Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of sulfur compounds to the antioxidant stability of white wines

Impact of sulfur compounds to the antioxidant stability of white wines

Abstract

The chemical mechanisms involved in oxidation/reduction potential of wine during winemaking and aging are affecting its color, aroma and taste. Chemical oxidation is one of the major causes of development of off-flavors during ageing1. Thus, the chemical changes in wine during storage should be controlled to ensure the sensory quality of the product and avoid consumer rejection that will compromise the economic value of the product. The 1-hydroxyethyl radical has been recognized as the key radical intermediate in the oxidative reactions in wine2. Based on the kinetic study of POBN-1-hydroxyethyl spin adduct formation in wines initiated via the Fenton reaction, a novel tool was recently developed in our laboratory to quantify the resistance of wines against oxidation3. Among the compounds in wine that potentially can inhibit oxidative reactions, thiol-containing compounds (RSH) have received increasing attention in recent years4. Moreover, the role of thiols as antioxidants in wine is usually assessed by quantifying the amounts of reduced and oxidized forms (i.e. GSH-GSSG) in wines5. In this study, in a vertical series of chardonnay wines, from 1995 to 2013 vintage, and from a same winery in Burgundy, we analyzed the amounts of targeted sulfur containing compounds. A good correlation among the total thiol content and the resistance against oxidation in different wines was observed. This provides direct information about the redox state of the wine and gives more insights in the mechanisms controlling wines ageing potential. Acknowledgements: We thank the regional council of Burgundy for their financial support.

1. Escudero, A.; Cacho, J.; Ferreira, V. Eur. Food Res. Tech. 2000, 211 (2), 105-110. 2. Elias, R. J.; Andersen, M. L.; Skibsted, L. H.; Waterhouse, A. L. Journal of Agricultural and Food Chemistry 2009, 57 (10), 4359-4365. 3. Nikolantonaki, M.; Coelho, C.; Gougeon, R. D. In A novel method for evaluation of white wine aging potential OENO, Bordeaux, Bordeaux, 2015. 4. Kreitman, G. Y.; Laurie, V. F.; Elias, R. J. Journal of Agricultural and Food Chemistry 2013, 61 (3), 685-692. 5. Mattivi, F.; Fedrizzi, B.; Zenato, A.; Tiefenthaler, P.; Tempesta, S.; Perenzoni, D.; Cantarella, P.; Simeoni, F.; Vrhovsek, U. Analytica Chimica Acta 2012, (0).

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Maria Nikolantonaki*, Christian Coelho, Régis Gougeon

*Université de Bourgogne

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The effect of cropload on the volatile aroma characteristics of ‘Beihong’ and ‘Beimei’ red wine

Beihong and Beimei were bred as winemaking cultivars released by Institute of Botany, the Chinese Academy of Sciences in 2008. The cultivars are selected from the population of ‘Muscat Hamburg’ (Vitis vinifera) ×V. amurensis. They are extended to most provinces in North of China because they have strong resistance to cold and disease and need not be buried in soil in winter. To better understand the effect of cropload on volatile compounds during wine-making, we surveyed volatiles composition and content of different cropload level in 3-years-old ‘Beihong’ and ‘Beimei’ vines which planted in east foot of Helan mountain of Ningxia (EHN).

Effect of malolactic fermentation in barrels or stainless steel tanks on wine composition. Influence of the barrel toasting

Ellagitannin, anthocyanin and woody volatile composition of Cabernet Sauvignon wines aged in oak barrels for 12 months was evaluated. Depending on the container where malolactic fermentation (MLF) was carried out, two wine modalities were investigated: wines with MLF carried out in stainless steel tanks and barrel-fermented wines. Three toasting methods (medium toast, MT; medium toast with watering, MTAA; noisette) were considered for ageing of each wine modality. Sensory analyses (triangle and rating tests) were also performed. Two-way ANOVA of the raw experimental data revealed that the toasting method and the container where MLF took place, as well as the interaction between both factors, have a significant influence (p < 0.05) on ellagitannin, anthocyanin and woody volatile profiles of Cabernet Sauvignon wines.

Influence of methyl jasmonate foliar application to vineyard on grape volatile composition over three consecutive vintages

An alternative to improve grape quality is the application to the vineyard of elicitors. Although these compounds were first used to increase resistance of plants against pathogens, it has been found that they are also able to induce mechanisms involved in the synthesis of phenolic compounds and some amino acids. However, researches about the influence of elicitors on grape volatile composition are scarcely. Therefore, the aim of this work was to study the influence of methyl jasmonate (MeJ) foliar application on grape aroma composition over three consecutive vintages. MeJ was applied to Tempranillo grapevines at a concentration of 10 mM in 2013, 2014, and 2015 years. Control plants were sprayed with water.

Anti/prooxidant activity of wine polyphenols in reactions of adrenaline auto-oxidation

Adrenaline (epinephrine) belongs to catecholamine class. It is a neurotransmitter and both a hormone which is released by the sympathetic nervous system and adrenal medulla in response to a range of stresses in order to regulate blood pressure, cardiac stimulation, relaxation of smooth muscles and other physiological processes. Adrenaline exhibits an effective antioxidant capacity (1). However, adrenalin is capable to auto-oxidation and in this case it generates toxic reactive oxygen intermediates and adrenochrome. Under in vitro conditions, auto-oxidation of adrenaline occurs in an alkaline medium (2).

Petrolomics-derived data interpretation to study acetaldehyde-epicatechin condensation reactions

During red wine ageing or conservation, color and taste change and astringency tends to reduce. These changes result from reactions of flavan-3-ols and/or anthocyanins among which condensation reactions with acetaldehyde are particularly important. The full characterization of these reactions has not been fully achieved because of difficulties in extracting and separating the newly formed compounds directly from wine. Model solutions mimicking food products constitute a simplified medium for their exploration, allowing the detection of the newly formed compounds, their isolation, and their structure elucidation.