Terroir 2020 banner
IVES 9 IVES Conference Series 9 Effects of soil characteristics on manganese transfer from soil to vine and wine

Effects of soil characteristics on manganese transfer from soil to vine and wine

Abstract

Aim: In recent times the export of Beaujolais wines has been jeopardised due to a limit of manganese content (Mn) in wine implemented by China (2 mg/L), related to suspicions of potassium permanganate fraud. Nevertheless, soil Mn content may be high in some soil types in Beaujolais. The aim of this study was to improve knowledge of manganese transfer from soil to vine and wine because data on this subject is scarce.

Methods and Results: Recent pedologic mapping of Beaujolais vineyards has enabled a Mn monitoring network to be set up in order to study Mn transfer from soil to vine and wine. Three soil types were considered. Two of the soils can be very high in EDTA Mn: soils from clays with cherts (soil type 7) and former piedmont deposits with leached soils (soil type 8). The third soil, though low in Mn, is the most important and symbolic of Beaujolais: granitic soil. Fifteen plots of Gamay were monitored during 3 years (2015-2017). Besides soil analysis made from pedologic pits, Mn content of petiole, must and wine (red standard wine-making of 40 kg grapes) were determined, as well as grape yield and biomass (pruning weight). Results show that Mn in petioles is better correlated with Mn in wine than Mn in must. Mn content of wine is little in relation with EDTA Mn in soil. It increases when soil pH or cation exchange capacity decreases.

Conclusions: 

This study has shown that Mn concentration in wine can be naturally very high (maximum of 14.6 g/L in this study). Soils with low cation exchange capacity and/or low pH, i.e. soil types 1 and 8, resulted in higher Mn content in wine. Low cation exchange capacity does not allow a great Mn fixation on clay-humic complex and low pH soil solubilizes metal generally and Mn in particular, so it can be taken up by the vine. Mn petiole content is a very good indicator of Mn content in wine. Maceration in red wine-making is also an element to take into consideration.

Significance and Impact of the Study: Mn content in Beaujolais wine can be very high because of soil type, rather than fraud. It is important to highlight this for wine exportations. Mn content in wine can be reduced by correcting the soil pH.

DOI:

Publication date: March 17, 2021

Issue: Terroir 2020

Type: Video

Authors

Jean-Yves Cahurel1, Pierre Martini1*, B. Chatelet2, I. Letessier3

1Institut Français de la Vigne et du Vin, 210 boulevard Vermorel, CS 60320, 69661 Villefranche-sur-Saône, France
2Sicarex Beaujolais, 210 boulevard Vermorel, CS 60320, 69661 Villefranche-sur-Saône Cedex, France
3Sigales, 453 route de Chamrousse, 38410 St Martin d’Uriage, France

Contact the author

Keywords

Manganese, terroir, soil, Beaujolais, vine, wine

Tags

IVES Conference Series | Terroir 2020

Citation

Related articles…

The grapevine single-berry clock, practical tools and outcomes 

The dynamic sequence of physiological events along the three-months of berry development from anthesis to ripe stage has been thoroughly investigated. Most studies were performed on average samples, taking care to crush enough fruits to fairly represent the overall trend of the future harvest. However, phenological stages like 30% caps off (EL25) highlights the asynchronous nature of this population. Consequently, softening, onset of sugar accumulation and coloration were melted by asynchrony in a developmental mumbo jumbo, until their respective timing could be clarified by single berries approaches.

The impact of Saccharomyces yeasts on wine varietal aroma, wine aging and wine longevity

The objective of the present work is to assess yeast effects on the development of wine varietal aroma throughout aging and on wine longevity.

Three independent experiments were carried out; two fermenting semi-synthetic musts fortified with polyphenols and aroma precursors extracted from Tempranillo (1) or Albariño (2) grapes and with synthetic precursors of polyfunctional mercaptans (PFMs), and a third in which a must, mixture of 6 different grape varieties was used. In all cases, fermentations were carried out by different Saccharomyces cerevisiae strains and one S. kudriavzevii, and the obtained wines were further submitted to anoxic accelerated aging to reproduce bottle aging. The volatile profile of the wines was analyzed using several chromatographic procedures, in order to provide a comprehensive evaluation of wine aroma. Aroma compounds analyzed included fermentation volatile metabolites, grape-derived aroma compounds including PFMs, and Strecker aldehydes (SA).

Results revealed that the effects of yeast on wine aroma throughout its self-life extend along three main axes:

1. A direct or indirect action on primary varietal aroma and on its evolution during wine
aging.

2. The direct production of SA during fermentation and/or their delayed formation by producing the required reagents (amino acids + dicarbonyls) for Strecker degradation
during anoxic aging.

3. Producing acids (leucidic, branched acids) precursors to fruity esters. More specifically, and leaving aside the infrequent de novo formation, the action of the different strains of yeast on primary varietal aroma takes four different forms:

1.- Speeding the hydrolysis of aroma precursors, which leads to early aroma formation without changing the amount of aroma formed. In the case of labile molecules, such as linalool, the enhancement of young wine aroma implies a short-living wine. 2.- Metabolizing the aroma precursor, reducing the amounts of aroma formed, which can be of advantage for negative aroma compounds, such as TDN or guaiacol; 3.- Transforming grape components into aroma precursors, increasing the amounts of aroma formed, as for ethyl cinnamate, leucidic acid or vinylphenols; 4.- Forming reactive species such as vinylphenols able to destroy varietal polyfunctional mercaptans.

Overall, it can be concluded that the yeast carrying alcoholic fermentation not only influences fermentative wine aroma but also affects to the wine varietal aroma, to its evolution during aging and to the development of oxidative off-odors

Influence of toasting oak wood on ellagitannin structures

Ellagitannins (ETs) have been reported to be the main phenolic compounds found in oak wood. These compounds, belonging to the hydrolysable tannin class of polyphenols, are esters of hexahydroxydiphenic acid (HHDP) and a polyol, usually glucose or quinic acid. They own their name to their capacity to be hydrolysed and liberate ellagic acid and they have an impact on astringency and bitterness sensation, which is strongly dependant on their structure. The toasting phase is particularly crucial in barrels fabrication and influences wood composition.

Contribution of seeds to red wine phenolic composition

Tannin composition is an important attribute in red wine quality, and it is therefore critical to understand the factors influencing tannin extraction during alcoholic fermentation. Tannins contribute to the mouthfeel of wines, but they also form pigmented polymers...

Discrimination of white wines by Raman spectroscopy coupled with chemometric methods

France is the largest exporter of wine in the world. The export turnover is estimated at 8.7 billion euros in 2017 for 13 million hectoliters sold. This lucrative business pushes scammers to increase the value of some low-end wines by cheating on their appellations, quality or even their origins. These facts lead to losing 1.3 billion euros each year to the European Union’s wine and spirits companies.