terclim by ICS banner
IVES 9 IVES Conference Series 9 FACTORS AFFECTING QUERCETIN SOLUBILITY IN SANGIOVESE RED WINE: FIRST RESULTS

FACTORS AFFECTING QUERCETIN SOLUBILITY IN SANGIOVESE RED WINE: FIRST RESULTS

Abstract

Quercetin (Q) is present in grape in form of glycosides and as aglycone. These compounds are extracted from grape skins during winemaking. In wines, following the hydrolysis reactions, the amount of quercetin aglycon can exceed its solubility value. Unfortunately, a threshold solubility concentration for quercetin in wine is not easy to determine because it depends on wine matrix (Gambuti et al., 2020).

This study is aimed at evaluating factors affecting the solubility of Q in red wine. The role of anthocyanins and mannoproteins (MPs) was evaluated. The role of anthocyanins in Q solubility was evaluated by adding known amount of grape derived anthocyanins to a model solution containing 30 mg/L of quercetin. Data showed that the solubility of Q increased by increasing the amount of grape derived anthocyanins in model solution until a complete dissolution of 30 mg/L of Q when 740,8903 ± 17,069 mg//l of anthocyanins were added. This is likely due to the π-π interactions between anthocyanins and Q determining the formation of stable copigmentation complexes in red wine (Whaterhouse 2016). In a further experiment the addition of two different mannoproteins to a model solution containing 30 mg/L of quercetin and grape derived anthocyanins was also tested in controlled conditions. A slight positive effect of MPs on quercetin solubility (until the twelve % of value detected in control samples) was observed. It is therefore likely that group of compounds tested are involved in Q colloidal stability.

 

1. Angelita Gambuti1 • Luigi Picariello1 • Alessandra Rinaldi1,2 • Martino Forino1 • Giuseppe Blaiotta1 • Virginie Moine2 • Luigi Moio New insights into the formation of precipitates of quercetin in Sangiovese wines (2020)
2. Waterhouse AL, Sacks GL, Jeffery DW (2016) Understanding wine chemistry. Wiley, Hoboken

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Alessandra Luciano¹, Alessandra Rinaldi¹, Luigi Picariello¹, Luigi Moio¹, Angelita Gambuti¹

1. Department of Agricultural Sciences, Section of Vine and Wine Sciences, University of Napoli ⟨Federico II⟨, Viale Italia, Avellino 83100, Italy

Contact the author*

Keywords

Quercetin, solubility, wine, anthocyanins, mannoproteins

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

IMPACT OF ACIDIFICATION AT BOTTLING BY FUMARIC ACID ON RED WINE AFTER 2 YEARS

Global warming is responsible for a lack of organic acid in grape berries, leading to wines with higher pH and lower titrable acidity. The chemical, microbiological and organoleptic equilibriums are impacted by this change of organic acid concentration. It is common practice to acidify the wine in order to prevent these imbalances that can lead to wine defects and early spoilage. Tartaric acid (TA) is most commonly used by winemaker for wine acidification purposes. Fumaric acid (FA), which is authorized by the OIV in its member states for the inhibition of malolactic fermentation, could also be used as a potential acidification candidate since it has a better acidifying power than tartaric acid.

TANNINS AND ANTHOCYANINS KINETICS OF EXTRACTION FROM ARINARNOA, MARSELAN AND TANNAT UNDER DIFFERENT WINEMAKING TECHNIQUES

Marselan wines have an unusual high proportion of seed derived tannins from grapes having high proportions of skins, which are rich in tannins. But the causes behind this characteristic have not yet been identified. In vintage 2023 wines were made at experimental scale (9 kg by experimental unit) from Arinarnoa, Marselan and Tannat Vitis vinifera grape cultivars by traditional maceration, and by techniques aimed to increase the wine content in skin derived tannin: addition of extraction enzymes, addition at vatting of grape-skin enological tannins, or by extended maceration, known to increase the seed derived tannin contents of wines.

HOW DOES ULTRASOUND TREATMENT AFFECT THE AGEING PROFILE OF AN ITALIAN RED WINE?

Many wine styles require moderate or extended ageing to ensure optimal consumer experience. However, few consumers have the interest or ability to age wine themselves, and holding wine in optimal conditions for extended periods is expensive for producers. A study was conducted on the use of ul-trasound energy on wine, with particular reference to its impact on sensory and chemical profiles. The OIV has authorised the use of ultrasound for processing crushed grapes (must) in Resolution OENO 616-2019, but not yet for finished wine1,2.

HYDROXYTYROSOL PRODUCTION BY DIFFERENT YEAST STRAINS: SACCHAROMYCES AND NON-SACCHAROMYCES AND THE RELATION WITH THE NITROGEN CONSUMPTION

Hydroxytyrosol (HT) is a phenolic compound with extensive bioactive properties. It is present in olives, olive oil and wines. Its occurrence in wines is partly due to yeast synthetise tyrosol from tyrosine by the Ehrlich pathway, which is subsequently hydroxylated to .
The aim of the present work is to study how different yeast strains can influence in the HT production and, how the different nitrogen consumption of each strain can interfere the production of bioactive compounds.

DEVELOPMENT OF BIOPROSPECTING TOOLS FOR OENOLOGICAL APPLICATIONS

Wine production is a complex biochemical process that involves a heterogeneous microbiota consisting of different microorganisms such as yeasts, bacteria, and filamentous fungi. Among these microorganisms, yeasts play a predominant role in the chemistry of wine, as they actively participate in alcoholic fermentation, a biochemical process that transforms the sugars in grapes into ethanol and carbon dioxide while producing additional by-products. The quality of the final product is greatly influenced by the microbiota present in the grape berry, and the demand for indigenous yeast starters adapted to specific grape must and reflecting the biodiversity of a particular region is increasing. This supports the concept that indigenous yeast strains can be associated with a “terroir”.