50009 Zaragoza, Spain.

Contact the author*

Keywords

untargeted analysis, metabolomics, PLS regression, sensory analysis, UPLCQTOF

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Effect of pH and ethanol on Lactiplantibacillus plantarum in red must fermentation: potential use of wine lees

Wine is the result of the alcoholic fermentation (AF) of grape must. Besides AF, wine can also undergo the malolactic fermentation (MLF) driven out by lactic acid bacteria (LAB). Among LAB, Oenococcus oeni and Lactiplantibacillus plantarum are the dominant species in wine. Even if O. oeni is the most common LAB undergoing MLF in wine, due to its high tolerance to wine conditions, L. plantarum can be used to undergo MLF in must. The moderate tolerance of L. plantarum to low pH and ethanol, may compromise the fermentative process in harsh wines.

White grape must processed by UHPH as an alternative to SO2 addition: Effect on the phenolic composition in three varieties

The quantity and distribution of polyphenols in musts play a fundamental role in the white winemaking. This is because these substances are exposed to oxidation reactions, which are catalysed by the polyphenol oxidase (PPO), leading to a decrease in the quality of the wines produced. PPO is inactivated by SO2, but currently, due to the restrictions of the legislation, other methodologies are being investigated. Ultra-High Pressure Homogenization (UHPH) is a non-thermal physic technology that exerts an ultrahigh pressure pumping (>200 MPa) of a fluid through a valve in a continuous system.

Vertical cordon training system enhances yield and delays ripening in cv. Maturana Blanca

The growing interest in minority grape varieties is due to their potential for adaptation to global warming and their oenological capabilities. However, the cultivation of these varieties has often been limited due to their low economic efficiency. One such example is Maturana Blanca, a recently recovered and authorized minority grape variety in the DOCa Rioja region, known for its remarkable oenological potential but low productivity. This study aimed to increase the yield of Maturana Blanca by implementing the vertical cordon training system, which allowed for a higher number of buds per plant and an increased cluster count per vine.

Impact of polyclonal selection for abiotic stress tolerance on the yield and must quality traits of grapevine varieties

The effects of climate change in viticulture are currently a major concern, with heat waves and drought affecting yield, wine quality, and in extreme cases, even plant survival. Ancient grapevine varieties have high intravarietal genetic variability that so far has been explored successfully to improve yield and must quality. Currently, there is little information available on intravarietal variability regarding responses to stress. In the current work, the intravarietal genetic variability of several Portuguese varieties was studied for yield, must quality, and tolerance to abiotic stress, through indirect, rapid, and nondestructive measurements carried out in the field.

Impact of toasting and botanical origin on oak wood (Q. sp.) volatilome using untargeted GCxGC-ToFMS analysis

Many works have been carried out to identify the key aroma volatile compounds of oak wood (e.g., whisky-lactone, furfural, maltol, eugenol, guaiacol, vanillin) using conventional gas chromatography coupled with olfactometry and mass spectrometry (GC-O-MS). Inspired by recent untargeted approaches in the field of food “omics”, this work aims to extend our knowledge on the impact of cooperage process on the volatile composition of oak wood using two-dimensional comprehensive gas chromatography coupled with time of flight mass spectrometry (GCxGC-ToFMS).