terclim by ICS banner
IVES 9 IVES Conference Series 9 AGING PATTERNS OF VARIETAL VOLATILE PROFILES OF WHITE WINES: A CASE STUDY ON 18 ITALIAN VARIETAL WHITE WINES

AGING PATTERNS OF VARIETAL VOLATILE PROFILES OF WHITE WINES: A CASE STUDY ON 18 ITALIAN VARIETAL WHITE WINES

Abstract

During wine aging many compositional changes take place. In particular, aroma undergoes dramatic modifications through a wide range of reactions that to date are only partly understood. Italy owns one of the largest ampelographic heritages worldwide, with over three-hundred different varieties. Among these, many white grapes are employed for the production of dry still white wines. Some of these wines are consumed young while others are more prone to aging. For many of these wines, the aging patterns related to volatile composition are still unknown.

An extensive survey was conducted on 18 monovarietal Italian still white wines with the aim of elucidating the behaviours of different volatile compounds during aging. In particular, a range of volatile compounds including terpenes, norisoprenoids, benzenoids and volatile sulfur compounds was investigated. A total of 108 different samples were analysed, including Nosiola, Vermentino, Müller-Thurgau, Greco di Tufo, Garganega, Lugana, Erbaluce di Caluso, Pinot Grigio, Cortese, Arneis, Albana, Pallagrello, Falanghina, Fiano, Ribolla Gialla, Vernaccia, Gewürztraminer, Verdicchio. All wines were adjusted to 30 mg/L of free SO2 and submitted to an accelerated aging protocol involving storage for 30 days 10 °C, 40 °C and 60°C in oxygen-free environment. Volatile compounds were analysed by means a combination of analytical methods based on SPME-GC-MS.

During aging some common trends were observed, among which a decrease in linear terpenes and an increase in bicyclic terpenes, non-megastigmane norisoprenoids and volatile sulfur compounds. From a quantitative point of view, the extent of these transformations varied significantly according to wine type. Besides Gewürztraminer, which was generally rich in terpenes, other wine types such as Vermentino Verdicchio and Lugana showed peculiar terpene patterns, for example accumulation of above-threshold levels of the bicyclic terpene 1,4-cineole. Regarding non-megastigmane norisoprenoids, Falanghina and Vermentino were found to accumulate high levels of TDN and vitispirane, which was not observed in other wines. Greco accumulated during aging the highest amount of DMS, showing an average content above the odor threshold. Müller-Thurgau, Nosiola and Vermentino also showed concentrations of DMS above the odor threshold after aging. In addition, the latter varieties also showed high accumulation of methanethiol.

As most of these patterns were not seen in young wines, this work highlights the important contribution of aging to the expression of aroma characters that are specific to the identity of individual varieties or wine types.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Giovanni Luzzini1, Nicole Furlan1, Davide Slagheanufi1, Susana Río Segade2, Paola Piombino3, Giuseppina Paola Parpinello4, Matteo Marangon5, Fulvio Mattivi6,7 Maurizio Piergiovanni6,8, Silvia Carlin7, Maurizio Ugliano1

1. University of Verona, Department of Biotechnology, 37039, San Pietro in Cariano (VR) Italy
2. Department of Agricultural, Forest and Food Sciences, University of Torino, 10095 Grugliasco (TO), Italy
3. Department of Agricultural Sciences, Division of Vine and Wine Sciences, University of Napoli Federico II, 83100 Avellino (AV), Italy
4. Department of Agricultural and Food Sciences, University of Bologna, 47521 Cesena (FC), Italy
5. Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, 35020 Le-gnaro (PD), Italy
6. Center Agriculture Food Environment (C3A), University of Trento, 38098, San Michele all’Adige (TN) Italy
7. Research and Innovation Centre, Fondazione Edmund Mach, 38098, San Michele all’Adige (TN) Italy
8. Department of Chemistry, Life Sciences and Environmental Sustainability (SCVSA), 43124, Parma (PR), Italy

Contact the author*

Keywords

Volatile compounds, white wine, Aging pattern, Varietal typicality

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

HYBRID GRAPEVINE CV BACO BLANC, BETWEEN TRADITION AND MODERNISM: FOCUS ON ENDOGENOUS EUGENOL AS RESISTANCE FACTOR TO BOTRYTIS CINEREA

The well-known antifungal and antibiotic molecule, eugenol, is widely spread in various plants including clove, basil and bay. It is also abundant in the hybrid grapevine cultivar (cv) Baco blanc (Vitis vi-nifera x Vitis riparia x Vitis labrusca), created by François Baco (19th century) in the Armagnac region. This study confirmed this cv as highly resistant to Botrytis cinerea by comparing fruit rot incidence and severity with two Vitis vinifera cultivars: Folle Blanche and Ugni Blanc. We have demonstrated the efficiency of eugenol in vitro, by further investigating the effect of small concentrations of eugenol, 3 to 4 ppm (corresponding to IC10), on B. cinerea. By comparing the two major modes of action (direct or volatile antibiosis), the vapour inhibiting effect of eugenol was more powerful. In the skin of Baco blanc berry, the total eugenol concentration reached a maximum at veraison, i.e. 1118 to 1478 μg/kg.

EFFECTS OF BIODYNAMIC VINEYARD MANAGEMENT ON GRAPE RIPENING MECHANISMS

Biodynamic agriculture, founded in 1924 by Rudolph Steiner, is a form of organic agriculture. Through a holistic approach, biodynamic agriculture seeks to preserve the diversity of agriculture and the existing interactions between the mineral world and the different components of the organic world. Biodynamic grape production involves the use of composts, herbal teas and mineral preparations such as 500, 501 and CBMT.
Several scientific studies have provided evidence on the effects of biodynamic farming on the soil, the plant and the wine. Numerous empirical opinions of wine growers support the existence of differences brought by such a management.

EFFECT OF FUMARIC ACID ON SPONTANEOUS FERMENTATION IN GRAPE MUST

Malolactic fermentation (MLF)¹, the decarboxylation of L-malic acid into L-lactic acid, is performed by lactic acid bacteria (LAB). MLF has a deacidifying effect that may compromise freshness or microbiological stability in wines² and can be inhibited by fumaric acid [E297] (FA). In wine, can be added at a maximum allowable dose of 0.6 g/L³. Its inhibition with FA is being studied as an alternative strategy to minimize added doses of SO₂⁴. In addition, wine yeasts are capable of metabolizing and storing small amounts of FA and during alcoholic fermentation (AF).

INFLUENCE OF THE NITROGEN / LIPIDS RATIO OF MUSTS ON THE REVELATION OF AROMATIC COMPOUNDS IN SAUVIGNON BLANC WINE

Production of volatile compounds by yeast is known to be modulated by must nitrogen. Nevertheless, various parameter of must quality have an impact on yeast fermentation. In this study we propose to evaluate the impact of nitrogen / lipids balance on a Sauvignon Blanc grape juice (Val de Loire).
Must was prepared from the same grapes at pilot scale. Three modalities were carried out: direct pressing, direct pressing with a pre-fermentation cold stabulation and pellicular maceration before pressing.

IMPACT OF MUST NITROGEN DEFICIENCY ON WHITE WINE COMPOSITION DEPENDING ON GRAPE VARIETY

Nitrogen (N) nutrition of the vineyard strongly influences the must and the wine compositions. Several chemical markers present in wine (i.e., proline, succinic acid, higher alcohols and phenolic compounds) have been proposed for the cultivar Chasselas, as indicators of N deficiency in the grape must at harvest [1]. Grape genetics potentially influences the impact of N deficiency on grape composition, as well as on the concentration of potential indicators in the wine. The goal of this study was to evaluate if the che- mical markers found in Chasselas wine can be extended for other white wines to indicate N deficiency in the grape must.