OENO IVAS 2019 banner
IVES 9 IVES Conference Series 9 OENO IVAS 9 OENO IVAS 2019 9 Analytical tools using electromagnetic spectroscopy techniques (IR, fluorescence, Raman) 9 Monitoring small-scale alcoholic fermentations using a portable FTIR-ATR spectrometer and multivariate analysis

Monitoring small-scale alcoholic fermentations using a portable FTIR-ATR spectrometer and multivariate analysis

Abstract

Although some wine production processes still rely on post-production evaluation and off-site laboratory analysis, the new winemaking industry is aware of a need for a better knowledge of the process to improve the properties of the final product. Thus, more and more wineries are interested in incorporating quality-by-design (QbD) strategies instead of postproduction testing because of the possibility to early detect deviations in fermentation or any other wine process. This would allow to detect unwanted situations and eventually to ‘readjust’ the process, thus minimizing rejects. 

A strategy consisting on coupling FTIR-ATR spectroscopy and multivariate analysis is here proposed as a fermentation process control strategy. The idea was to develop a portable, rapid, easy-to-use and economic device/tool to monitor fermentation processes and to detect deviations from the normal fermentation conditions (NFC). A portable FTIR-ATR spectrometer was used to monitor small-scale alcoholic fermentations (microvinifications), some of them conducted in NFC and some others intentionally deviated from it. FTIR-ATR measurements were collected during the fermentation process and relative density and content of sugars (glucose and fructose), acetic acid, malic acid and lactic acid were analyzed by traditional methods. 

Multivariate analysis (exploratory methods and linear regression methods) was applied in order to model the whole fermentation process and detect deviations. The prediction of the sugar content in fermenting samples was achieved, demonstrating the possibility to use this portable device to rapidly monitor fermentations and to detect at an early stage slower fermentations, giving the possibility to the winemaker to eventually correct the process and to obtain a good quality product. Moreover, control charts based on multivariate Hotelling T2 and Q statistics were built to detect abnormal deviations. In conclusion, this methodology shows great potential as a fast and simple at-line analysis tool for early detection of fermentation problems. 

Acknowledgment:

The financial support by the Spanish Ministry of Science and Technology (Project AGL2015-70106-R) is acknowledged.

DOI:

Publication date: June 23, 2020

Issue: OENO IVAS 2019

Type: Article

Authors

Julieta Cavaglia, Barbara Giussani, Olga Busto, Laura Aceña, Joan Ferré, Montserrat Mestres, Ricard Boqué

Dipartimento di Scienza e Alta Tecnologia. Universitàdegli Studi dell’Insubria. Via Valleggio, 9. 22100 Como Italy 
Chemometrics, Qualimetrics and Nanosensors Group, Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili 43007 Tarragona Spain 

Contact the author

Keywords

rocess Control, Alcoholic Fermentation, FTIR, Portable device 

Tags

IVES Conference Series | OENO IVAS 2019

Citation

Related articles…

Grape must quality and mesoclimatic variability in Fruška Gora wine-growing region, Serbia

The Fruška Gora mountain is a traditional wine-growing region in Serbia situated in the Pannonian Basin. Due to such a position, the vicinity of the Danube River and the presence of concave configuration, it is suitable for grape production. This paper provides analyses of spatial variations in meteorological parameters and grape juice quality within Fruška Gora wine region over three consecutive vintages (2018-2020). The examined period can be defined as warm with cool nights during September (AVG 18,9°C; GDD 1918°C; CI 12°CF) and with the presence of mesoclimatic variability. The East part of the study area was somewhat drier and hotter compared to other parts of the region. The analyses of grape must samples (190 in total) of five cultivars (Cabernet-Sauvignon, Merlot, Chardonnay, Sauvignon blanc and Grašac (Welschriesling)) commonly grown across the region (19 sites), were performed using Fourier Transform Infrared Technology (FTIR). Among all cultivars, Sauvignon blanc was harvested first in the East area (DOY=246±5, GDD at harvest=1552±74, 22.2±0.7 °Brix), while the latest harvest was recorded for Cabernet-Sauvignon in the West (DOY=283±5, GDD at harvest=1936±187, 23.4±1.0 °Brix ). Both the red and white cultivars had higher acidity and YAN in the grape must if the vines were grown in the North and East compared to South and West areas. According to PCA analysis, Grašac showed the lowest variation in grape must chemical composition. Thus, the results confirm that Grašac is the most stable cultivar in Fruška Gora. All monitored cultivars reached technological fruit ripeness by the end of the growing season. However, it was difficult to reach full ripeness of red cultivars, mostly beacuse of uncoupling of technolocical and phenolic ripeness. Thus, Cabernet-Sauvignon had higher variations in GDD sums at harvest compared to other cultivars, which probably increased variations in grape must quality.

Vine responses to two irrigation systems in the region of Vinhos Verdes

In this work we try to know the influence of two irrigation systems (Drip and Micro – jet ) with the same levels of water applied in an experimental vineyard in the region of Felgueiras.

From a local to an international scale: sensory benchmarking of PDO wines. Quincy and Reuilly PDO wines (Sauvignon blanc) as a case study (France)

In a collective marketing strategy, the Protected Designation of Origin (PDO) can be used as a quality indicator. To highlight terroir specificities, it is useful to know how the wines are positioned on the local, national or international market from a sensory point of view. This is especially true for a comparison of varietal wines (e.g. Sauvignon blanc). We focus on the case of two closed Loire Valley PDO (France): Quincy and Reuilly. Three distinct tastings were organized. Firstly, at the local level comparing the 2 PDO (11 and 9 wines, 17 professional assessors); secondly at a regional level adding 3 closed PDO: Menetou-Salon, Sancerre and Pouilly-Fumé (3 wines per PDO, 16 assessors) and thirdly at an international level comparing these 5 PDO with Sauvignon Blanc wines coming from South Africa, New Zealand and Chile (1 to 3 wines per PDO, 19 assessors). All the wines were from the 2019 vintage and were considered to have a traditional elaboration process without contact with oak. A sensory descriptive analysis was performed using an aroma wheel allowing to combine a Check-All-That-Apply methodology, often used in sensory benchmarking, with a hierarchical structuration of the attributes. The aim is to facilitate data acquisition in a professional context without common training, to consider the hierarchical relationships among the attributes during the data analysis and to be able to characterize wines with a large range of sensorial variability. We use univariate, multivariate and clustering analyses. Similarities and differences between Quincy and Reuilly PDO wines and other Sauvignon blanc wines were identified. Specific attributes can distinguish the two PDO and different proximities exist with other local PDO, while clear differences were observed compared to international wines. Our study contributes to propose and discuss a method to do a wine sensory benchmarking highlighting sensory specificities linked to origin.

The geological and geomorphological events that determine the soil functional characters of a terroir

The geology of a region is deemed to be an important component of terroir, as it influences the shape of the landscape and the climate of vineyard. The nature of rock and the geomorphological history of a terroir affect soil physical and chemical composition through a dynamic interplay with the changes of climate, vegetation and other living organisms, as well as with man activities.

EXTRACTIBLE COMPOUNDS FROM MICROAGGLOMERATED CORK STOPPERS

After bottling, the wine continues to evolve during storage. The choice of the stopper is an important factor in this evolution. In addition to the oxygen permeability of the closure, the migration of stopper compounds into the wine can also have an impact on the wine organoleptic properties. Many studies have shown that transfers of volatile compounds from the stoppers into the wine can happen depending on the type of closure used (1). Moreover, when cork-made stoppers are used, the migration of phenolic compounds from the stopper into the wine can also occur (2, 3).