terclim by ICS banner
IVES 9 IVES Conference Series 9 PRECISE AND SUSTAINABLE OENOLOGY THROUGH THE OPTIMIZED USE OF AD- JUVANTS: A BENTONITE-APPLIED MODEL OF STUDY TO EXPLOIT

PRECISE AND SUSTAINABLE OENOLOGY THROUGH THE OPTIMIZED USE OF AD- JUVANTS: A BENTONITE-APPLIED MODEL OF STUDY TO EXPLOIT

Abstract

As wine resilience is the result of different variables, including the wine pH and the concentration of wine components, a detailed knowledge of the relationships between the adjuvant to attain stability and the oenological medium is fundamental for process optimization and to increase wine durability till the time of consumption.

This work merges our 10-years’ studies¹ on bentonite along with information from the literature to design a study-model feasible to optimize the effects of adjuvants by maximizing the impact on targeted compounds, while minimizing the one on desirable wine components. The boosting was simply based on the frequently unintended uses of oenological adjuvants by winemakers based also on some lacking in the EU regulations, which produces jeopardized main and side-effects, as the ones by bentonite are emblematic.

Indeed, there is no EU regulated upper limit for the addition of bentonite during the winemaking process, but the International Oenological Codex establishes the properties of the oenological bentonites amending the three classes of Ca-, Na-, and Na-activated bentonite.

Our studies demonstrated that the from-bentonite enrichment in wine cations results from the clay Cation Exchange Capacity (CEC) and from the pH, ethanol content and ionic strength which also impact on the residual card-house clay structure that is an important property for deproteinization. Indeed, for the removal of hazing forming proteins (b-glucanases, thaumatin-like proteins, chitinases) clay properties as CEC, Swell Index (SI), and Specific Surface Area (SSA) as well as wine pH are more impacting than the bentonite dose.

Considering adjuvant side-effects, bentonite can remove phenolic compounds so to modify wine colour and astringency. About terpenic wines, double addition to must for clarifying and to wine for fining outlined less removal than to the solely wine treatment. Removal of aglycones by low doses and of glycosylated terpenols especially by Ca-bentonite were predicted by RSM. For the fermentative aroma compounds, adsorption intensity and capacity more depended on the characteristics of the bentonite (SSA and CEC) than on the properties of the substances: the main removal is an indirect effect of deproteinization, while a direct adsorption can be described by the Freundlich equation for only a few compounds.

 

1. Lambri M., Colangelo D., Dordoni R., Torchio F., De Faveri D.M. (2016). Innovations in the Use of Bentonite in Oenology: Interactions with Grape and Wine Proteins, Colloids, Polyphenols and Aroma Compounds, Chapter 18 in (Ed. Morata A. and Loira I., Intech Publisher) book: Grape and Wine Biotechnology. p. 381-400. ISBN 978-953-51-2692-8.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Milena Lambri*1, Roberta Dordoni1, Mario Gabrielli1

1. Department for Sustainable Food Process – DiSTAS, Università Cattolica del Sacro Cuore, Via Emilia Parmese, 84 – 20122 Piacenza (Italy)

Contact the author*

Keywords

Oenological practices, Precision oenology, Adjuvant optimization, Bentonite, Wine resi-lience

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

PROGRESS OF STUDIES OF LEES ORIGINATING FROM THE FIRST ALCOHOLIC FERMENTATION OF CHAMPAGNE WINES

Champagne wines are produced via a two-step process: the first is an initial alcoholic fermentation of grape must that produces a still base wine, followed by a second fermentation in bottle – the prise de mousse – that produces the effervescence. This appellation produces non-vintage sparkling wines composed of still base wines assembled from different vintages, varieties, and regions. These base wines, or “reserve wines,” are typically conserved on their fine lies and used to compensate for quality variance between vintages (1). Continuously blending small amounts of these reserve wines into newer ones also facilitates preserving the producer’s “house style.”

INVESTIGATION OF MALIC ACID METABOLIC PATHWAYS DURING ALCOHOLIC FERMENTATION USING GC-MS, LC-MS, AND NMR DERIVED 13C-LABELED DATA

Malic acid has a strong impact on wine pH and the contribution of fermenting yeasts to modulate its concentration has been intensively investigated in the past. Recent advances in yeast genetics have shed light on the unexpected property of some strains to produce large amounts of malic acid (“acidic strains”) while most of the wine starters consume it during the alcoholic fermentation. Being a key metabolite of the central carbohydrate metabolism, malic acid participates to TCA and glyoxylate cycles as well as neoglucogenesis. Although present at important concentrations in grape juice, the metabolic fate of malic acid has been poorly investigated.

ALCOHOLIC FERMENTATION AND COLOR OF ROSÉ WINES: INVESTIGATIONS ON THE MECHANISMS RESPONSIBLE FOR SUCH DIVERSITY

Color is one of the key elements for the marketing of rosé wines due to their packaging in transparent bottles. Their broad color range is due to the presence of pigments belonging to phenolic compounds extracted from grapes or formed during the wine-making process. However, the mechanisms responsible for such diversity are poorly understood. The few investigations performed on rosé wines showed that their phenolic composition is highly variable, close to that of red wines for the darkest rosés but very different for light ones [1]. Moreover, large variations in the extent of color loss taking place during fermentation have been reported but the mechanisms involved and causes of such variability are unknown.

THE INFLUENCE OF COMMERCIAL SACCHAROMYCES CEREVISIAE ON THE POLY-SACCHARIDES AND OTHER CHEMICAL PROFILES OF NEW ZEALAND PINOT NOIR WINES

Wine polysaccharides (PS) play an important role in balancing mouthfeel and stability of wine and even influence aroma volatility. Despite this, there is limited research into the effect of winemaking additives on the polysaccharide profile and other macromolecules of New Zealand (NZ) Pinot noir wine. In this study the influence of a selection of commercial S. cerevisiae strains on the chemical profile, including polysaccharides, of New Zealand Pinot noir (PN) wine was investigated. Research scale PN fermentations using five strains of commercially available S. cerevisiae (Lalvin EC1118 and RC212, Levuline BRG YSEO, Viallate Ferm R71 and R82) were undertaken. PS were qualified and quantified using HPLC-RID.

MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

From the chemical angle, Champagne wines are complex hydro-alcoholic mixtures supersaturated with dissolved carbon dioxide (CO₂). During the pouring process and throughout the several minutes of tasting, the headspace of a champagne glass is progressively invaded by many chemical species, including gas-phase CO₂ in large majority. CO₂ bubbles nucleated in the glass and collapsing at the champagne surface act indeed as a continuous paternoster lift for aromas throughout champagne or sparkling wine tasting [1]. Nevertheless, inhaling a gas space with a concentration of gaseous CO₂ close to 30% and higher triggers a very unpleasant tingling sensation, the so-called “carbonic bite”, which might completely perturb the perception of the wine’s bouquet.