Macrowine 2021
IVES 9 IVES Conference Series 9 Chemical and sensory diversity of regional Cabernet-Sauvignon wines

Chemical and sensory diversity of regional Cabernet-Sauvignon wines

Abstract

AIM: To investigate chemical and sensory drivers of regional typicity of Cabernet Sauvignon from different geographical regions of Australia.

METHODS: Commercial Cabernet wines (n = 52) from Coonawarra, Margaret River, and Yarra Valley Geographical Indications of Australia, and from Bordeaux, France, were selected for extensive chemical and sensory analysis.1 A range of analytical methods were optimised to quantify a comprehensive array of volatile compounds (> 70) originating from different sources, including grape, fermentation, oak maturation, and ageing. Along with basic chemical data, measurement of non-volatile compounds such as tannins and other secondary metabolites and elements was also undertaken. Multivariate statistical analysis using partial least squares regression was applied to the combined chemical data and the sensory analysis ratings obtained through a trained descriptive analysis panel of the same wines, to determine important compounds driving relevant sensory attributes.

RESULTS: The compound 1,4-cineole, described as ‘mint’ and ‘bay leaf’, was partly responsible for separation of the Cabernet Sauvignon wines from the Australian regions, particularly from Margaret River, whereas compounds such as 4-ethylphenol and 4-ethylguaiacol were linked to the aromas of ‘earthy’ and ‘yeasty’, which drove some of the separation of Bordeaux wines from the others. Varietal thiol, 3-mercapto-1-hexanol, which is mainly associated with Sauvignon Blanc and other white wine varieties, was measured in concentrations above its aroma detection threshold in all of the wines analysed, with similar concentrations present in Bordeaux and Coonawarra wines, and significantly higher concentrations in Margaret River and Yarra Valley wines. Additionally, non-volatiles such as particular elements drove some the separation between the regions; for example strontium was present in highest concentration in the Coonawarra wines and was found at lowest concentration in the Bordeaux wines. Free anthocyanins were also found to differ between Coonawarra and Bordeaux regions, with higher concentration being measured in the latter.

CONCLUSION

In determining the influential drivers of sensory properties of regional Cabernet Sauvignon wines, this study has uncovered various volatile and non-volatile constituents that are associated with specific sensory attributes. This is an important step in being able to define and subsequently help preserve the distinctive characters associated with regional Cabernet Sauvignon wines.

 

DOI:

Publication date: September 7, 2021

Issue: Macrowine 2021

Type: Article

Authors

Dimitra L. Capone 

Australian Research Council Training Centre for Innovative Wine Production, The University of Adelaide,Paul BOSS, CSIRO, and Australian Research Council Training Centre for Innovative Wine Production  Lira SOUZA GONZAGA, Australian Research Council Training Centre for Innovative Wine Production, and The University of Adelaide  Susan E. P. BASTIAN, Australian Research Council Training Centre for Innovative Wine Production, and The University of Adelaide Ruchira RANAWEERA, Department of Wine Science, The University of Adelaide David W. JEFFERY, Australian Research Council Training Centre for Innovative Wine Production, and The University of Adelaide

Contact the author

Keywords

volatile compound, non-volatile compound, sensory analysis, partial least squares regression, regionality, terroir

Citation

Related articles…

Influence of weather and climatic conditions on the viticultural production in Croatia

The research includes an analysis of the impact of weather conditions on phenological development of the vine and grape quality, through monitoring of four experimental cultivars (Chardonnay, Graševina, Merlot and Plavac mali) over two production years. In each experimental vineyard, which were evenly distributed throughout the regions of Slavonia and The Croatian Danube, Croatian Uplands,

Impact of climate change on the viticultural climate of the Protected Designation of Origin “Jumilla” (SE Spain)

Protected Designation of Origin “Jumilla” (PDO Jumilla) is located in the Spanish provinces of Albacete and Murcia, in the South-eastern part of the Iberian Peninsula, where most of the models predict a severe impact of climate change in next decades. PDO Jumilla covers an area of 247,054 hectares, of which more than 22,000 hectares

An analytical framework to site-specifically study climate influence on grapevine involving the functional and Bayesian exploration of farm data time series synchronized using an eGDD thermal index

Climate influence on grapevine physiology is prevalent and this influence is only expected to increase with climate change. Although governed by a general determinism, climate influence on grapevine physiology may present variations according to the terroir. In addition, these site-specific differences are likely to be enhanced when climate influence is studied using farm data. Indeed, farm data integrate additional sources of variation such as a varying representativity of the conditions actually experienced in the field. Nevertheless, there is a real challenge in valuing farm data to enable grape growers to understand their own terroir and consequently adapt their practices to the local conditions. In such a context, this article proposes a framework to site-specifically study climate influence on grapevine physiology using farm data. It focuses on improving the analysis of time series of weather data. The analytical framework includes the synchronization of time series using site-specific thermal indices computed with an original method called Extended Growing Degree Days (eGDD). Synchronized time series are then analyzed using a Bayesian functional Linear regression with Sparse Steps functions (BLiSS) in order to detect site-specific periods of strong climate influence on yield development. The article focuses on temperature and rain influence on grape yield development as a case study. It uses data from three commercial vineyards respectively situated in the Bordeaux region (France), California (USA) and Israel. For all vineyards, common periods of climate influence on yield development were found. They corresponded to already known periods, for example around veraison of the year before harvest. However, the periods differed in their precise timing (e.g. before, around or after veraison), duration and correlation direction with yield. Other periods were found for only one or two vineyards and/or were not referred to in literature, for example during the winter before harvest.

Estimating bulk stomatal conductance of grapevine canopies

In response to changes in their environment, grapevines regulate transpiration using various physiological mechanisms that alter conductance of water through the soil-plant-atmosphere continuum. Expressed as bulk stomatal conductance at the canopy scale, it varies diurnally in response to changes in vapor pressure deficit and net radiation, and over the season to changes in soil water deficits and hydraulic conductivity of both soil and plant. It is necessary to characterize the response of conductance to these variables to better model how vine transpiration also responds to these variables. Furthermore, to be relevant for vineyard-scale modeling, conductance is best characterized using data collected in a vineyard setting. Applying a crop canopy energy flux model developed by Shuttleworth and Wallace, bulk stomatal conductance was estimated using measurements of individual vine sap flow, temperature and humidity within the vine canopy, and estimates of net radiation absorbed by the vine canopy. These measurements were taken on several vines in a non-irrigated vineyard in Bordeaux France, using equipment that did not interfere with ongoing vineyard operations. An inverted Penman-Monteith equation was then used to calculate bulk stomatal conductance on 15-minute intervals from July to mid-September 2020. Time-series plots show significant diurnal variation and seasonal decreases in conductance, with overall values similar to those in the literature. Global sensitivity analysis using non-parametric regression found transpiration flux and vapor pressure deficit to be the most important input variables to the calculation of bulk stomatal conductance, with absorbed net radiation and bulk boundary layer conductance being much less important. Conversely, bulk stomatal conductance was one of the most important inputs when calculating vine transpiration, further emphasizing the need for characterizing its response to environmental changes for use in vineyard water use modeling.

Influence of a spontaneous cover crop on the vineyard and soil erosion under Mediterranean climate

Sixty five % of the agricultural area of the Basque Country located in the DO Ca Rioja corresponds to vineyards. More than 40% of it has an average slope greater than 10%, which makes it sensitive to erosive processes. Furthermore, it is foreseeable that extreme weather events (storms, hail, extreme heat and cold, etc.) will be favored due to climate change. Cover cropping can mitigate this risk, and therefore the objective of this work is to evaluate the impact that a vegetable cover has on the agronomic behavior of the vineyard, the quality of the grape and soil erosion. For this, a trial has been carried out with a Graciano variety vineyard with a slope between 10% -20% during the years 2020 and 2021. Conventional tillage management in the area has been compared (4-6 passes per year of tillage machinery) versus spontaneous vegetation cover management in the vineyard. This implies not tilling and allowing the grass of the land to colonize the range between the lines of vines, controlling their height through 1-3 mowing passes per year, always trying to affect the surface of the land as little as possible. The vegetative growth, yield and quality of the grape and wine was measured. Furthermore, erosion has been measured using Gerlasch boxes. The yield was lower in the second year of the trial in the cover crop treatment, but erosion was significantly reduced.