qNMR metabolomics a tool for wine authenticity and winemaking processes discrimination

In Spain, the wide diversity of red grapevine varieties represents an advantage when choosing the most suitable one for cultivation based on different climatic conditions, without implying a loss of their enological potential.

Questo simposio organizzato dall ‘Associazione nazionale Città del Vino, che mi onoro di presiedere, è per me motivo di particolare soddisfazione perché porta a compimento parte di un percorso iniziato dall’associazione da alcuni anni e che ha un obiettivo apparentemente semplice: sollecitare gli amministratori delle Città del Vino a perseguire con tenacia, tal­volta anche con la necessaria caparbietà, programmi ed interventi che abbiano al centro, sempre, la qualità della vita dei loro territori.

In winemaking, the use of wood products alternative to barrels, has become a useful tool for the achievement of numerous oenological objectives, including the fast release of desirable volatile and polyphenolic compounds, colour stabilization, and important economic advantages if compared to the traditional barrel production. Among a huge array of variables, the wood format, the vinification protocol, especially the moment of the infusion of the woods and the exposed surface area of the alternative woods are of relevant significance, since they may influence the speed and intensity of the aroma transfer from the wood to the wine defining different sensory profiles.

In interaction with climate and genetic or human factors, the soil is a major component of the viticulture terroir. The mineral composition of the soil influences vine performance and wine sensory attributes. Among the elements that vines take from the soil, nitrogen is the one that has the strongest impact on vine physiology, vigor and grape composition. In addition to its major effect on primary metabolites in berries, nitrogen plays also a decisive role in the secondary metabolism, especially in the production of key compounds for berries quality, like volatile thiols, methoxypyrazines and glutathione (GSH).

Sangiovese is one of the main cultivar in the Italian ampelographic outline and it occupies more than 60% of total vineyard surface in the Tuscany region. It is also well known that the environmental