Macrowine 2021
IVES 9 IVES Conference Series 9 Development and validation of a standardized oxidation assay for the accurate measurement of the ability of different wines to form “de novo” oxidation-related aldehydes

Development and validation of a standardized oxidation assay for the accurate measurement of the ability of different wines to form “de novo” oxidation-related aldehydes

Abstract

From the standpoint of wine aroma oxidation there are two effects observed: aroma degradation of oxygen sensitive compounds (polyfunctional mercaptans) and the appearance of new substances with high aromatic power (acetaldehyde, methional, phenylacetaldehyde, sotolon, alkenals, isobutanal and 2, 3-metylbutanals) (1-5). According to our experience, Strecker aldehydes are compounds with highest sensory relevance in the oxidative degradation of many wines (5-7). Based on previous research, it was observed that these compounds can be already present in freshly bottled wines, free from any sign of oxidation; forming stable, non-volatile and odorless complexes with sulfur dioxide (8). During storage in the bottle these compounds are released as the level of free SO2 decreases by oxidation causing a shift in the SO2-aldehyde adduct chemical equilibria. Moreover, wine aldehydes can be formed throught direct oxidation of their precursors (“de novo” formation), when the free SO2 level is under 5 mg/l (7-8). The main goal of this work is to study the intrinsic ability of the wines for the formation of “aldehydes de novo”. Hence, a method to consume oxygen at controlled doses, at 45 ° C, has been developed. This oxidation method allows to reach de novo formation of aldehydes on a fast way (2-7 days) depending on the wine. The validation of this method is carried out maintaining the same oxidation conditions at 25º C. In addition, the same wines have been submitted to consecutive air saturation cycles (9) for means of comparation. The proposed strategy comprises the study of eight red wines in duplicate, each wine underwent three increasing oxygen doses. The analysis carried out at the beginning at the and end of the oxidation were: aminoacids, metals, free and total SO2, total carbonyl compounds, acetaldehyde, color, IPT, Folin, as well as major and trace aroma compounds. The results show that this is a reproducible method of oxidation, which allows to reach de novo formation of aldehydes at all doses studied. Different profiles of oxygen consumption are obtained depending on the age and previous contact with oxygen, temperature had a strong effect on the formation of Strecker aldehydes with respect to the oxygen consumed.

1. Wildenradt et al., AJEV,1974, 25, 119 2. Escudero et al., JAFC, 2000, 48, 4268 3. Ferreira, A.C.S et al., JAFC, 2003, 51, 1377 4. Cutzach et al., JISVV, 1998, 32, 211 5. Culleré et al., JAFC, 2007, 55, 876 6. San Juan et al., JAFC, 2012, 60, 5045 7. Ferreira et al., JAFC, 2014,62, 10015 8. Bueno et al., JAFC., DOI 10.102117acs.jafc5b04634 9. Ferreira et al. ., JAFC., 2015, 63, 10928

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Almudena Marrufo-Curtido*, Ana Escudero, Ignacio Ontañon, Mónica Bueno, Vanesa Carrascon, Vicente Ferreira

*

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The impact of different yeasts and harvest time on the wine quality of Beihong and Beimei (<I>V. vinifera x V. amurensis</I>)

Beihong and Beimei are two wine cultivars from ‘Muscat Hamberg’ (V. vinifera L.) and wild V. amurensis Rupr., which were released in China in 2008. Here,two enology practices were reported. Firstly, the impact of different yeasts including D254, GRE, K1, D21 and BDX on dry wine quality of Beihong and Beimei was investigated. For Beihong, among wines fermented by all yeasts, residual sugar content was the lowest, total anthocyanin and resveratrol contents were the highest in the wine by D254. However, the wine by D254 had lower titrable acid than those by the other yeasts except BDX.

Attractiveness and sweetness of red wines: Synergies between American oak barrels and mannoproteins

In partnership with a Bordeaux property wanting to improve the quality of its second wine, the effects of two factors, American oak barrels and mannoproteins were studied. Their impact on the attractiveness and sweetness of wines were characterized during two successive vintages (2012 and 2013). Vinification took place with a homogeneous batch of Cabernet Sauvignon. The wine was then divided up into various groups of five barrels of French and American oak, new or reused. Analyses of volatile and non-volatile wood compounds were undertaken at four months and eight months of wood ageing, by LC-MS and GC-MS.

Study of the volatil profile of minority white varieties

The genetic material preservation is a priority issue in winemaking research. The recovery of minority grape varieties can control the genetic erosion, contributing also to preserve wine typical characteristics. In D.O.Ca. Rioja (Spain) the number of grown white varieties has been very limited, representing Viura the 91% of the cultivated white grape area in 2005, while the others, Garnacha Blanca and Malvasía riojana, hardly were grown. For this reason, a recovery and characterization study of plant material was carried out in this region. In 2008, the results obtained allowed the authorization of three minority white varieties: Tempranillo Blanco, Maturana Blanca and Turruntés.

Ethyl esters interact with the major wine Thaumatin Like Protein VVTL1

The interactions among aromatic compounds and proteins is an important issue for the quality of foods and beverages. In wine, the loss of flavor after vinification is associated to bentonite treatment and this effect can be the result of the removal of aroma compounds which are bound wine proteins. This phenomenon was recently demonstrated for long chain fatty acids and their ethyl esters (1). Since these latter compounds are spectroscopically silent, their association with proteins is not easy to measure.

How small amounts of oxygen introduced during bottling and storage can influence the metabolic fingerprint and SO2 content of white wines

The impact of minute amounts of headspace oxygen on the post-bottling development of wine is generally considered to be very important, since oxygen, packaging and storage conditions can either damage or improve wine quality. This is reflected in the generalised use of inert bottling lines, where the headspace between the white wine and the stopper is filled with an inert gas. This experiment aimed to address some open questions about the chemistry of the interaction between wine and oxygen, crucial for decisions regarding optimal closure. While it is known that similar amounts of oxygen affect different wines to a variable extent, our knowledge of chemistry is not sufficient to construct a predictive method.