Macrowine 2021
IVES 9 IVES Conference Series 9 Chemical and sensory diversity of regional Cabernet-Sauvignon wines

Chemical and sensory diversity of regional Cabernet-Sauvignon wines

Abstract

AIM: To investigate chemical and sensory drivers of regional typicity of Cabernet Sauvignon from different geographical regions of Australia.

METHODS: Commercial Cabernet wines (n = 52) from Coonawarra, Margaret River, and Yarra Valley Geographical Indications of Australia, and from Bordeaux, France, were selected for extensive chemical and sensory analysis.1 A range of analytical methods were optimised to quantify a comprehensive array of volatile compounds (> 70) originating from different sources, including grape, fermentation, oak maturation, and ageing. Along with basic chemical data, measurement of non-volatile compounds such as tannins and other secondary metabolites and elements was also undertaken. Multivariate statistical analysis using partial least squares regression was applied to the combined chemical data and the sensory analysis ratings obtained through a trained descriptive analysis panel of the same wines, to determine important compounds driving relevant sensory attributes.

RESULTS: The compound 1,4-cineole, described as ‘mint’ and ‘bay leaf’, was partly responsible for separation of the Cabernet Sauvignon wines from the Australian regions, particularly from Margaret River, whereas compounds such as 4-ethylphenol and 4-ethylguaiacol were linked to the aromas of ‘earthy’ and ‘yeasty’, which drove some of the separation of Bordeaux wines from the others. Varietal thiol, 3-mercapto-1-hexanol, which is mainly associated with Sauvignon Blanc and other white wine varieties, was measured in concentrations above its aroma detection threshold in all of the wines analysed, with similar concentrations present in Bordeaux and Coonawarra wines, and significantly higher concentrations in Margaret River and Yarra Valley wines. Additionally, non-volatiles such as particular elements drove some the separation between the regions; for example strontium was present in highest concentration in the Coonawarra wines and was found at lowest concentration in the Bordeaux wines. Free anthocyanins were also found to differ between Coonawarra and Bordeaux regions, with higher concentration being measured in the latter.

CONCLUSION

In determining the influential drivers of sensory properties of regional Cabernet Sauvignon wines, this study has uncovered various volatile and non-volatile constituents that are associated with specific sensory attributes. This is an important step in being able to define and subsequently help preserve the distinctive characters associated with regional Cabernet Sauvignon wines.

 

DOI:

Publication date: September 7, 2021

Issue: Macrowine 2021

Type: Article

Authors

Dimitra L. Capone 

Australian Research Council Training Centre for Innovative Wine Production, The University of Adelaide,Paul BOSS, CSIRO, and Australian Research Council Training Centre for Innovative Wine Production  Lira SOUZA GONZAGA, Australian Research Council Training Centre for Innovative Wine Production, and The University of Adelaide  Susan E. P. BASTIAN, Australian Research Council Training Centre for Innovative Wine Production, and The University of Adelaide Ruchira RANAWEERA, Department of Wine Science, The University of Adelaide David W. JEFFERY, Australian Research Council Training Centre for Innovative Wine Production, and The University of Adelaide

Contact the author

Keywords

volatile compound, non-volatile compound, sensory analysis, partial least squares regression, regionality, terroir

Citation

Related articles…

Effects of graft quality on growth and grapevine-water relations

Climate change is challenging viticulture worldwide compromising its sustainability due to warmer temperatures and the increased frequency of extreme events. Grafting Vitis vinifera L.

Grapevine xylem embolism resistance spectrum reveals which varieties have a lower mortality risk in a future dry climate

Wine growing regions have recently faced intense and frequent droughts that have led to substantial economical losses, and the maintenance of grapevine productivity under warmer and drier climate will rely notably on planting drought-resistant cultivars. Given that plant growth and yield depend on water transport efficiency and maintenance of photosynthesis, thus on the preservation of the vascular system integrity during drought, a better understanding of drought-related hydraulic traits that have a significant impact on physiological processes is urgently needed. We have worked towards this end by assessing vulnerability to xylem embolism in 30 grapevine commercial varieties encompassing red and white Vitis vinifera varieties, hybrid varieties characterized by a polygenic resistance for powdery and downy mildew, and commonly used rootstocks. These analyses further allowed a global assessment of wine regions with respect to their varietal diversity and resulting vulnerability to stem embolism. Hybrid cultivars displayed the highest vulnerability to embolism, while rootstocks showed the greatest resistance. Significant variability also arose among Vitis vinifera varieties, with Ψ12 and Ψ50 values ranging from -0.4 to -2.7 MPa and from -1.8 to -3.4 MPa, respectively. Cabernet franc, Chardonnay and Ugni blanc featured among the most vulnerable varieties while Pinot noir, Merlot and Cabernet Sauvignon ranked among the most resistant. In consequence, wine regions bearing a significant proportion of vulnerable varieties, such as Poitou-Charentes, France and Marlborough, New Zealand, turned out to be at greater risk under drought. These results highlight that grapevine varieties may not respond equally to warmer and drier conditions, outlining the importance to consider hydraulic traits associated with plant drought tolerance into breeding programmes and modeling simulations of grapevine yield maintenance under severe drought. They finally represent a step forward to advise the wine industry about which varieties and regions would have the lowest risk of drought-induced mortality under climate change.

Grape must quality and mesoclimatic variability in Fruška Gora wine-growing region, Serbia

The Fruška Gora mountain is a traditional wine-growing region in Serbia situated in the Pannonian Basin. Due to such a position, the vicinity of the Danube River and the presence of concave configuration, it is suitable for grape production. This paper provides analyses of spatial variations in meteorological parameters and grape juice quality within Fruška Gora wine region over three consecutive vintages (2018-2020). The examined period can be defined as warm with cool nights during September (AVG 18,9°C; GDD 1918°C; CI 12°CF) and with the presence of mesoclimatic variability. The East part of the study area was somewhat drier and hotter compared to other parts of the region. The analyses of grape must samples (190 in total) of five cultivars (Cabernet-Sauvignon, Merlot, Chardonnay, Sauvignon blanc and Grašac (Welschriesling)) commonly grown across the region (19 sites), were performed using Fourier Transform Infrared Technology (FTIR). Among all cultivars, Sauvignon blanc was harvested first in the East area (DOY=246±5, GDD at harvest=1552±74, 22.2±0.7 °Brix), while the latest harvest was recorded for Cabernet-Sauvignon in the West (DOY=283±5, GDD at harvest=1936±187, 23.4±1.0 °Brix ). Both the red and white cultivars had higher acidity and YAN in the grape must if the vines were grown in the North and East compared to South and West areas. According to PCA analysis, Grašac showed the lowest variation in grape must chemical composition. Thus, the results confirm that Grašac is the most stable cultivar in Fruška Gora. All monitored cultivars reached technological fruit ripeness by the end of the growing season. However, it was difficult to reach full ripeness of red cultivars, mostly beacuse of uncoupling of technolocical and phenolic ripeness. Thus, Cabernet-Sauvignon had higher variations in GDD sums at harvest compared to other cultivars, which probably increased variations in grape must quality.

Modeling the suitability of Pinot Noir in Oregon’s Willamette Valley in a changing climate

Air temperature is the key driver of grapevine phenology and a significant environmental factor impacting yield and quality for a winegrape growing region. In this study the optimal downscaled CMIP5 ensemble for computing thegrowing season average temperature (GST) viticulture climate classification index was determined to spatially compute on a decadal basis predictions of the GST climate index and the grapevine sugar ripeness (GSR) model for Pinot Noir throughout the Willamette Valley (WV) American Viticultural Area (AVA). Forecasts for average temperature and a 220 g/L target sugar concentration level were computed using daily Localized Constructed Analogs (LOCA) downscaled CMIP5 historic and Representative Concentration Pathways (RCP) future climate projections of minimum and maximum daily temperature. We explore spatiotemporal trends of the GST climate classification index and Pinot Noir specific applications of the GSR phenology model for the WV AVA. Spatiotemporal computations of the GST climate index and Pinot Noir specific applications of the GSR model enable the opportunity to explore relationships between their computed values with one intent being to provide updated GST ranges that better align with current temperature-based modeling understanding of Pinot Noir grapevine phenology and the viticultural application of LOCA CMIP5 climate projections for the WV AVA. The Pinot Noir specific applications of the GSR model or the GST index with updated bounds indicate that the percent of the WV AVA area suitable for Pinot Noir production is currently at or near its peak value in the upper 80s to lower 90s of this century.

Grapevine sugar concentration model in the Douro Superior, Portugal

Increasingly warm and dry climate conditions are challenging the viticulture and winemaking sector. Digital technologies and crop modelling bear the promise to provide practical answers to those challenges. As viticultural activities strongly depend on harvest date, its early prediction is particularly important, since the success of winemaking practices largely depends upon this key event, which should be based on an accurate and advanced plan of the annual cycle. Herein, we demonstrate the creation of modelling tools to assess grape ripeness, through sugar concentration monitoring. The study area, the Portuguese Côa valley wine region, represents an important terroir in the “Douro Superior” subregion. Two varieties (cv. Touriga Nacional and Touriga Franca) grown in five locations across the Côa Region were considered. Sugar accumulation in grapes, with concentrations between 170 and 230 g l-1, was used from 2014 to 2020 as an indicator of technological maturity conditioned by meteorological factors. The climatic time series were retrieved from the EU Copernicus Service, while sugar data were collected by a non-profit organization, ADVID, and by Sogrape, a leading wine company. The software for calibrating and validating this model framework was the Phenology Modeling Platform (PMP), version 5.5, using Sigmoid and growing degree-day (GDD) models for predictions. The performance was assessed through two metrics: Roots Mean Square Error (RMSE) and efficiency coefficient (EFF), while validation was undertaken using leave-one-out cross-validation. Our findings demonstrate that sugar content is mainly dependent on temperature and air humidity. The models achieved a performance of 0.65