terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 A sensometabolomic approach to understand wine mouthfeel percepts

A sensometabolomic approach to understand wine mouthfeel percepts

Abstract

Targeted analytical methods can overlook compounds that are a priori unknown to play a role in the mouthfeel sensations. This limitation can be overcome with the information provided by untargeted metabolomic analysis using UPLCQTOF-MS. To this end, an untargeted metabolomic approach applied to 42 red wines has allowed development of a model with predictive capacity by cross-validation for the “dry”, “oily” and “unctuous” sensations perceived by a sensory panel. The optimal PLS model for “dry” retained compounds with positive regression coefficients (≥ 0.17) including a trimer procyanidin, a peptide, and four anthocyanins. The compounds with negative contribution were flavonols, hydroxycinnamic acids, and malvidin-ethyl-flavan-3-ol, which agreed with the results of the PLS model obtained from targeted analysis. The relevance of phenolics to the “dry” sensation was sensible, but the predictive models obtained for “unctuous” and “oily” also showed that the chemical composition analyzed was involved in both mouthfeel sensations. The UPLCQTOF-MS has allowed to identify a tripeptide with important implication in “dry”, develop “oily” and “unctuous” models and confirm again the involvement of anthocyanins in mouthfeel perception of red wines. This sensometabolomic approach has found strong correlations between some perceived sensations and the chemical compounds analyzed. The role of the key compounds identified will need to be confirmed in future studies.

Acknowledgements: MICIN (AGL-2017-87373-C3-3-R & PID2021-126031OB-C22 FEDER, UE). SFT: University of La Rioja (predoctoral fellowship, UR-CAR-2018). MPSN: MICIN (RYC2019-027995-I/AEI/10.13039/501100011033 & CAS21/00221). PA & FM: (AdP 2019 by the Autonomous Province of Trento, Italy).

DOI:

Publication date: October 13, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Sara Ferrero-del-Teso1, Panagiotis Arapitsas2,3, David W. Jeffery4, Chelo Ferreira5, Fulvio Mattivi2, Purificación Fernández-Zurbano1*, María-Pilar Sáenz-Navajas1

1Instituto de Ciencias de la Vid y del Vino (UR-CSIC-GR) Department of Enology, Logroño, La Rioja, Spain

2Unit of Metabolomics, Research and Innovation Centre, Fondazione Edmund Mach, via E. Mach 1, 38010 San Michele all’Adige, Italy.

3Department of Wine, Vine and Beverage Sciences, School of Food Science, University of West Attica, Ag. Spyridonos 28, Egaleo, 12243 Athens, Greece.

4School of Agriculture, Food and Wine, and Waite Research Institute, The University of Adelaide, PMB 1, Glen Osmond, South Australia 5064, Australia.

5Laboratorio de Análisis del Aroma y Enología (LAAE), Instituto Universitario de Matemáticas y Aplicaciones (IUMA-UNIZAR), Universidad de Zaragoza, c/ Pedro Cerbuna 12, 50009 Zaragoza, Spain.

Contact the author*

Keywords

untargeted analysis, metabolomics, PLS regression, sensory analysis, UPLCQTOF

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Induction of polyphenols in seedlings of Vitis vinifera cv. Monastrell by the application of elicitors

Contamination problems arising from the use of pesticides in viticulture have raised concerns. One of the alternatives to reduce contamination is the use of elicitors, molecules capable of stimulating the natural defences of plants, promoting the production of phenolic compounds (PC) that offer protection against biotic and abiotic stress. Previous studies on Cabernet-Sauvignon seedlings demonstrated that foliar application of elicitors methyl jasmonate (MeJ) and benzothiadiazole (BTH) increased proteins and PC involved in grapevine defence mechanisms. However, no trials had been conducted on Monastrell seedlings, a major winegrape variety in Spain.

Quantification of polysaccharides of variety Pomaces of the D.O.Ca Rioja

Pomace is one of the main residues generated by the wine industry and represents an environmental problem. Currently, there is a growing interest in the revaluation of these products because different bioactive compounds can be obtained from them, such as polyphenols, grape seed oils and polysaccharides. Red grape pomace can be an important source of polysaccharides, but they are currently little studied and even less with viable and environmental extraction processes (green extraction), such as flash extraction. The residual amount of the fraction rich in pectin (residual pulp) and component rich in hemicellulose in the pomace and the strength of association of the pectin with the cellulose-xyloglucan network depend on the degree of extractability of the polysaccharides in red winemaking and on the winemaking conditions.

Association between dietary pattern and wine consumption and Alzheimer’s disease in a cohort from La Rioja (Spain)

Addressing modifiable risk factors is the most promising strategy to prevent/delay Alzheimer Disease (AD)[1]. The aim of the study was to establish the connections between dietetic habits, wine consumption and AD. Thus, 98 volunteers were recruited: 50 diagnosed as AD and 48 healthy/controls. The Food Frequency Questionnaire (FFQ) was used for dietary patterns assessment and, based on these data, the Mind Diet Score was calculated. (Poly)phenol metabolites (especially derived from wine consumption) were analyzed by UPLC-QqQ-MS/MS in 24-h urine samples to confirm dietary (poly)phenol consumption.

Early defoliation positively enhances bioactive composition of berries with no effect on cuticle characteristics

Leaf removal in the fruit-zone has been employed to improve cluster light exposure and ventilation and therefore increase metabolite accumulation and reduce botrytis incidence in berries. When applied before flowering (early defoliation – ED), it can also decrease cluster compactness and regulate yield in high-yielding varieties. This study aimed to evaluate the impact of ED on the physiology and metabolism of Aragonez (syn. Tempranillo) berries along the ripening period. The experiment was set up in 2013 at a commercial vineyard located in the Lisbon winegrowing region.

Distribution and sensory impact of new oak wood-derived compounds in wines

Despite the numerous research studies carried out in recent years, the study of wine aroma remains of great interest due to its complexity. Wine maturation in oak barrels is described as an important step in the production of quality wines. In fact, oak wood develops several aromatic nuances through its toasting which can be released into the wine. A great deal of work has been performed in order to identify the wood-derived volatile compounds that contribute to wine aroma (e.g., whisky-lactone, maltol, eugenol, guaiacol, vanillin).