terclim by ICS banner
IVES 9 IVES Conference Series 9 EMERGENCE OF INORGANIC PHOSPHONATE RESIDUES IN GRAPEVINE PLANT PARTS, BERRIES AND WINES FROM SOURCES OTHER THAN FOLIAR SPRAYING

EMERGENCE OF INORGANIC PHOSPHONATE RESIDUES IN GRAPEVINE PLANT PARTS, BERRIES AND WINES FROM SOURCES OTHER THAN FOLIAR SPRAYING

Abstract

Inorganic phosphonates are known to effectively support the control of grapevine downy mildew in vi- ticulture. Their application helps the plant to induce an earlier and more effective pathogen defense. However, inorganic phosphonates have been banned in organic viticulture due to their classification as plant protection products since October 2013. Despite the ban, phosphonate has been recently detected in organic wines. Winemakers often assured that they had not applied the fungicide, however, without providing solid proof. This development has fueled the need to better understand potential phosphonate sources and, in particular, phosphonate uptake and distribution in vines. For this purpose, we set up an isolated test field with container vines, allowing to investigate different routes of uptake and the subse- quent mobility of phosphonate over two consecutive years after defined applications. Samples of leaves, stems and berries were analysed by IC-ICP-MS, being validated for quantification of low phosphonate levels therein (LOQs of 0.08-0.15 mg/kg fresh weight). Thereby, grapevines were shown to take up well detectable amounts of phosphonate through the roots, although the total amount found in berries was significantly lower when applying a 0.54 % (w/v) phosphonate solution to the roots (6 mg/kg) than after foliar spray application (38 mg/kg). Furthermore, the determination of the ratios of phosphonate levels in leaves and those in stems allowed identifying whether the vines were sprayed with phosphonate or took up phosphonate through the roots, e.g., from contaminated groundwater. We also present data from open-field vineyards to validate the results obtained with container vines. Besides soil-borne phospho- nate, we also found phosphonate residues in enological additives and processing aids, also contributing to potential phosphonate contaminations in the final wine product. In brief, our contribution will provi- de new insights into the origin of phosphonate in vines and derived wines originating from vineyards that had not been sprayed with phosphonate in the respective growing season.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Sören Otto1, Randolf Kauer2, Yvette Wohlfahrt¹, Beate Berkelmann-Löhnertz3, Bianca May4, Ralf Schweiggert1

1. Geisenheim University, Von-Lade-Strasse 1, D-65366 Geisenheim, Germany
2. Department of Beverage Research, Chair of Analysis & Technology of Plant-based Foods
3. Department of Viticulture, Chair of Organic Viticulture
4. Department of Crop Protection, Chair of Crop Protection in Viticulture and Horticulture
5. Department of Enology, Chair of Wine and Beverage Chemistry

Contact the author*

Keywords

phosphonic acid, contaminants, IC-ICP-MS, organic viticulture

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

PESTICIDE RESIDUES IN THE VINEYARD ENVIRONMENTS: VINE LEAVES, GRAPE BERRIES, WINES, HONEYBEES AND ASIAN HORNETS

Synthetic pesticides are widely used in viticulture to ensure steady harvest quality and quantity. Fungicides are primarily used to control grapevine diseases but insecticides and herbicides are likewise used. Pesticide residues in viticultural areas currently represent a strong societal concern, but may also affect different trophic chains in such areas. In this project we wish to analyse honeybees collected from hives placed in different vineyards, their natural predator (the invasive hornet Vespa velutina), as well as the honey, grape berries, and wines produced.

ADDITION OF OAK WOOD ALTERNATIVE PRODUCTS: QUALITATIVE AND SENSORIAL EFFECTS FOR A WHITE WINE OF ALIGOTE

Wines matured in contact with wood are extremely popular with consumers all over the world. Oak wood allows the organoleptic characteristics of wine to be modified. Wines are enriched with volatile and non-volatile compounds extracted from the wood. The aromas extracted from oak wood contribute to the construction of the wine’s aromatic profile and the main polyphenols extracted can modify taste perceptions such as astringency and bitterness. All the compounds extracted from the wood thus contribute to the balance and quality of the wines.

USING CHECK-ALL-THAT-APPLY (CATA) TO CATEGORIZE WINES: A DECISION-MAKING TOOL FOR WINE SELECTION

Bordeaux is the largest appellation vineyard in France. This contrasting vineyard with varied terroirs offers all styles of wine, resulting from the blending of several grape varieties. If these different profiles make the renown of Bordeaux wines, it can appear as a constraint when the aim is to study Bordeaux wines in their diversity. The selection of a representative sample can be performed by a sensory analysis carried out by trained panelists or by wine professionals, which can take several forms: consensus among experts, conventional descriptive analysis, typicality or quality evaluation. However, because of time, economic, and logistical constraints, these methods have limited applications. As an alternative to classical descriptive analysis, more intuitive methods that do not require training have been proposed recently to describe wines using an expert panel such as Napping, Free Choice or Flash Profiling, CATA or RATA.

CHARACTERIZATION AND IDENTIFICATION OF YEAST BIOACTIVE PEPTIDES RELEASED DURING FERMENTATION AND AUTOLYSIS IN MODEL WINE

Aging wine on lees is a consolidated practice during which some yeast components (e.g., polysaccharides,
proteins, peptides) are released and solubilized in wine thus, affecting its stability and quality.
Apart from the widely studied mannoproteins, the role of other yeast components in modulating wine
characteristics is still scarce. Wine peptides have been studied for their contribution to taste, antioxidant,
and antihypertensive potentials. However, the peptides detected in wine can be influenced by the
interaction between yeasts and grape components.

OENOLOGICAL POTENTIAL OF AUTOCHTHONOUS SACCHAROMYCES CEREVISIAE STRAINS AND THEIR EFFECT ON THE PRODUCTION OF TYPICAL SAVATIANO WINES

Due to the global demand for terroir wines, the winemaking industry has focused attention on exploiting the local yeast microflora of each wine growing region to express the regional character and enhance the sensory profile of wines such as varietal typicity and aroma complexity. The objective of the present study was to isolate and compare the indigenous strains of Saccharomyces cerevisiae present in different vineyards in the Mesogeia – Attiki wine region (Greece), evaluate their impact on chemical composition and sensory profile of Savatiano wines and select the most suitable ones for winemaking process.