terclim by ICS banner
IVES 9 IVES Conference Series 9 PINKING PHENOMENA ON WHITE WINES: RELATION BETWEEN PINKING SUSCEPTIBILITY INDEX (PSI) AND WINE ANTHOCYANINS CONTENT

PINKING PHENOMENA ON WHITE WINES: RELATION BETWEEN PINKING SUSCEPTIBILITY INDEX (PSI) AND WINE ANTHOCYANINS CONTENT

Abstract

Pinking is the emergence of pink tones in white wines exclusively produced from white grape varieties, known as pinking phenomena for many years. Pinking is essentially appeared when white wines are produced under reducing conditions [1,2,3]. Pinking usually occurs after bottling and storage of white wines, but its appearance has also been described after alcoholic fermentation or even as soon as the grape must is extracted [4]. Therefore, the purpose of this work was to investigate the existence of an-thocyanins in white wines made from different white grape varieties and grown locations and critically evaluate the most common method used for predicting pinking appearance in white wines: the Pinking Susceptibility Index (PSI). Anthocyanins were concentrated by SPE [1]. Also, the products formed by hy-drogen peroxide oxidation of the same wines were isolated using this method. The correlation between the PSI and the whole visible spectra was studied by multivariate statistical methods, PCA and PLS ana-lysis, to evaluate the spectral regions in the visible spectra most important to the measured PSI. No cor-relation between anthocyanins concentration and the Pinking Susceptibility Index (PSI) was observed contrarily to the colour of wines exposed to oxygen (r = 0.871, p < 0.00005) [5]. The oxidation of wines with hydrogen peroxide resulted in the formation of various compounds. PSI was correlated with com-pounds absorbing in the 400–480 nm region, probably more related to the browning than the pinking phenomenon. The lack of correlation between the PSI and anthocyanins concentration in white wines can be due to the different chemical compositions of white wines that yield various compounds after oxidation that might not be related to the natural wine pinking phenomenon. Acknowledgments We appreciate the financial support provided to CQ-VR – Chemistry Research Centre – Vila Real (UIDB/00616/2020 and UIDP/00616/2020) by FCT – Portugal and COMPETE. The financial support of the project AgriFood XXI (NORTE-01-0145-FEDER-000041) co-financed by the European Regional Development Fund through NORTE 2020 (Programa Operacional Regional do Norte 2014/2020) is also acknowledged.

 

1. Andrea-Silva, J., Cosme, F., Filipe-Ribeiro, L., Moreira, A. S. P., Malheiro, A. C., Coimbra, M. A., … Nunes, F. M. (2014). Origin of the pinking phenomenon of white wines. Journal of Agricultural and Food Chemistry, 62, 5651–5659
2. Du Toit, W., Marais, J., Pretorius, I., & Du Toit, M. (2006). Oxygen in must and wine: A review. South African Journal for Eno-logy and Viticulture, 27, 76–94.
3. Filipe-Ribeiro, L., Andrea-Silva, J., Cosme, F., & Nunes, F. M. (2022). Chapter 15 –Pinking. In A. Morata (Ed.), White wine technology (pp. 187–195). Cambridge, Massachusetts, USA: Academic Press.
4. Simpson, R., Miller, G., & Orr, L. (1982). Oxidative pinking of whites wines: Recent observations. Food Technology in Australia, 34, 46–47.
5. Ana Carolina Gonçalves a, Fabrizio Minute b, Federico Giotto b, Luís Filipe-Ribeiro a, Fernanda Cosme a, Fernando M. Nunes (2022). Is pinking susceptibility index a good predictor of white wines pinking phenomena? Food Chemistry, 386, 132861

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Ana Carolina Gonçalves¹, Fabrizio Minute², Federico Giotto², Luís Filipe-Ribeiro¹, Fernanda Cosme¹, Fernando M. Nunes¹

1. CQ-VR—Chemistry Research Centre—Vila Real, Food and Wine Chemistry Laboratory, University of Trás-os-Montes and Alto Douro, 5000-801 Vila Real, Portugal
2. Giottoconsulting srl, 31051 Follina

Contact the author*

Keywords

White wines, Pinking, PSI, Monomeric anthocyanins

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

VALORIZATION OF GRAPE WINE POMACE USING PULSED ELECTRIC FIELDS (PEF) AND SUPERCRITICAL CO₂ (SC CO₂) EXTRACTION

Wine grape pomace quantitatively and qualitatively represents the most important fraction of wine waste. Namely, this by-product makes ~ 20% of the total mass of vinified grapes, and it is characterized with high concentrations of polyphenolic antioxidants, as well as grape seed oil. Hence, valorization of wine pomace, as an alternative to traditionally employed disposal, has drown considerable interest in recent years. Earlier studies were mostly focused on the extraction of phenolics, while mechanisms enhancing the extraction of lipid fraction from grape pomace, as well as their impact on the grape seed oil quality are far less investigated.

Grouping Vitis vinifera grapevine varieties based on their aromatic composition

Climate change is likely to impact wine typicity across the globe, raising concerns in wine regions historically renowned for the quality of their terroir1. Amongst several changes in viticultural practices, replacing some of the planting material (i.e. clones, rootstocks and cultivars) is thought to be one of the most promising potential levers to be used for adapting to climate change. But the change of cultivars also involves the issue of protecting the region’s wine typicity. In Bordeaux (France), extensive research has been conducted on identifying meridional varieties that could be good candidates to help guard against the effects of climate change2 while less research has been done concerning their impacts on Bordeaux wine typicity.

NEW TOOL FOR SIMULTANEOUS MEASUREMENT OF OXYGEN CONSUMPTION AND COLOUR MODIFICATIONS IN WINES

Measuring the effect of oxygen consumption on the colour of wines as the level of dissolved oxygen decreases over time is very useful to know how much oxygen a wine is able to consume without significantly altering its colour. The changes produced in wine after being exposed to high oxygen concen-trations have been studied by different authors, but in all cases the wine has been analysed once the oxygen consumption process has been completed. This work presents the results obtained with the use of an equipment designed and made to measure simultaneously the level of dissolved oxygen and the spectrum of the wine, during the oxygen consumption process from saturation levels with air to very low levels, which indicate the total consumption of the dosed oxygen.

ACIDIC AND DEMALIC SACCHAROMYCES CEREVISIAE STRAINS FOR MANAGING PROBLEMS OF ACIDITY DURING THE ALCOHOLIC FERMENTATION

In a recent study several genes controlling the acidification properties of the wine yeast Saccharomyces cerevisiae have been identified by a QTL approach [1]. Many of these genes showed allelic variations that affect the metabolism of malic acid and the pH homeostasis during the alcoholic fermentation. Such alleles have been used for driving genetic selection of new S. cerevisiae starters that may conversely acidify or deacidify the wine by producing or consuming large amount of malic acid [2]. This particular feature drastically modulates the final pH of wine with difference of 0.5 units between the two groups.

EXTRACTIBLE COMPOUNDS FROM MICROAGGLOMERATED CORK STOPPERS

After bottling, the wine continues to evolve during storage. The choice of the stopper is an important factor in this evolution. In addition to the oxygen permeability of the closure, the migration of stopper compounds into the wine can also have an impact on the wine organoleptic properties. Many studies have shown that transfers of volatile compounds from the stoppers into the wine can happen depending on the type of closure used (1). Moreover, when cork-made stoppers are used, the migration of phenolic compounds from the stopper into the wine can also occur (2, 3).