Macrowine 2021
IVES 9 IVES Conference Series 9 Development and validation of a standardized oxidation assay for the accurate measurement of the ability of different wines to form “de novo” oxidation-related aldehydes

Development and validation of a standardized oxidation assay for the accurate measurement of the ability of different wines to form “de novo” oxidation-related aldehydes

Abstract

From the standpoint of wine aroma oxidation there are two effects observed: aroma degradation of oxygen sensitive compounds (polyfunctional mercaptans) and the appearance of new substances with high aromatic power (acetaldehyde, methional, phenylacetaldehyde, sotolon, alkenals, isobutanal and 2, 3-metylbutanals) (1-5). According to our experience, Strecker aldehydes are compounds with highest sensory relevance in the oxidative degradation of many wines (5-7). Based on previous research, it was observed that these compounds can be already present in freshly bottled wines, free from any sign of oxidation; forming stable, non-volatile and odorless complexes with sulfur dioxide (8). During storage in the bottle these compounds are released as the level of free SO2 decreases by oxidation causing a shift in the SO2-aldehyde adduct chemical equilibria. Moreover, wine aldehydes can be formed throught direct oxidation of their precursors (“de novo” formation), when the free SO2 level is under 5 mg/l (7-8). The main goal of this work is to study the intrinsic ability of the wines for the formation of “aldehydes de novo”. Hence, a method to consume oxygen at controlled doses, at 45 ° C, has been developed. This oxidation method allows to reach de novo formation of aldehydes on a fast way (2-7 days) depending on the wine. The validation of this method is carried out maintaining the same oxidation conditions at 25º C. In addition, the same wines have been submitted to consecutive air saturation cycles (9) for means of comparation. The proposed strategy comprises the study of eight red wines in duplicate, each wine underwent three increasing oxygen doses. The analysis carried out at the beginning at the and end of the oxidation were: aminoacids, metals, free and total SO2, total carbonyl compounds, acetaldehyde, color, IPT, Folin, as well as major and trace aroma compounds. The results show that this is a reproducible method of oxidation, which allows to reach de novo formation of aldehydes at all doses studied. Different profiles of oxygen consumption are obtained depending on the age and previous contact with oxygen, temperature had a strong effect on the formation of Strecker aldehydes with respect to the oxygen consumed.

1. Wildenradt et al., AJEV,1974, 25, 119 2. Escudero et al., JAFC, 2000, 48, 4268 3. Ferreira, A.C.S et al., JAFC, 2003, 51, 1377 4. Cutzach et al., JISVV, 1998, 32, 211 5. Culleré et al., JAFC, 2007, 55, 876 6. San Juan et al., JAFC, 2012, 60, 5045 7. Ferreira et al., JAFC, 2014,62, 10015 8. Bueno et al., JAFC., DOI 10.102117acs.jafc5b04634 9. Ferreira et al. ., JAFC., 2015, 63, 10928

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Almudena Marrufo-Curtido*, Ana Escudero, Ignacio Ontañon, Mónica Bueno, Vanesa Carrascon, Vicente Ferreira

*

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

On the losses of dissolved CO2 from laser-etched champagne glasses under standard tasting conditions

Under standard champagne tasting conditions, the complex interplay between the level of dissolved CO2 found in champagne, its temperature, the glass shape, and the bubbling rate, definitely impacts champagne tasting by modifying the neuro-physico-chemical mechanisms responsible for aroma release and flavor perception. Based on theoretical principles combining heterogeneous bubble nucleation, ascending bubble dynamics and mass transfer equations, a global model is proposed (depending on various parameters of both the wine and the glass itself), which quantitatively provides the progressive losses of dissolved CO2 from laser-etched champagne glasses.

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way.

Characterizing the effects of nitrogen on grapevines with different scion/rootstock combinations: agronomic, metabolomic and transcriptomic approaches

Most vineyards are grafted and include a variety (Vitis vinifera) grafted over a wild Vitis rootstock (hybrids of V. berlandieri, riparia and rupestris). Grape berry quality at harvest depends on a subtle balance between acidity and the concentrations of sugars, polyphenols and precursors of aroma compounds. The mechanisms controlling the balance of sugars/acids/polyphenols are influenced by the abiotic environment, in particular nitrogen supply, and interact with the genotypes of both the scion variety and the rootstock. Previous work suggests that some of the effects of water stress are in fact linked to a nitrogen deficiency driven indirectly by the reduction of water absorption.

Towards multi-purpose valorisation of polyphenols from grape pomace: Pressurized liquid extraction coupled to purification by membrane processes

Grape by-products (including skins, seeds, stems and vine shoots) are rich in health promoting polyphenols. Their extraction from winery waste and their following purification are of special interest to produce extracts with high added value compounds. Meanwhile, the growing concern over environmental problems associated with economic constraints, require the development of environmentally sustainable extraction technologies. The extraction using semi-continuous subcritical water, as a natural solvent at high temperature and high pressure a technology is promising “green” technology that is environmentally friendly, energy efficient and improve the extraction process in plant tissues.

How small amounts of oxygen introduced during bottling and storage can influence the metabolic fingerprint and SO2 content of white wines

The impact of minute amounts of headspace oxygen on the post-bottling development of wine is generally considered to be very important, since oxygen, packaging and storage conditions can either damage or improve wine quality. This is reflected in the generalised use of inert bottling lines, where the headspace between the white wine and the stopper is filled with an inert gas. This experiment aimed to address some open questions about the chemistry of the interaction between wine and oxygen, crucial for decisions regarding optimal closure. While it is known that similar amounts of oxygen affect different wines to a variable extent, our knowledge of chemistry is not sufficient to construct a predictive method.