terclim by ICS banner
IVES 9 IVES Conference Series 9 AGING PATTERNS OF VARIETAL VOLATILE PROFILES OF WHITE WINES: A CASE STUDY ON 18 ITALIAN VARIETAL WHITE WINES

AGING PATTERNS OF VARIETAL VOLATILE PROFILES OF WHITE WINES: A CASE STUDY ON 18 ITALIAN VARIETAL WHITE WINES

Abstract

During wine aging many compositional changes take place. In particular, aroma undergoes dramatic modifications through a wide range of reactions that to date are only partly understood. Italy owns one of the largest ampelographic heritages worldwide, with over three-hundred different varieties. Among these, many white grapes are employed for the production of dry still white wines. Some of these wines are consumed young while others are more prone to aging. For many of these wines, the aging patterns related to volatile composition are still unknown.

An extensive survey was conducted on 18 monovarietal Italian still white wines with the aim of elucidating the behaviours of different volatile compounds during aging. In particular, a range of volatile compounds including terpenes, norisoprenoids, benzenoids and volatile sulfur compounds was investigated. A total of 108 different samples were analysed, including Nosiola, Vermentino, Müller-Thurgau, Greco di Tufo, Garganega, Lugana, Erbaluce di Caluso, Pinot Grigio, Cortese, Arneis, Albana, Pallagrello, Falanghina, Fiano, Ribolla Gialla, Vernaccia, Gewürztraminer, Verdicchio. All wines were adjusted to 30 mg/L of free SO2 and submitted to an accelerated aging protocol involving storage for 30 days 10 °C, 40 °C and 60°C in oxygen-free environment. Volatile compounds were analysed by means a combination of analytical methods based on SPME-GC-MS.

During aging some common trends were observed, among which a decrease in linear terpenes and an increase in bicyclic terpenes, non-megastigmane norisoprenoids and volatile sulfur compounds. From a quantitative point of view, the extent of these transformations varied significantly according to wine type. Besides Gewürztraminer, which was generally rich in terpenes, other wine types such as Vermentino Verdicchio and Lugana showed peculiar terpene patterns, for example accumulation of above-threshold levels of the bicyclic terpene 1,4-cineole. Regarding non-megastigmane norisoprenoids, Falanghina and Vermentino were found to accumulate high levels of TDN and vitispirane, which was not observed in other wines. Greco accumulated during aging the highest amount of DMS, showing an average content above the odor threshold. Müller-Thurgau, Nosiola and Vermentino also showed concentrations of DMS above the odor threshold after aging. In addition, the latter varieties also showed high accumulation of methanethiol.

As most of these patterns were not seen in young wines, this work highlights the important contribution of aging to the expression of aroma characters that are specific to the identity of individual varieties or wine types.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Giovanni Luzzini1, Nicole Furlan1, Davide Slagheanufi1, Susana Río Segade2, Paola Piombino3, Giuseppina Paola Parpinello4, Matteo Marangon5, Fulvio Mattivi6,7 Maurizio Piergiovanni6,8, Silvia Carlin7, Maurizio Ugliano1

1. University of Verona, Department of Biotechnology, 37039, San Pietro in Cariano (VR) Italy
2. Department of Agricultural, Forest and Food Sciences, University of Torino, 10095 Grugliasco (TO), Italy
3. Department of Agricultural Sciences, Division of Vine and Wine Sciences, University of Napoli Federico II, 83100 Avellino (AV), Italy
4. Department of Agricultural and Food Sciences, University of Bologna, 47521 Cesena (FC), Italy
5. Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, 35020 Le-gnaro (PD), Italy
6. Center Agriculture Food Environment (C3A), University of Trento, 38098, San Michele all’Adige (TN) Italy
7. Research and Innovation Centre, Fondazione Edmund Mach, 38098, San Michele all’Adige (TN) Italy
8. Department of Chemistry, Life Sciences and Environmental Sustainability (SCVSA), 43124, Parma (PR), Italy

Contact the author*

Keywords

Volatile compounds, white wine, Aging pattern, Varietal typicality

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

SIP and save the planet: a sensory and consumer exploration of australian wines made from potentially drought-tolerant white wine grapes

In order to attenuate the effects of climate change on the ability to cultivate quality wine grape vines in Australia, it is essential to adapt to the projected less favourable Australian climate scenarios. One response may be to convert a portion of the current grapevine plantings to those varieties that demand less water and can tolerate increased heat. This investigation aimed to (i) generate sensory profiles and (ii) obtain knowledge about Australian wine consumers’ preferences and opinions of Australian wines made from potentially drought tolerant, white wine grape varieties not traditionally cultivated in Australia. A Rate-All-That-Apply (RATA) sensory panel (n = 49) generated sensory profiles of 44 commercial white wines made from 7 different white grape varieties (Arinto, Fiano, Garganega, Greco, Verdejo, Verdelho and Vermentino), plus two benchmark examples each of an Australian Riesling, Pinot Gris and Chardonnay wine.

NEW TOOL FOR SIMULTANEOUS MEASUREMENT OF OXYGEN CONSUMPTION AND COLOUR MODIFICATIONS IN WINES

Measuring the effect of oxygen consumption on the colour of wines as the level of dissolved oxygen decreases over time is very useful to know how much oxygen a wine is able to consume without significantly altering its colour. The changes produced in wine after being exposed to high oxygen concen-trations have been studied by different authors, but in all cases the wine has been analysed once the oxygen consumption process has been completed. This work presents the results obtained with the use of an equipment designed and made to measure simultaneously the level of dissolved oxygen and the spectrum of the wine, during the oxygen consumption process from saturation levels with air to very low levels, which indicate the total consumption of the dosed oxygen.

CHANGES IN CU FRACTIONS AND RIBOFLAVIN IN WHITE WINES DURING SHORT-TERM LIGHT EXPOSURE: IMPACTS OF OXYGEN AND BOTTLE COLOUR

Copper in white wine can be associated with Cu(II) organic acids (Cu fraction I), Cu(I) thiol species (Cu fraction II), and Cu sulfides (Cu fraction III). The first two fractions are associated with the repression of reductive aromas in white wine, but these fractions gradually decrease in concentration during the normal bottle aging of wine. Although exposure of white wine to fluorescent light is known to induce the accumulation of volatile sulfur compounds, causing light-struck aroma, the influence on the loss of protective Cu fractions is uncertain. Riboflavin is known to be a critical initiator of photochemical reac-tions in wine, but the rate of its decay under short-term light exposure in different coloured bottles and for wine of different oxygen concentrations is not well understood.

INVESTIGATION OF MALIC ACID METABOLIC PATHWAYS DURING ALCOHOLIC FERMENTATION USING GC-MS, LC-MS, AND NMR DERIVED 13C-LABELED DATA

Malic acid has a strong impact on wine pH and the contribution of fermenting yeasts to modulate its concentration has been intensively investigated in the past. Recent advances in yeast genetics have shed light on the unexpected property of some strains to produce large amounts of malic acid (“acidic strains”) while most of the wine starters consume it during the alcoholic fermentation. Being a key metabolite of the central carbohydrate metabolism, malic acid participates to TCA and glyoxylate cycles as well as neoglucogenesis. Although present at important concentrations in grape juice, the metabolic fate of malic acid has been poorly investigated.

ACCUMULATION OF GRAPE METABOLITES IS DIFFERENTLY IMPACTED BY WATER DEFICIT AT THE BERRY AND PLANT LEVELS IN NEW FUNGUS DISEASE-TOLERANT GENOTYPES

The use of new fungus disease-tolerant varieties is a promising long-term solution to better manage chemical input in viticulture, but unfortunately little is known regarding these new hybrids fruit development and metabolites accumulation in front of abiotic stresses such as water deficit (WD). Thus, prior to the adoption of such varieties by the wine industry in Mediterranean regions, there is a need to consider their suitability to WD.