terclim by ICS banner
IVES 9 IVES Conference Series 9 EFFECTIVENESS OF APPLIED MATERIALS IN REDUCING THE ABSORPTION OF SMOKE MARKER COMPOUNDS IN A SIMULATED WILDFIRE SCENARIO

EFFECTIVENESS OF APPLIED MATERIALS IN REDUCING THE ABSORPTION OF SMOKE MARKER COMPOUNDS IN A SIMULATED WILDFIRE SCENARIO

Abstract

Smoke taint (ST) is a grape-wine off-flavour that may occur when grapes absorb volatile phenols (VPs) originating from wildfire smoke (1). ST is associated with the negative sensory attributes such as smoky and ashy notes. VPs are glycosylated in the plant and thus present in both free and bound forms (2; 3). Wildfire smoke has resulted in a decline in grape and wine quality and financial losses which has become a prominent issue for the global wine industry. This fact has highlighted the need to develop mitigation strategies to manage the impact of smoke exposure on grapes and the resulting wines (4). Currently there are no recommended mitigation action for grape smoke exposure.
The objective of this experiment was to compare the relative effectiveness of applying different potential protective barrier sprays to grapes in a simulated wildfire scenario. Twelve different material combina-tions were applied close to harvest as potential barrier sprays on three bunches each using four Cabernet Sauvignon vines. The vines were exposed to smoke for two hours three days after the barrier application. Control samples prior to smoke exposure was taken and smoked control (no barrier applied) grapes were sampled at different time points after exposure. For the smoke application a rectangular tent structure was built. The smoke was generated by a wood pellet smoker. Air samples were taken, and atmospheric parameters were monitored during the experiment. Grapes were analysed for free and acid-labile forms of VPs using a GC-MS and for glycosylated forms using UHPLC-qTOF MS.
Results show the presence of smoke and smoke derived compounds, however there was a strong stratifi-cation in the distribution of VPs within the structure. The heterogeneous distribution of smoke is reflected in the different concentrations of uptake of VPs in the grapes. Results from non-treated grapes indicate that glycosylation of the free volatile phenols takes place within hours, with significant increases in almost all glycosylated compounds. However, variation in smoke exposure will affect the glycosylation kinetics of VPs. The study indicated that some sprays exhibited some efficacy in reducing VPs absorption under these conditions. However, other treatments seemed to exacerbate the adsorption of VPs in grapes. In a next step, these barrier sprays will be studied further under field conditions. Acknowledgements: This work has been funded by the USDA-ARS.

 

1. Kennison, K. R., Wilkinson, K. L., Williams, H. G., Smith, J. H., & Gibberd, M. R. (2007). Smoke-derived taint in wine: Effect of postharvest smoke exposure of grapes on the chemical composition and sensory characteristics of wine. Journal of Agricultural and Food Chemistry, 55(26), 10897–10901. https://doi.org/10.1021/jf072509k
2. Caffrey, A., Lerno, L., Rumbaugh, A., Girardello, R., Zweigenbaum, J., Oberholster, A., & Ebeler, S. E. (2019). Changes in Smoke-Taint Volatile-Phenol Glycosides in Wildfire Smoke-Exposed Cabernet Sauvignon Grapes throughout Winemaking. American Journal of Enology and Viticulture, 70(4), 373–381. https://doi.org/10.5344/ajev.2019.19001
3. Hayasaka, Y., Dungey, K. A., Baldock, G. A., Kennison, K. R., & Wilkinson, K. L. (2010). Identification of a beta-D-glucopyranoside precursor to guaiacol in grape juice following grapevine exposure to smoke. Analytica Chimica Acta, 660(1–2), 143–148. https://doi.org/10.1016/j.aca.2009.10.039
4. Mirabelli-Montan, Y. A., Marangon, M., Graça, A., Mayr Marangon, C. M., & Wilkinson, K. L. (2021). Techniques for mitigating the effects of smoke taint while maintaining quality in wine production: A review. Molecules, 26(6), 1–19. https://doi. org/10.3390/molecules26061672

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Ignacio Arias-Pérez¹, Yan Wen1 and Anita Oberholster¹

1. Department of Viticulture and Enology, University of California Davis, 95616, CA, USA

Contact the author*

Keywords

Smoke taint, Barrier spray, Volatile phenols, Glycosylation

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

POTENTIAL DEACIDIFYING ROLE OF A COMMERCIAL CHITOSAN: IMPACT ON PH, TITRATABLE ACIDITY, AND ORGANIC ACIDS IN MODEL SOLUTIONS AND WHITE WINE

Chitin is the main structural component of a large number of organisms (i.e., mollusks, insects, crustaceans, fungi, algae), and marine invertebrates including crabs and shrimps. The main derivative of chitin is chitosan (CH), produced by N-deacetylation of chitin in alkaline solutions. Over the past decade, the OIV/OENO 338A/ 2009 resolution approved the addition of allergen-free fungoid CH to must and wine as an adjuvant for microbiological control, prevention of haziness, metals chelation and ochratoxins removal (European Commission. 2011). Despite several studies on application of CH in winemaking, there are still very limited and controversial data on its interaction with acidic components in wine (Colan-gelo et al., 2018; Castro Marin et al., 2021).

CONSENSUS AND SENSORY DOMINANCE ARE DEPENDENT ON QUALITY CONCEPT DEFINITIONS

The definition of the term “quality” in sensory evaluation of food products does not seem to be consensual. Descriptive or liking methods are generally used to differentiate between wines (Lawless et al., 1997). Nevertheless, quality evaluation of a product such as wine can also relate to emotional aspects. As exposed by Costell (2002), product quality is defined as an integrated impression, like acceptability, pleasure, or emotional experiences during tasting. According to the ‘modality appropriateness’ hypothesis which predicts that wine tasters weigh the most suitable sensory inputs for a specific assess- ment (Freides, 1974; Welch & Warren, 1980), the nature of the quality definitions may modulate sensory influences.

IMPACT OF HARVEST DATE ON THE FINE MOLECULAR COMPOSITION OF MUST AND BORDEAUX RED WINE (VAR. MERLOT, CABERNET SAUVIGNON). FOCUS ON ACIDITY AND SENSORY IMPACT AFTER FIVE YEARS OF AGING

Climate change has brought several impacts that are becoming increasingly intense during the last few years and put at risk the quality of the berries or even the plant’s sustainability. Such extreme climatic events impact the composition of the wine while modulating its quality and the consumer preferences (Tempère et al., 2019). The three most important changes that take place in the must are: 1) decrease acidity, 2) increase of the concentration of sugar, hence increase of alcohol in the wine, and 3) modification
of the sensory balance and the development for example of cooked fruit aromas.

INVESTIGATION OF MALIC ACID METABOLIC PATHWAYS DURING ALCOHOLIC FERMENTATION USING GC-MS, LC-MS, AND NMR DERIVED 13C-LABELED DATA

Malic acid has a strong impact on wine pH and the contribution of fermenting yeasts to modulate its concentration has been intensively investigated in the past. Recent advances in yeast genetics have shed light on the unexpected property of some strains to produce large amounts of malic acid (“acidic strains”) while most of the wine starters consume it during the alcoholic fermentation. Being a key metabolite of the central carbohydrate metabolism, malic acid participates to TCA and glyoxylate cycles as well as neoglucogenesis. Although present at important concentrations in grape juice, the metabolic fate of malic acid has been poorly investigated.

PROBING GRAPEVINE-BOTRYTIS CINEREA INTERACTION THROUGH MASS SPECTROMETRY IMAGING

Plants in their natural environment are in continuous interaction with large numbers of potentially pathogenic and beneficial microorganisms. Depending on the microbe, plants have evolved a variety of resistance mechanisms that can be constitutively expressed or induced. Phytoalexins, which are biocidal compounds of low to medium molecular weight synthesized by and accumulated in plants as a response to stress, take part in this intricate defense system.1,2
One of the limitations of our knowledge of phytoalexins is the difficulty of analyzing their spatial responsiveness occurring during plant- pathogen interactions under natural conditions.