terclim by ICS banner
IVES 9 IVES Conference Series 9 EMERGENCE OF INORGANIC PHOSPHONATE RESIDUES IN GRAPEVINE PLANT PARTS, BERRIES AND WINES FROM SOURCES OTHER THAN FOLIAR SPRAYING

EMERGENCE OF INORGANIC PHOSPHONATE RESIDUES IN GRAPEVINE PLANT PARTS, BERRIES AND WINES FROM SOURCES OTHER THAN FOLIAR SPRAYING

Abstract

Inorganic phosphonates are known to effectively support the control of grapevine downy mildew in vi- ticulture. Their application helps the plant to induce an earlier and more effective pathogen defense. However, inorganic phosphonates have been banned in organic viticulture due to their classification as plant protection products since October 2013. Despite the ban, phosphonate has been recently detected in organic wines. Winemakers often assured that they had not applied the fungicide, however, without providing solid proof. This development has fueled the need to better understand potential phosphonate sources and, in particular, phosphonate uptake and distribution in vines. For this purpose, we set up an isolated test field with container vines, allowing to investigate different routes of uptake and the subse- quent mobility of phosphonate over two consecutive years after defined applications. Samples of leaves, stems and berries were analysed by IC-ICP-MS, being validated for quantification of low phosphonate levels therein (LOQs of 0.08-0.15 mg/kg fresh weight). Thereby, grapevines were shown to take up well detectable amounts of phosphonate through the roots, although the total amount found in berries was significantly lower when applying a 0.54 % (w/v) phosphonate solution to the roots (6 mg/kg) than after foliar spray application (38 mg/kg). Furthermore, the determination of the ratios of phosphonate levels in leaves and those in stems allowed identifying whether the vines were sprayed with phosphonate or took up phosphonate through the roots, e.g., from contaminated groundwater. We also present data from open-field vineyards to validate the results obtained with container vines. Besides soil-borne phospho- nate, we also found phosphonate residues in enological additives and processing aids, also contributing to potential phosphonate contaminations in the final wine product. In brief, our contribution will provi- de new insights into the origin of phosphonate in vines and derived wines originating from vineyards that had not been sprayed with phosphonate in the respective growing season.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Sören Otto1, Randolf Kauer2, Yvette Wohlfahrt¹, Beate Berkelmann-Löhnertz3, Bianca May4, Ralf Schweiggert1

1. Geisenheim University, Von-Lade-Strasse 1, D-65366 Geisenheim, Germany
2. Department of Beverage Research, Chair of Analysis & Technology of Plant-based Foods
3. Department of Viticulture, Chair of Organic Viticulture
4. Department of Crop Protection, Chair of Crop Protection in Viticulture and Horticulture
5. Department of Enology, Chair of Wine and Beverage Chemistry

Contact the author*

Keywords

phosphonic acid, contaminants, IC-ICP-MS, organic viticulture

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

EFFECT OF FUMARIC ACID ON SPONTANEOUS FERMENTATION IN GRAPE MUST

Malolactic fermentation (MLF)¹, the decarboxylation of L-malic acid into L-lactic acid, is performed by lactic acid bacteria (LAB). MLF has a deacidifying effect that may compromise freshness or microbiological stability in wines² and can be inhibited by fumaric acid [E297] (FA). In wine, can be added at a maximum allowable dose of 0.6 g/L³. Its inhibition with FA is being studied as an alternative strategy to minimize added doses of SO₂⁴. In addition, wine yeasts are capable of metabolizing and storing small amounts of FA and during alcoholic fermentation (AF).

NEW INSIGHTS INTO VOLATILE SULPHUR COMPOUNDS SCALPING ON MICROAGGLOMERATED WINE CLOSURES

The evolution of wine during bottle ageing has been of great interest to ensure consistent quality over time. While the role of wine closures on the amount of oxygen is well-known [1], closures could also play other roles such as the scalping phenomenon of flavour compounds. Flavour scalping has been described as the sorption of flavour compounds by the packaging material, which could result in losses of flavour intensity. It has been reported in the literature that volatile sulphur compounds (VSC) can be scalped on wine closures depending on the type of closure (traditional and agglomerated cork, screw-cap, synthetic [2]).

MOVING FROM SULFITES TO BIOPROTECTION: WHICH IMPACT ON CHARDONNAY WINE?

Over the last few years, several tools have been developed to reduce the quantity of sulfites used during winemaking, including bioprotection. Although its effectiveness in preventing the development of spoilage microorganisms has been proven, few data are available on the impact of sulfite substitution by bioprotection on the final product. The objective of this study was therefore to characterize Chardonnay wines with the addition of sulfite or bioprotection in the pre-fermentation stage. The effects of both treatments on resulting matrices was evaluated at several scales: analysis of classical oenological parameters, antioxidant capacity, phenolic compounds, non-volatile metabolome and sensory profile.

NEW TREATMENTS FOR TEMPRANILLO WINES BY USING CABERNET SAUVIGNON VINE-SHOOTS AND MICRO-OXYGENATION

Toasted vine-shoots as enological additive represents a promising topic due to their significant effect on wine profile. However, the use of this new enological tool with SEGs varieties different than wine and combined with others winemaking technologies, such as micro-oxygenation (MOX), has not been studied so far, despite this combination could result in wine with high chemical and organoleptic quality.

EXPLORING THE ROLE OF TRANSITION METAL IONS IN THE EVOLUTION OF ESTERS COMPOSITION OF YOUNG WHITE WINE DURING AGEING

Young white wines are typically released to the market a few months after harvest, to be consumed within a year, when their fresh fruity aromas are still dominant and appealing to modern consumers. Esters, particularly higher alcohol acetates (HAAs) and ethyl esters of fatty acids (EEFAs), play a central role in the fruity expression of young white wines [1]. However, these esters are known to undergo significant hydrolysis during the first months of aging [1, 2].