Red wine oxidation: oxygen consumption kinetics and high resolution uplc-ms analysis

Dans les Charentes, en réponse à une crise de production du vignoble destiné à la production de Cognac, un plan de diversification viticole pour des vins de pays de qualité est mis en place. Il nécessite une connaissance des sols et de leurs caractéristiques viticoles pour orienter le choix des types de vins et adapter l’itinéraire technique de production.

Plant roots fulfil important functions as they are responsible for the acquisition of water and nutrients, for anchorage and stability, for interaction with symbionts and, in some cases, for the storage of carbohydrates. These functions are associated with the Root System Architecture (RSA, i.e. the form and the spatial arrangement of the roots in the soil). The RSA results from several biological processes (elongation, ramification, mortality…) genetically determined but with high structural plasticity.

Several classes of flavonoids, such as anthocyanins, flavonols, flavanols and flavones, undergo a slow H/D exchange on aromatic ring A, leading to full deuteration at positions C(6) and C(8). Within the flavanol class, H-C(6) and H-C(8) of catechin and epicatechin are slowly exchanged in D2O to the corresponding deuterated analogues; even quercetin, a relevant flavonol representative, shows the same behaviour in a D2O/DMSOd6 1:1 solution. Detailed kinetic measurements of these H/D scrambling processes are here reported by exploiting the time-dependent changes of their peak areas in the 1H-NMR spectra taken at different temperatures. A unifying reaction mechanism is also proposed based on our detailed kinetic observations, even taking into account pH and solvent effects. Molecular modelling and QM calculations were also carried out to shed more light on several molecular details of the proposed mechanism.

Une variable composite, dénommée Indice de Site (SI), intégrant les propriétés physiques du sol et le mésoclimat, avait été proposée pour caractériser les terroirs dans le cadre d’une étude des vignobles de Cabernet Sauvignon de Hawke’s Bay en Nouvelle Zélande.

The effects of climate change on viticulture are complex due to interactions among factors and cascading effects.