terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 A sensometabolomic approach to understand wine mouthfeel percepts

A sensometabolomic approach to understand wine mouthfeel percepts

Abstract

Targeted analytical methods can overlook compounds that are a priori unknown to play a role in the mouthfeel sensations. This limitation can be overcome with the information provided by untargeted metabolomic analysis using UPLCQTOF-MS. To this end, an untargeted metabolomic approach applied to 42 red wines has allowed development of a model with predictive capacity by cross-validation for the “dry”, “oily” and “unctuous” sensations perceived by a sensory panel. The optimal PLS model for “dry” retained compounds with positive regression coefficients (≥ 0.17) including a trimer procyanidin, a peptide, and four anthocyanins. The compounds with negative contribution were flavonols, hydroxycinnamic acids, and malvidin-ethyl-flavan-3-ol, which agreed with the results of the PLS model obtained from targeted analysis. The relevance of phenolics to the “dry” sensation was sensible, but the predictive models obtained for “unctuous” and “oily” also showed that the chemical composition analyzed was involved in both mouthfeel sensations. The UPLCQTOF-MS has allowed to identify a tripeptide with important implication in “dry”, develop “oily” and “unctuous” models and confirm again the involvement of anthocyanins in mouthfeel perception of red wines. This sensometabolomic approach has found strong correlations between some perceived sensations and the chemical compounds analyzed. The role of the key compounds identified will need to be confirmed in future studies.

Acknowledgements: MICIN (AGL-2017-87373-C3-3-R & PID2021-126031OB-C22 FEDER, UE). SFT: University of La Rioja (predoctoral fellowship, UR-CAR-2018). MPSN: MICIN (RYC2019-027995-I/AEI/10.13039/501100011033 & CAS21/00221). PA & FM: (AdP 2019 by the Autonomous Province of Trento, Italy).

DOI:

Publication date: October 13, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Sara Ferrero-del-Teso1, Panagiotis Arapitsas2,3, David W. Jeffery4, Chelo Ferreira5, Fulvio Mattivi2, Purificación Fernández-Zurbano1*, María-Pilar Sáenz-Navajas1

1Instituto de Ciencias de la Vid y del Vino (UR-CSIC-GR) Department of Enology, Logroño, La Rioja, Spain

2Unit of Metabolomics, Research and Innovation Centre, Fondazione Edmund Mach, via E. Mach 1, 38010 San Michele all’Adige, Italy.

3Department of Wine, Vine and Beverage Sciences, School of Food Science, University of West Attica, Ag. Spyridonos 28, Egaleo, 12243 Athens, Greece.

4School of Agriculture, Food and Wine, and Waite Research Institute, The University of Adelaide, PMB 1, Glen Osmond, South Australia 5064, Australia.

5Laboratorio de Análisis del Aroma y Enología (LAAE), Instituto Universitario de Matemáticas y Aplicaciones (IUMA-UNIZAR), Universidad de Zaragoza, c/ Pedro Cerbuna 12, 50009 Zaragoza, Spain.

Contact the author*

Keywords

untargeted analysis, metabolomics, PLS regression, sensory analysis, UPLCQTOF

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Nitrogen forms and Iron deficiency: how do Grapevine rootstocks responses change?

Grapevine rootstocks provide protection against environmental biotic and abiotic stresses. Nitrogen (N) and iron (Fe) are growth-limiting factors in many crop plants due to their effects on the chlorophyll and photosynthetic characteristics. Iron nutrition of plants can be significantly affected by different nitrogen forms through altering the uptake ratio of cations and anions, and changing rhizosphere pH. The aim of this study was to investigate the response mechanisms of grapevine rootstocks due to the interaction between different nitrogen forms and iron uptake.

Applicability of spectrofluorometry and voltammetry in combination with machine learning approaches for authentication of DOCa Rioja Tempranillo wines

The main objective of the work was to develop a simple, robust and selective analytical tool that allows predicting the authenticity of Tempranillo wines from DOCa Rioja. The techniques of voltammetry and absorbance-transmission and fluorescence excitation emission matrix (A-TEEM) spectroscopy have been applied in combination with machine learning (ML) algorithms to classify red wines from DOCa Rioja according to region (Alavesa, Alta or Oriental) and category (young, crianza or reserva).

Retrospective analysis of our knowledge regarding the genetics of relevant traits for rootstock breeding 

Rootstocks were the first sustainable and environmentally friendly strategy to cope with a major threat for Vitis vinifera cultivation. In addition to providing Phylloxera resistance, they play an important role in protecting against other soil-borne pests, such as nematodes, and in adapting V. vinifera to limiting abiotic conditions. Today viticulture has to adapt to ongoing climate change whilst simultaneously reducing its environmental impact. In this context, rootstocks are a central element in the development of agro-ecological practices that increase adaptive potential with low external inputs. Despite the apparent diversity of the Vitis genus, only few rootstock varieties are used worldwide and most of them have a very narrow genetic background. This means that there is considerable scope to breed new, improved rootstocks to adapt viticulture for the future.

Metabolomic profiling of heat-stressed grape berries 

The projected rise in mean air temperatures together with the frequency, intensity, and length of heat waves in many wine-growing regions worldwide will deeply impact grape berry development and quality. Several studies have been conducted and a large set of molecular data was produced to better understand the impact of high temperatures on grape berry development and metabolism[1]. According to these data, it is highly likely that the metabolomic dynamics could be strongly modulated by heat stress (HS).

Vineyard yield estimation using image analysis: assessing bunch occlusions and its dependency on fruiting zone canopy features

Performing accurate vineyard yield estimation is of upmost importance as it provides important benefits to the whole vine and wine industry. Recently, image-analysis approaches have been explored to address this issue however this approach has as main challenge the bunch occlusion, mostly by vegetation but also by neighboring bunches. The present work aims at assessing the magnitude of bunch occlusion by neighboring bunches and to evaluate its dependency on a selection of vegetative and reproductive vine parameters assessed at fruiting zone. Forty vine segments (1 m) of two vineyard plots of the white cultivars ‘Alvarinho’ and ‘Arinto’ were assessed for vegetative and reproductive features at fruiting zone and imaged with a 2D camera.