OENO IVAS 2019 banner
IVES 9 IVES Conference Series 9 OENO IVAS 9 OENO IVAS 2019 9 Analytical developments from grape to wine, spirits : omics, chemometrics approaches… 9 Development of a new method to understand headspace aroma distribution and explore the pre-sensory level in perceptive interactions involved in red wine fruity aroma expression

Development of a new method to understand headspace aroma distribution and explore the pre-sensory level in perceptive interactions involved in red wine fruity aroma expression

Abstract

A part, at least, of red wines fruity expression may be explained by perceptive interactions involving particularly various substituted ethyl esters and acetates present at concentration far below their olfactory threshold, specifically thanks to synergistic effects. 

Wine sensory perception is directly linked to the stimulation of the taster at the level of olfactory epithelium by volatiles. These compounds are liberated from the matrix to the atmosphere, and will then be smelt. From a physico-chemical point of view, these volatiles ability to be released may be evaluated by their partition coefficients, which correspond to the volatile concentration ratio between the liquid and gas phase. Our goal is, through these coefficients determination, to assess if volatile matrix composition is able to impact the volatility of some compounds, and then explain sensory perception, i.eto evaluate what is called the pre-sensorial level impact. 

Up to our works, various experimental methods have already been developed to determine gas-liquid partition coefficients, but were not adapted to red wines fruity aromatic expression context. Recently, we have developed a new method coupling the low-pressure and static headspace gas chromatography to a mass spectrometry (LP-HS-GC-MS) in order to calculate simultaneously main esters partition coefficients, and that, at their wine concentrations. 

This method of partition coefficients determination was used to study potential modifications of headspace aroma distribution and was applied to understand various perceptive interactions previously described by our team. Results revealed that pre-sensory effects may explain the effects observed during sensory analysis. For example, the presence of dimethyl sulfide led to an increase of esters partition coefficients, and therefore their concentration in the headspace what was correlated to the enhancement of the blackberry-fruit notes observed concomitantly. Furthermore, addition of malolactic fermentation by-products (as diacetyle, acetic acid, g-butyrolactone and acetoin) led to a decrease of esters partition coefficients, and thus of their concentration in the headspace, what may explain partly the masking effect of these compounds on fruity notes perception.

DOI:

Publication date: June 23, 2020

Issue: OENO IVAS 2019

Type: Article

Authors

Margaux Cameleyre, Georgia Lytra, Sophie Tempère, Jean-Christophe Barbe

Unité de recherche Oenologie, EA 4577, USC 1366 INRA, ISVV, Université de Bordeaux, Bordeaux INP, F33882 Villenave d’Ornon France 

Contact the author

Keywords

Analytical method development, Red wine, Sensory analysis, Perceptive interactions

Tags

IVES Conference Series | OENO IVAS 2019

Citation

Related articles…

Aroma accumulation trends during berry development and selection of grape aroma candidate genes suitable for functional characterization

Grape flavour management in the vineyard requires knowledge of the derivation of individual flavour and aroma characteristics and the effects that different concentrations and interactions between these compounds have on flavour potential.

Sensory evaluation of the effect of anthocyanins on in-mouth perceptions

In this audio recording of the IVES science meeting 2022, Maria Paissoni (Dipartimento di Scienze Agrarie, Forestali e Alimentari, Università degli Studi di Torino, Alba, Italy) speaks about sensory evaluation of the effect of anthocyanins on in-mouth perceptions. This presentation is based on an original article accessible for free on OENO One.

El medio natural de Chile como factor de adaptación de la vid

Chile, junto con Australia, EE.UU., Sudáfrica, Argentina y Nueva Zelanda constituye el grupo de países del nuevo mundo vitivinícola. Todos ellos en conjunto han experimentado en la última década

New varieties descendant from Monastrell with lower sugar and high phenolic content adapted to warm climates

Given that climate change is a continuous process, it is necessary to constantly search for new strategies that help the viticulturist sector to mitigate its consequences. All adaptation strategies will have a greater or lesser effect that in turn will be marked by the times of action. As a long-term action, a genetic breeding program to obtain new varieties descendant from Monastrell has been developed in the Region of Murcia (more specifically, in the IMIDA Research Center) since 1997. In this program, new red varieties have been developed through directed crosses of the Monastrell variety with other varieties such as Cabernet Sauvignon, Tempranillo and Syrah.

Climate change projections to support the transition to climate-smart viticulture

The Earth’s system is undergoing major changes through a wide range of spatial and temporal scales as a response to growing anthropogenic radiative forcing, which is pushing the whole system far beyond its natural variability. Sources of greenhouse gases largely exceed their sinks, thus leading to a strengthened greenhouse effect. More energy is thereby being supplied to the system, with inevitable shifts in climatic patterns and weather regimes. Over the last decades, these modifications have been manifested in the full statistical distributions of the atmospheric variables, with dramatic changes in the frequency and intensity of extremes. Natural hazards, such as severe droughts, floods, forest fires, or heatwaves, are being triggered by extreme atmospheric events worldwide, thus threatening human activities. Viticultculture is not only exposed to changing climates but is also highly vulnerable, as grapevine phenology and physiological development are strongly controlled by atmospheric conditions. Therefore, the assessment of climate change projections for a given region is critical for climate change adaptation and risk reduction in viticulture. By adopting timely and suitable measures, the future sustainability and resiliency of the sector can be fostered. Climate-grapevine chain modelling is an essential tool for better planning and management. However, the accuracy of the resulting projections is limited by many uncertainties that must be duly taken into account when transferring knowledge to stakeholders and decision-makers. Climate-smart viticulture will comprise ensembles of locally tuned strategies, envisioning both adaptation and mitigation, assisted by emerging technologies and decision-support systems.