terclim by ICS banner
IVES 9 IVES Conference Series 9 CHEMICAL DRIVERS OF POSITIVE REDUCTION IN NEW ZEALAND CHARDONNAY WINES

CHEMICAL DRIVERS OF POSITIVE REDUCTION IN NEW ZEALAND CHARDONNAY WINES

Abstract

According to winemakers, wine experts and sommeliers, aromas of wet stone, mineral, struck match and flint in white wines styles, such as those produced from Vitis vinifera L. cv. Chardonnay, are considered to be hallmarks of positive reduction.1,2 In recent years, the production of Chardonnay styles defined by aroma characteristics related to positive reduction has become more desirable among wine experts and consumers. The chemical basis of positive reduction is thought to originate from the concentration of specific volatile sulfur compounds (VSCs), including methanethiol (MeSH) imparting mineral and chalk notes,3 and benzenemethanethiol (BMT) responsible for struck match and flint.1,4 However, the role of other aroma compounds, including esters, higher alcohols, and other VSCs, and their contribution to the sensory perception of positive reduction in New Zealand (NZ) Chardonnay wines has not been fully investigated. We selected 12 commercial NZ Chardonnay wines to represent a range of styles from low to high intensities of mineral and flint. Wine aroma profiles were analysed using headspace solid phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS). Quantitative descriptive analysis (QDA) was performed on the same wines using a trained panel. Wines varied greatly in both their chemical and sensorial characteristics. Multivariate analysis showed that there were several key VSCs found to be explanatory variables driving the perception of attributes related to positive reduction in the NZ Chardonnay wines. These results will be presented in the context of winemaking techniques that can be applied by the industry to achieve Chardonnay styles with positive reduction, if desired by the winemaker.

 

1. Tominaga, T.; Guimbertau, G.; Dubourdieu, D. Contribution of Benzenemethanethiol to Smoky Aroma of Certain Vitis Vinifera 
L. Wines. J. Agric. Food Chem. 2003, 51 (5), 1373–1376. https://doi.org/10.1021/jf020756c.
2. Malfeito-Ferreira, M. Wine Minerality and Funkiness: Blending the Two Tales of the Same Story. Fermentation 2022, 8 (12). https://doi.org/10.3390/fermentation8120745.
3. Rodrigues, H.; Sáenz-Navajas, M.-P.; Franco-Luesma, E.; Valentin, D.; Fernández-Zurbano, P.; Ferreira, V.; De La Fuente Blanco, A.; Ballester, J. Sensory and Chemical Drivers of Wine Minerality Aroma: An Application to Chablis Wines. Food Chem. 2017, 230, 553–562. https://doi.org/10.1016/j.foodchem.2017.03.036.
4. Capone, D. L.; Barker, A.; Williamson, P. O.; Francis, I. L. The Role of Potent Thiols in Chardonnay Wine Aroma. Aust. J. Grape Wine Res. 2018, 24 (1), 38–50. https://doi.org/10.1111/ajgw.12294.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Rebecca C.Deed1, Daisy Zhang¹, Jennifer R. Muhl², Mathilde Derycke²

1. School of Biological Sciences, The University of Auckland
2. School of Chemical Sciences, The University of Auckland

Contact the author*

Keywords

Chardonnay, Flint, Mineral, Volatile Sulfur Compounds

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

Grouping Vitis vinifera grapevine varieties based on their aromatic composition

Climate change is likely to impact wine typicity across the globe, raising concerns in wine regions historically renowned for the quality of their terroir1. Amongst several changes in viticultural practices, replacing some of the planting material (i.e. clones, rootstocks and cultivars) is thought to be one of the most promising potential levers to be used for adapting to climate change. But the change of cultivars also involves the issue of protecting the region’s wine typicity. In Bordeaux (France), extensive research has been conducted on identifying meridional varieties that could be good candidates to help guard against the effects of climate change2 while less research has been done concerning their impacts on Bordeaux wine typicity.

ANTI-TRANSPIRANT MODULATION OF GRAPE RIPENING: EFFECTS ON MERLOT VINE DEVELOPMENT AND ROSÉ WINE PHENOLIC AND AROMATIC PROFILES

Climate changes are impacting viticultural regions throughout the world with temperature increases being most prevalent.1 These changes will not only impact the regions capable of growing grapes, but also
the grapes that can be grown.2 As temperatures rise the growing degree days increase and with it the sugar accumulation within the berries and subsequent alcohol levels in wine. Consequently, viticultural
practices need to be examined to decrease the levels of sugars.

DETERMINATION OF FREE AMINO ACIDS, AMINO ACID POTENTIAL AND PROTEASE ACTIVITY IN THE LEES AND STILL WINES OF CHAMPAGNE

Prior to winemaking, organic or mineral nitrogen compound concentrations are usually measured in the vineyard and in grape musts. These indicators facilitate vine cultivation decisions, usually through yield or vigor. During vinification, yeast and bacteria metabolize nitrogen compounds in the musts in order to generate biomass. After fermentation, the microorganisms rerelease a part of this nitrogen as soluble compounds into the wines. Another part remains bound in the lees and can be lost during racking. The must’s natural nitrogen quantities, additional supplements during fermentation, and lees contact management enhance the release of nitrogen compounds to the wines. During ageing these nitrogen compounds – primarily the amino acids – are implicated in the generation of odorous compounds such as heterocycles(1).

WHITE WINES OXIDATIVE STABILITY: A 2-VINTAGE STUDY OF CHARDONNAY CHAMPAGNE BASE WINES AGED ON LEES IN BARRELS

Ultra-premium champagne wines are characterized by a long stay on laths. The goal of the winemaker is to use all possible oenological techniques to keep the aromatic freshness of the future products. To that purpose, some champagne base wines can be aged on lees in oak barrels. However, if it is now acknowledged that such ageing practices contribute to the oxidative stability of dry white wines, no study has been done on Chardonnay champagne base wines designed for a long ageing on laths [1].

AGEING REVEALS THE TERROIR OF AGED RED BORDEAUX WINES REGARDLESS OF THE VINTAGES! TARGETED APPROACH USING ODOROUS COMPOUNDS LEVELS INCLUDING TERPENES AND C13 NORISOPRENOIDS

The chemistry of wine is notably complex and is modified by ageing of the bottles. The composition of wines is the result of vine production (under the influence of vintage, climate and soils); yeast production (under the influence of juice composition and fermentation management); lactic bacteria production (under the influence of young wine composition and malolactic fermentation management); and of the ageing process either in vats, barrels or bottles or both. The composition is linked to the quality perceived by consumers but also to their origin, sometimes associated to the “terroir” concept.