terclim by ICS banner
IVES 9 IVES Conference Series 9 EXPLORING THE ROLE OF TRANSITION METAL IONS IN THE EVOLUTION OF ESTERS COMPOSITION OF YOUNG WHITE WINE DURING AGEING

EXPLORING THE ROLE OF TRANSITION METAL IONS IN THE EVOLUTION OF ESTERS COMPOSITION OF YOUNG WHITE WINE DURING AGEING

Abstract

Young white wines are typically released to the market a few months after harvest, to be consumed within a year, when their fresh fruity aromas are still dominant and appealing to modern consumers. Esters, particularly higher alcohol acetates (HAAs) and ethyl esters of fatty acids (EEFAs), play a central role in the fruity expression of young white wines [1]. However, these esters are known to undergo significant hydrolysis during the first months of aging [1, 2]. Therefore, understanding the factors that affect the hydrolysis of esters is crucial for wine producers. Although the hydrolysis of esters in wine matrices has been extensively studied for decades [3], the role of transition metal ions on the fate of esters in wines is still poorly documented.

This study aimed to explore the influence of Fe, Mn and Cu on the evolution of the ester composition of young white wines after 8-weeks of artificial ageing at 30 ºC under different conditions. Young white wines were spiked with different mixtures of Fe, Mn and Cu, to reach final concentrations of 5 mg/L, 4 mg/L and 1 mg/L of metal ions, respectively. Wines were then aged in 20 mL SPME vials, full and half-full (oxidative conditions).

The presence of gallic acid was also tested in interaction with metal ions added.

The presence of the Fe, Mn, and Cu mixture, described, above significantly increased the hydrolysis of HAAs and EEFAs in two different wine samples, with an 18% and 25% drop in HAAs and a 12% and 15% drop in EEFAs, respectively, compared to the same wine samples without the addition of metal ions. The oxidative aging did not affect this trend, except for EEFAs with long carbon chains (C10 and C12), which showed a decrease in concentration when the vial was half-full in comparison to full vial.

In contrast, the presence of gallic acid at 50 mg/L limited the effect of the metal ion mixture on esters hydrolysis. Each metal ion was also tested individually. Fe alone or in association with Cu had the same impact as the mixture of the three metal ions. Surprisingly, esters hydrolysis was significantly boosted with the addition of Cu and Mn alone or in mixture, but also when Fe was mixed with Mn. The addition of Mn alone had the strongest impact with a drop of 40% and 30% of HAAs and EEFAs concentration, respectively.

This work opens new research perspectives on how transition metal ions can shape the evolution of wine esters and, more broadly, the aromatic composition of wine.

1. Antalick, G.; Perello, M.-C.; de Revel, G. Esters in Wines: New Insight through the establishment of a Database of French wines. Am. J. Enol. Vitic. 2014, 65, 293-304.
2. Gammacurta, M; Marchand, S.; Albertin, W.; Moine, V.; de Revel G. Impact of yeast strain on ester levels and fruity aroma persistence during aging of Bordeaux red wines. J. Agric. Food Chem. 2014, 62(23), 5378-89.
3. Ribéreau-Gayon, P., Y. Glories, A. Maujean, and D. Dubourdieu. Handbook of Enology. Vol 2. The Chemistry of Wine: Stabilisation and Treatments. Wiley & Sons, Chichester, 2000.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Tatjana Radovanović Vukajlović¹, Mitja Martelanc¹, Martin Šala², Vid Simon Šelih², Melita Sternad Lemut¹, Guillaume Antalick¹

1. University of Nova Gorica, Wine Research Centre, Lanthieri Palace, Glavni trg 8, SI-5271 Vipava, Slovenia
2. National Institute of Chemistry, Hajdrihova 19, 1000, Ljubljana, Slovenia

Contact the author*

Keywords

esters, transition metal ions, hydrolysis, radical scavengers

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

NEW PLANT BIOPOLYMERS FOR THE COLLOIDAL STABILITY OF THE COLORING MATTER OF RED WINES

The color as well as the “clarity” of red wines are ones of the qualities required by the consumers. Red wines must have colloidal stability from its bottling to its consumption. The supplementation of red wines with additives, and especially Acacia senegal gum, contributes to its organoleptic properties such as the colloidal stabilization of the coloring matter. In a global perspective of limitation of additives in the field of enology, one of the objectives is notably (i) to reduce the use of additives in wines, by their number and/or their quantity, and (ii) to favor the use of natural additives while preserving the organoleptic and sensory qualities of wines.

Beyond liking scores: the importance of the drinking experience to understand our consumers

The presentation will approach the understanding of wine consumers´ perception based on the experiential model suggested by Warell (2008). In this framework, wine consumption gives rise to a
variety of experiences related to the perception, understanding, and judgment of the product. These
multidimensional facets of the drinking experience can be explored by measuring affective, cognitive,
and sensory responses of consumers, which are shown to be stable regardless of the social context.

IMPACT OF MUST NITROGEN DEFICIENCY ON WHITE WINE COMPOSITION DEPENDING ON GRAPE VARIETY

Nitrogen (N) nutrition of the vineyard strongly influences the must and the wine compositions. Several chemical markers present in wine (i.e., proline, succinic acid, higher alcohols and phenolic compounds) have been proposed for the cultivar Chasselas, as indicators of N deficiency in the grape must at harvest [1]. Grape genetics potentially influences the impact of N deficiency on grape composition, as well as on the concentration of potential indicators in the wine. The goal of this study was to evaluate if the che- mical markers found in Chasselas wine can be extended for other white wines to indicate N deficiency in the grape must.

USING CHECK-ALL-THAT-APPLY (CATA) TO CATEGORIZE WINES: A DECISION-MAKING TOOL FOR WINE SELECTION

Bordeaux is the largest appellation vineyard in France. This contrasting vineyard with varied terroirs offers all styles of wine, resulting from the blending of several grape varieties. If these different profiles make the renown of Bordeaux wines, it can appear as a constraint when the aim is to study Bordeaux wines in their diversity. The selection of a representative sample can be performed by a sensory analysis carried out by trained panelists or by wine professionals, which can take several forms: consensus among experts, conventional descriptive analysis, typicality or quality evaluation. However, because of time, economic, and logistical constraints, these methods have limited applications. As an alternative to classical descriptive analysis, more intuitive methods that do not require training have been proposed recently to describe wines using an expert panel such as Napping, Free Choice or Flash Profiling, CATA or RATA.

FLAVONOID POTENTIAL OF MINORITY RED GRAPE VARIETIES

The alteration in the rainfall pattern and the increase in the temperatures associated to global climate change are already affecting wine production in many viticultural regions all around the world (1). In fact, grapes are nowadays ripening earlier from a technological point of view than in the past, but they are not necessarily mature from a phenolic point of view. Consequently, the wines made from these grapes can be unbalanced or show high alcohol content. Dramatic shifts in viticultural areas are currently being projected for the future (2).