Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of sulfur compounds to the antioxidant stability of white wines

Impact of sulfur compounds to the antioxidant stability of white wines

Abstract

The chemical mechanisms involved in oxidation/reduction potential of wine during winemaking and aging are affecting its color, aroma and taste. Chemical oxidation is one of the major causes of development of off-flavors during ageing1. Thus, the chemical changes in wine during storage should be controlled to ensure the sensory quality of the product and avoid consumer rejection that will compromise the economic value of the product. The 1-hydroxyethyl radical has been recognized as the key radical intermediate in the oxidative reactions in wine2. Based on the kinetic study of POBN-1-hydroxyethyl spin adduct formation in wines initiated via the Fenton reaction, a novel tool was recently developed in our laboratory to quantify the resistance of wines against oxidation3. Among the compounds in wine that potentially can inhibit oxidative reactions, thiol-containing compounds (RSH) have received increasing attention in recent years4. Moreover, the role of thiols as antioxidants in wine is usually assessed by quantifying the amounts of reduced and oxidized forms (i.e. GSH-GSSG) in wines5. In this study, in a vertical series of chardonnay wines, from 1995 to 2013 vintage, and from a same winery in Burgundy, we analyzed the amounts of targeted sulfur containing compounds. A good correlation among the total thiol content and the resistance against oxidation in different wines was observed. This provides direct information about the redox state of the wine and gives more insights in the mechanisms controlling wines ageing potential. Acknowledgements: We thank the regional council of Burgundy for their financial support.

1. Escudero, A.; Cacho, J.; Ferreira, V. Eur. Food Res. Tech. 2000, 211 (2), 105-110. 2. Elias, R. J.; Andersen, M. L.; Skibsted, L. H.; Waterhouse, A. L. Journal of Agricultural and Food Chemistry 2009, 57 (10), 4359-4365. 3. Nikolantonaki, M.; Coelho, C.; Gougeon, R. D. In A novel method for evaluation of white wine aging potential OENO, Bordeaux, Bordeaux, 2015. 4. Kreitman, G. Y.; Laurie, V. F.; Elias, R. J. Journal of Agricultural and Food Chemistry 2013, 61 (3), 685-692. 5. Mattivi, F.; Fedrizzi, B.; Zenato, A.; Tiefenthaler, P.; Tempesta, S.; Perenzoni, D.; Cantarella, P.; Simeoni, F.; Vrhovsek, U. Analytica Chimica Acta 2012, (0).

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Maria Nikolantonaki*, Christian Coelho, Régis Gougeon

*Université de Bourgogne

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Microbial stabilization of wines using innovative coiled UV-C reactor process: impact on chemical and organoleptic proprieties

For several years, numerous studies aimed at limiting the use of SO2 in wines (thermal treatments, pulsed electric fields, microwaves …). Processes must be able to preserve the organoleptic qualities of wines with low energy consumption. In this context, ultraviolet radiations (UV-C), at 254 nm, are well known for their germicidal proprieties. In order to inactivate microorganisms in grape juice and wine without affecting the quality of the product, efficiency of UV-C treatment process should be optimized.

Effects of bottle closure type on sensory characteristics of Chasselas wines

Several winemaking operations, such as filtration, pumping, and racking, are known to potentially facilitate the incorporation of atmospheric O2 into the wine. Control of grape must oxidation is one key aspect in the management of white wine aroma expression, color stability and shelf-life extension. On the one hand, controlled must oxidation may help to remove highly reactive phenolic compounds, which otherwise could contribute to premature oxidation. And on the other hand, in certain cases of extreme protection of the must from O2 (e.g. pressing under inert atmosphere), it can help to preserve varietal aromas and natural must antioxidants.

Elicitors used as a tool to increase stilbenes in grapes and wines

The economic importance of grapevine as a crop plant makes Vitis vinífera a good model system to study the improvement of the nutraceutical properties of food products (Vezulli et al. 2007). Stilbenes in general, and trans-resveratrol in particular, have been reported to be responsible for various beneficial effects. Resveratrol´s biological properties include antibacteria and antifungal effects, as well as cardioprotective, neuroprotective and anticâncer actions (Guerrero et al. 2010 ). Stilbenes can be induced by biotic and abiotic elicitors since they are phytoalexins (Bavaresco et al. 2001).

Interactions of wine polyphenols with dead or living Saccharomyces cerevisiae Yeast Cells and Cell Walls: polyphenol location by microscopy

Tannin, anthocyanins and their reaction products play a major role in the quality of red wines. They contribute to their sensory characteristics, particularly colour and astringency. Grape tannins and anthocyanins are extracted during red wine fermentation. However, their concentration and composition change over time, due to their strong chemical reactivity1. It is also well known that yeasts influence the wine phenolic content, either through the release of metabolites involved in the formation of derived pigments1, or through polyphenol adsorption2,3.

The impact of different yeasts and harvest time on the wine quality of Beihong and Beimei (<I>V. vinifera x V. amurensis</I>)

Beihong and Beimei are two wine cultivars from ‘Muscat Hamberg’ (V. vinifera L.) and wild V. amurensis Rupr., which were released in China in 2008. Here,two enology practices were reported. Firstly, the impact of different yeasts including D254, GRE, K1, D21 and BDX on dry wine quality of Beihong and Beimei was investigated. For Beihong, among wines fermented by all yeasts, residual sugar content was the lowest, total anthocyanin and resveratrol contents were the highest in the wine by D254. However, the wine by D254 had lower titrable acid than those by the other yeasts except BDX.