terclim by ICS banner
IVES 9 IVES Conference Series 9 METHYL SALICYLATE: A TRENDY COMPOUND MARKER OF ZELEN, A UNIQUE SLOVENIAN VARIETY

METHYL SALICYLATE: A TRENDY COMPOUND MARKER OF ZELEN, A UNIQUE SLOVENIAN VARIETY

Abstract

The wine market interest for autochthonous varieties, particularly from less known wine regions, has significantly raised in the past few years. In that context, Slovenia, a small country from central Europe with a long winemaking tradition, is getting more and more attention, particularly through its range of unique regional varieties. Among them, Zelen, meaning “green” in Slovene, can only be found in the Vipava valley region, located on the western side of the country, near the border with Italy. When they are young, Zelen wines display very singular aromas reminiscent of rosemary, sage and white fruit. Despite its uniqueness, Zelen wine aromatic typicality is poorly documented in the literature. The goal of this study was to highlight some potential aromatic markers specific to Zelen in comparison to other international and regional varieties grown in Slovenia. A first batch of 28 white wines from different Slovenian wine regions including 8 Zelen wines, were analysed for their contents in volatile thiols by GC/MS/MS, terpenoids, and untargeted screening by HS/SPME-GC/MS. Thereafter a second batch of 67 wines from Vipava valley including 25 Zelen wines, were analysed for their contents in methyl salicylate and volatile phenols by HS/SPME-GC/MS. The first batch of analyses showed that Zelen had lower content in volatile thiols and higher concentration in some monoterpenols such as linalool in comparison to other varieties. Nevertheless, two com- pounds identified with the untargeted analysis seemed to be particularly important in Zelen wines aro- matic profile: methyl salicylate and 4-vinylguaiacol. The second batch of analysis confirmed this trend with the average concentration of methyl salicylate at 14 µg/L and 3 µg/L in Zelen and other wines respectively. The highest concentration was measured at 38 µg/L in one Zelen wine, which corresponds to the sensory threshold measured in neutral white wines [1]. Methyl salicylate has recently gained some attention as it was found that this compound could contribute to the Italian Verdicchio and Lugana wines aromatic profile [1,2] and to some Bordeaux red wines made under specific conditions [3,4]. Zelen wines also displayed higher concentrations of 4-vinylguaiacol with 30% of Zelen wines having concentrations above the perception threshold reported for white wines [5]. Preliminary sensory investigations suggested that both compounds could potentially contribute to Zelen aromatic typicality.

 

1. Slaghenaufi, D.; Luzzini, G.; Solis, J. S.; Forte, F., Ugliano, M.; Two Sides to One Story—Aroma Chemical and Sensory Signature of Lugana and Verdicchio Wines (2021), Molecules 26: 2127.
2. Carlin, S.; Vrhovsek, U.; Lonardi, A.; Landi L.; Mattivi F., Aromatic complexity in Verdicchio wines: a case study. (2019), OENO One 4: 597-610
3. Pelonnier-Magimel, E.; Lytra, G.; Franc, C.; Farris, L.; Darriet, P.; Barbe, J-C. Methyl Salicylate, an Odor-Active Compound in Bordeaux Red Wines Produced without Sulfites Addition (2022), J. Agric. Food Chem.70: 39
4. Poitou, X.; Redon, P.; Pons, A.; Bruez, E.; Delière, L.; Marchal, A.; Cholet, C.; Geny-Denis, L.; Darriet, P. Methyl salicylate, a grape and wine chemical marker and sensory contributor in wines elaborated from grapes affected or not by cryptogamic diseases. (2021). Food Chem. 360:130120
5. Chatonnet, P.; Dubordieu, D.; Boidron, J-N.; Lavigne, V.; Synthesis of volatile phenols by Saccharomyces cerevisiae in wines (1993). J. Sci. Food Agric. 62(2): 191–202 

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Guillaume Antalick¹, Mitja Martelanc¹, Tatjana Radovanović Vukajlović¹, Diana Martin¹, Katja Šuklje², Andreja Vanzo², Klemen Lisjak², Davide Slaghenaufi³ Branka Mozetič Vodopivec¹, Melita Sternad Lemut¹, Lorena Butinar¹

1. University of Nova Gorica, Wine Research Centre, Lanthieri Palace, Glavni trg 8, SI-5271 Vipava, Slovenia
2. Agricultural Institute of Slovenia, Department of Fruit Growing, Viticulture and Oenology, Hacquetova ulica 17, 1000 Ljubl-jana, Slovenia
3. Department of Biotechnology, University of Verona, 37134 Verona, Italy

Contact the author*

Keywords

Zelen, typicality, methyl salicylate, 4-vinylguaiacol

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

WHICH IMPACT FOR PROANTHOCYANIDIC TANNINS ON RED WINE FRUITY AROMA? SENSORY AND PHYSICOCHEMICAL APPROACHES

Previous research on the fruity character of red wines highlighted the role of esters. Literature provides evidence that, besides these esters, other compounds that are not necessarily volatiles may have an important impact on the overall aroma of wine, contributing to a modulation of its global aromatic expression. The goal of this work was to assess the olfactory consequences of a mixture between esters and proanthocyanidic tannins, through sensory and physico-chemical approaches.
Sensory analysis of numerous aromatic reconstitutions, including triangular tests, detection thresholds, and sensory profiles, were conducted in order to evaluate the sensory impact of tannins on red wine esters perception.

LARGE-SCALE PHENOTYPIC SCREENING OF THE SPOILAGE YEAST BRETTANOMYCES BRUXELLENSIS: UNTANGLING PATTERNS OF ADAPTATION AND SELECTION, AND CONSEQUENCES FOR INNOVATIVE WINE TREATMENTS

Brettanomyces bruxellensis is considered as the main spoilage yeast in oenology. Its presence in red wine leads to off-flavour due to the production of volatile phenols such as 4-vinylphenol, 4-vinylguaiacol, 4-ethylphenol and 4-ethylguaiacol, whose aromatic notes are unpleasant (e.g. animal, leather, horse or pharmaceutical). Beside wine, B. bruxellensis is commonly isolated from beer, kombucha and bioethanol production, where its role can be described as negative or positive. Recent genomic studies unveiled the existence of various populations.

YEAST DERIVATIVE PRODUCTS: CHARACTERIZATION AND IMPACT ON RIBOFLAVIN RELEASE DURING THE ALCOHOLIC FERMENTATION

Light-struck taste (LST) is a wine fault that can occur in white and sparkling wines when exposed to light. This defect is mainly associated to the formation of methanethiol and dimethyl disulfide due to light-induced reactions involving riboflavin (RF) and methionine [1]. The presence of RF in wine is mainly due to the metabolism of yeast [2] which fermenting activity can be favoured by using yeast derivative products (YDPs) as nutrients. Nonetheless, a previous study showed the addition of YDPs before the alcoholic fermentation (AF) led to higher concentrations of RF in wines [3]. Due to the widespread use of YDPs in the winemaking process, this study aimed to understand the possible relation between the content of RF in wine and the YDP adopted as nutrient for AF.

SENSORY EVALUATION OF WINE AROMA: SHOULD COLOR-DRIVEN DESCRIPTORS BE USED?

The vocabulary used to describe wine aroma is commonly organized according to color, raising the question of whether they reflect the reality of olfactory perception. Previous studies have assumed this convention of color-aroma matching, and have investigated color’s influence on the perception of aroma only in dyed white wine or in red wine from particular places of origin. Here 48 white and red varietal wines from around the world were evaluated in black glasses then in clear glasses by a panel of wine experts, who gave intensity ratings for aroma attributes commonly used by wine professionals. In black glasses, aromas conventionally associated with white wine were perceived in the red wines, and vice versa.

NEW METHOD FOR THE QUANTIFICATION OF CONDENSED TANNINS AND OTHER WINE PHENOLIC COMPOUNDS USING THE AUTOMATED BIOSYSTEMS SPICA ANALIZER

Wine phenolic compounds are important secondary metabolites in enology due to their antioxidant and nutraceutical properties, and their role in the development of color, taste, and protection of wine from oxidation and spoilage. Tannins are valuable phenolic compounds that contribute significantly to these wine properties, especially in mouthfeel characteristics; however, tannin determination remains a significant challenge, with manual and time-consuming methods or complex methodologies. The purpose of this study is to propose a novel method for quantifying condensed tannins in finished wine products.