Macrowine 2021
IVES 9 IVES Conference Series 9 Study of the volatil profile of minority white varieties

Study of the volatil profile of minority white varieties

Abstract

The genetic material preservation is a priority issue in winemaking research. The recovery of minority grape varieties can control the genetic erosion, contributing also to preserve wine typical characteristics. In D.O.Ca. Rioja (Spain) the number of grown white varieties has been very limited, representing Viura the 91% of the cultivated white grape area in 2005, while the others, Garnacha Blanca and Malvasía riojana, hardly were grown. For this reason, a recovery and characterization study of plant material was carried out in this region. In 2008, the results obtained allowed the authorization of three minority white varieties: Tempranillo Blanco, Maturana Blanca and Turruntés. Tempranillo Blanco comes from a mutation of Tempranillo Tinto and it was picked up for the first time in La Rioja in 1988. Maturana Blanca and Turruntés have been grown since long time ago and were recovered from old vineyards. Tempranillo Blanco and Maturana Blanca are only authorized in D.O.Ca. Rioja, and therefore they can really contribute to wines differentiation, increasing the added value and providing wines with personal and marked characteristics. Turruntés, that is a synonym of Albillo Mayor, is cultivated in other Spanish regions. The variety is one of the main factors responsible for the must and wine aroma. In this study, the pre-fermentative volatile profile of five minority white varieties was determined during the 2014 vintage, in comparison to Viura, considering it as the reference variety. All the cultivars were grown in an experimental vineyard. The volatile compounds of these varieties were analyzed by HS-SPME-GC-MS. The results showed marked differences in the aromatic profile of the studied grape varieties. In all cases, C6 were the most abundant compounds (70 – 93%), followed by norisoprenoids (4 – 13%), carbonyl (0.6 – 4%), benzenoids (0.1 – 4%) and terpenoids (1.2 – 3.3%). Cv. Tempranillo Blanco highlighted by a high content of C6 compounds, greater than cv. Malvasía, Turruntés and Viura. The most representative compounds were hexanal and (E)-2-hexenal. Within norisoprenoids, (E)-β-damascenone and (Z)-β-damascenone were the most abundant compounds in cv. Garnacha Blanca and Malvasía. In these varieties a higher content of terpenoids, such as trans-geranyl-acetone, β-linalool and nerol oxide was observed. Both, norisoprenoids and terpenoids are the most odoriferous groups of compounds, with floral scents that play a key role in the varietal aroma. The content of benzenoids in cv. Malvasía and cv. Turruntés was higher than in the rest of varieties, being 2-phenylethanol the most important molecule. Tempranillo Blanco and Garnacha Blanca presented a significantly higher global aromatic content than Turruntés and Viura. Thus, minority white grape varieties can provide wines with interesting and marked aromatic characteristics.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Ana Gonzalo-Diago*, Enrique García-Escudero, Estela Terroba-Pérez, Juana Martínez

*ICVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Impact of smoke exposure on the chemical composition of grapes

Vineyard exposure to smoke can lead to grapes and wine which exhibit objectionable smoky and ashy aromas and flavours, more commonly known as ‘smoke taint’ [1, 2]. In the last decade, significant bushfires have occurred around the world, including near wine regions in Australia, Canada, South Africa and the USA, as a consequence of the warmer, drier conditions associated with climate change. Considerable research has subsequently been undertaken to determine the chemical, sensory and physiological consequences of grapevine exposure to smoke. The sensory attributes associated with smoke-tainted wine have been linked to the presence of several smoke-derived volatile phenols, such as guaiacols, syringols and cresols [2].

The impact of different yeasts and harvest time on the wine quality of Beihong and Beimei (<I>V. vinifera x V. amurensis</I>)

Beihong and Beimei are two wine cultivars from ‘Muscat Hamberg’ (V. vinifera L.) and wild V. amurensis Rupr., which were released in China in 2008. Here,two enology practices were reported. Firstly, the impact of different yeasts including D254, GRE, K1, D21 and BDX on dry wine quality of Beihong and Beimei was investigated. For Beihong, among wines fermented by all yeasts, residual sugar content was the lowest, total anthocyanin and resveratrol contents were the highest in the wine by D254. However, the wine by D254 had lower titrable acid than those by the other yeasts except BDX.

Reaction Mechanisms of Copper and Iron with Hydrogen Sulfide and Thiols in Model Wine

Fermentation derived sulfidic off-odors due to hydrogen sulfide (H2S) and low molecular weight thiols are commonly encountered in wine production and removed by Cu(II) fining. However, the mechanism underlying Cu(II) fining remains poorly understood, and generally results in increased Cu concentration that lead to deleterious reactions in finished wine. The present study describes a mechanistic investigation of the iron and copper mediated reaction of H2S, cysteine, 3-sulfanylhexan-1-ol, and 6-sulfanylhexan-1-ol with oxygen. The concentrations of H2S, thiols, oxygen, and acetaldehyde were monitored over time. It was found that Cu(II) was rapidly reduced by both H2S and thiols to Cu(I).

Analysis of voltammetric fingerprints of different white grape musts reveals genotype-related oxidation patterns

Must oxidation is a complex process involving multiple enzymatic transformations, including the oxidation of phenolics containing an ortho-diphenol function. The latter process has a primary influence on wine aroma characteristics and stability, due to the central role of ortho-diphenols in the non-enzymatic oxidative reactions taking place during winemaking and in finished wine. Although oxidation of must is traditionally avoided, in recent years its contribution to wine quality has been revisited, and in some cases improvements to wine aroma have been observed with the application of controlled must oxidation. Nowadays there is a great interest in the wine industry towards the identification of specific markers or patterns to characterize and classify the response of grape must to oxidation.

Analysis of the oenological potentials of different oak forests in Hungary

Like France, Hungary has many oak forests used for making barrels since many years. But if the differences between the woods of the North, the East and the South-West forests of France are well known, this is probably not the case of Hungarian forests. However taking into account the essential differences of climates and soils, differences must be significant and the general name “Hungarian oak” must not have any real meaning. We have studied precisely (determination of concentrations of volatile and non-volatile wood compounds, anatomical criteria, measurement of antioxidant capacity) of oaks collected from northeastern Hungary and others collected from the Danube valley in the northwest of the country.