Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of non-fruity compounds on red wines fruity aromatic expression: the role of higher alcohols

Impact of non-fruity compounds on red wines fruity aromatic expression: the role of higher alcohols

Abstract

A part, at least, of the fruity aroma of red wines is the consequence of perceptive interactions between various aromatic compounds, particularly ethyl esters and acetates, which may contribute to the perception of fruity aromas, specifically thanks to synergistic effects.1,2 The question of the indirect impact of non-fruity compounds on this particular aromatic expression has not yet been widely investigated. Among these compounds higher alcohols (HA) represent the main group, from a quantitative standpoint, of volatiles in many alcoholic beverages. Moreover, some bibliographic data suggested their contribution to the aromatic complexity by either increasing or masking flavors of wine, depending of their concentrations.3 Thus, we focused on the impact of five HA on the perception of fruity aroma in red wines. Various aromatic reconstitutions were prepared, consisting of five HA and the red wine fruity pool composed of thirteen ethyl esters and acetates, all at the average concentrations found in red wine. Sensory analysis highlighted the individual particular behavior of two HA, 3-methylbutan-1-ol and butan-1-ol, added individually at supra- and infra-threshold concentrations, respectively. Furthermore, these two compounds reduced the “olfactory threshold” of the fruity mixture as well as modified the qualitative perception of the fruity reconstitution. Adding five HA to different matrices and at various concentrations, representative of the diversity of wine composition, revealed a new remarkable perceptive interaction, and more precisely, a masking effect on fruity aromas perception. Their simultaneous addition to the model solution also modified the qualitative perception of the fruity reconstitution, particularly exacerbating the perception of butyric and solvent notes and attenuating the perception of fruity notes.4 This study, the first one devoted to the impact of HA on fruity aromatic expression, demonstrated that HA participate, both quantitatively and qualitatively, in masking fruity aroma perception of a wine fruity model mixture. These findings emphasized the importance of HA, a chemical family described for a long time which could therefore lead to a decrease of the perception of fruity notes in red wine. Thus the modulation of their levels during winemaking process is likely to influence indirectly the sensory quality of red wine. Keywords: red wine, perceptive interactions, higher alcohols, ethyl esters and acetates.

1. Pineau, B.; Barbe, J.-C.; Van Leeuwen, C.; Dubourdieu, D. J. Agric. Food Chem. 2009, 57 (9), 3702–3708. 2. Lytra, G.; Tempere, S.; Le Floch, A.; de Revel, G.; Barbe, J.-C. J. Agric. Food Chem. 2013, 61 (36), 8504–8513. 3. Ribéreau-Gayon, P.; Dubourdieu, D.; Donèche, B.; Lonvaud-Funel, A. Handbook of Enology – The chemistry of wine: Stabilisation and treatments, 6th ed.; Dunod; 2012; Vol. 1. 4. Cameleyre, M., Lytra, G., Tempère, S., Barbe, J-C. J. Agric. Food Chem. 2015. 63 (44), pp 9777–9788.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Jean-Christophe Barbe*, Georgia Lytra, Margaux Cameleyre, Sophie Tempere

*Université De Bordeaux

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Effect of malolactic fermentation in barrels or stainless steel tanks on wine composition. Influence of the barrel toasting

Ellagitannin, anthocyanin and woody volatile composition of Cabernet Sauvignon wines aged in oak barrels for 12 months was evaluated. Depending on the container where malolactic fermentation (MLF) was carried out, two wine modalities were investigated: wines with MLF carried out in stainless steel tanks and barrel-fermented wines. Three toasting methods (medium toast, MT; medium toast with watering, MTAA; noisette) were considered for ageing of each wine modality. Sensory analyses (triangle and rating tests) were also performed. Two-way ANOVA of the raw experimental data revealed that the toasting method and the container where MLF took place, as well as the interaction between both factors, have a significant influence (p < 0.05) on ellagitannin, anthocyanin and woody volatile profiles of Cabernet Sauvignon wines.

Impact of elemental sulfur (S0) residues in Sauvignon blanc juice on the formation of the varietal thiols 3-mercapto hexanol and 3-mercaptohexyl acetate

Elemental sulfur is a fungicide used by grape growers to control the development of powdery mildew, caused by the fungus Erysiphe necator. This compound is effective, cheap and has a low toxicity with no withholding period recommended. However, high levels of S0 residues in the harvested grapes can lead to the formation of reductive sulfur compounds that can impart taints and faults to the wine. Hydrogen sulphide (H2S) is a very volatile and unpleasant sulfur compound which formation is connected to high residues of S0 in juice (10 – 100 mg/L).

Nitrogen – Lipid Balance in alcoholic fermentations. Example of Champagne musts

Nutrient availability – nitrogen, lipids, vitamins or oxygen – has a major impact on the kinetics of winemaking fermentations. Nitrogen is usually the growth-limiting nutrient and its availability determines the fermentation rate, and therefore the fermentation duration. In some cases, in particular in Champagne, grape musts have high nitrogen concentrations and are sometimes clarified with turbidity below 50 NTU. In these conditions, lipid deficiencies may occur and longer fermentations can be observed. To better understand this situation, a study was realized using a synthetic medium simulating the composition of a Champagne must : 180 g/L of sugar, 360 mg/L of assimilable nitrogen and a lipid content ranging from 1 to 8 mg/L of phytosterols (mainly β-sitosterol).

Cover crops influence on soil N availability and grapevine N status, and its relationship with biogenic

The type of soil management, tillage versus cover crops, can modify the soil microbial activity, which causes the mineralization of organic N to NO3–N and, therefore, may change the soil NO3–N availability in vineyard. The soil NO3–N availability could influence the grapevine nutritional status and the grape amino acid composition. Amino acids are precursors of biogenic amines, compounds mainly formed during the malolactic fermentation. Biogenic amines have negative effects on consumer health and on the wine organoleptic quality. The objective was to study if the effect of conventional tillage and two different cover crops (leguminous versus gramineous) on grapevine N status, could relate to the wine biogenic amines composition.

The effect of Nitrogen and Sulphur foliar applications in hot climates

ine nitrogen deficiency can negatively influence the aroma profile and ageing potential of white wines. Canopy management can alter vine microclimate, affect the nitrogen availability and influence the response of leaf senescence. Increasing the nitrogen availability to vines can increase the Yeast Assimilable Nitrogen (YAN) levels in harvested fruit and wine. Studies show that foliar nitrogen and sulphur applications at véraison, on low YAN Sauvignon blanc grapes have an effect on the level of amino acids (Jreij et al. 2009) and on S-containing compounds such as glutathione and thiols (Lacroux et al. 2008), which in turn can influence the formation of major volatiles and the aroma profile of the wine.