Macrowine 2021
IVES 9 IVES Conference Series 9 Evaluation of three alternative strategies for the long-term remediation of reductive off-odours in wines

Evaluation of three alternative strategies for the long-term remediation of reductive off-odours in wines

Abstract

Sulfur-like off-odours are a problem caused by the presence of free forms of volatile sulphur compounds (VSCs). H2S is the most frequently found above its odour threshold (1-10 µg/L), followed by methanethiol (MeSH). Recent evidences showed that the usual treatments to eliminate VSCs from wine e.g.: addition of Cu salts or micro-oxygenation only delay the occurrence of reductive off-odours. (Vela et al., 2017, 2018) The present work aims to assess the effectiveness of three alternative remediation strategies on the removal of VSCs:

1.- intensive oxygenation in the presence of a 3-mercaptopropyl-functionalized adsorbent (MPS);

2.- purging out with N2 the wine stored in reductive conditions; and,

3.- incubation with lees. The treatment with MPS consisted in the addition of 1 mM (of -SH groups) of the functionalized adsorbent to two different wines.

They were further saturated with air and, after three days, were centrifuged and analysed. The purge with N2 was applied to two different wines, which had been previously stored during 2 weeks at 50ºC under anoxia. They were purged at 100 mL/min during 60 min and analysed after the treatment. For lees treatment, three different types of lees were studied: fresh active lees, fresh inactive lees and commercial inactivated dry yeast. They were added (3,3 g/L) to wines with reductive off-odour, then they were incubated for 16 weeks at 25ºC, with weekly agitation. After the incubation, the wines were centrifugated to remove the lees. VSCs and redox potential of wines were analysed by GC-SCD (Ontañón et al., 2019) before and after each essay. Additionally, after the treatments an accelerated reductive aging was carried out (incubation at 50ºC under anoxia for 2 weeks) to assess the long-term effect of the treatments. Intensive oxygenation was very effective (-85% H2S BR after treatment and accelerated aging in both cases). Purge treatment was effective only in the short time, removing completely free H2S free and -70% BR-H2S. However, it was not effective in the long-term. The use of inactivated dry yeast was ineffective. The use of active or inactive fresh lees was effective only in some cases. In conclusion, oxidation with MPS provides the most effective treatment; purging was effective only in the short-term; and treatments with lees were not conclusive. Further studies to assess side effects of oxidation with MPS on wine characteristics should be carried out.

DOI:

Publication date: September 13, 2021

Issue: Macrowine 2021

Type: Article

Authors

Diego Sánchez-Gimeno

Diego Sánchez-Gimeno, Laboratory  of Aroma Analsis and Oenology (LAAE), Instituto Agroalimentario de Aragón –IA2-; Departamento de Química Analítica, Facultad de Ciencias, Universidad de Zaragoza, 50009. Zaragoza, Spain,Ignacio Ontañon, LAAE, –IA2- Universidad de Zaragoza Vicente Ferreira, LAAE, –IA2- Universidad de Zaragoza

Contact the author

Keywords

reduction, off-odours, vscs, lees, purge

Citation

Related articles…

Revealing the Barossa zone sub-divisions through sensory and chemical analysis of Shiraz wine

The Barossa zone is arguably one of the most well-recognised wine producing regions in Australia and internationally; known mainly for the production of its distinct Shiraz wines. However, within the broad Barossa geographical delimitation, a variation in terroir can be perceived and is expressed as sensorial and chemical profile differences between wines. This study aimed to explore the sub-division classification across the Barossa region using chemical and sensory measurements. Shiraz grapes from 4 different vintages and different vineyards across the Barossa (2018, n = 69; 2019, n = 72; 2020, n = 79; 2021, n = 64) were harvested and made using a standardised small lot winemaking procedure. The analysis involved a sensory descriptive analysis with a highly trained panel and chemical measurement including basic chemistry (e.g. pH, TA, alcohol content, total SO2), phenolic composition, volatile compounds, metals, proline, and polysaccharides. The datasets were combined and analysed through an unsupervised, clustering analysis. Firstly, each vintage was considered separately to investigate any vintage to vintage variation. The datasets were then combined and analysed as a whole. The number of sub-divisions based on the measurements were identified and characterised with their sensory and chemical profile and some consistencies were seen between the vintages. Preliminary analysis of the sensory results showed that in most vintages, two major groups could be identified characterised with one group showing a fruit-forward profile and another displaying savoury and cooked vegetables characters. The exploration of distinct profiles arising from the Barossa wine producing region will provide producers with valuable information about the regional potential of their wine assisting with tools to increase their target market and reputation. This study will also provide a robust and comprehensive basis to determine the distinctive terroir characteristics which exist within the Barossa wine producing region.

Vineyards and clay minerals: multi-technique analytical approach and correlations with soil properties

Purpose of this research is to quantitatively assess the mineral component of vineyard soils, with particular attention to the mineralogical analysis of clays, which represent an element of high importance in the vineyard culture as well as in general agriculture. An X-ray diffraction (XRD) / thermogravimetric (TG) multi-technique analytical approach was developed, tested on soil samples taken from vineyards around the world. This codified analytical procedure was necessary to obtain precise qualitative and quantitative mineralogical data, globally comparable to distinguish the geopedological identity of the vineyards. Soil samples from vineyards of various locations were analysed, in very different geological conditions. The bulk-rock quantitative phase analysis (QPA) was obtained by the Rietveld method while the detailed composition of the clay-sized fraction was determined by modelling of the oriented X-ray diffraction patterns. The research provided a precise classification of the mineral component of soils, distinguishing the mineral phases of the clays and the so-called mixed-layer clay minerals. We found that the content in mixed layers can be directly correlated with the water retention and the cation exchange capacity ​​of the soil, while the presence of other clayey minerals and phyllosilicates in this research did not affect this CEC parameter, which codes the fertility level of the soils. The study demonstrates that terroir, in particular soils formed in complex or very different geological conditions, can only be effectively interpreted by properly analysing its mineral phases, in particular the mixed-layer clay component. These are characteristic abiotic ecological indicators, which may have specific eco-physiological influences on the plant.

Spiders in vineyards show varying effects of inter-row management and the surrounding landscape

In vineyards, management and the surrounding landscape can have different effects on spiders. In temperate regions management (organic vs. conventional) may have less strong effects than for other crops.

Développement du concept d’Appellation d’Origine Contrôlée et d’Indication Géographique

L’identification des produits par le nom de la ville, de la région, de la province d’origine d’un produit tend aujourd’hui à se développer partout dans le monde et notamment dans le secteur agro-alimentaire, mais aussi dans les secteurs des produits artisanaux.

Clones of 10 Vitis vinifera varieties: degree of inter- and intra-varietal variation and putative mechanisms underlying clonal variability

Context and purpose of the study. Intra-varietal variability for key physiological and oenologically important traits can be exploit in viticulture following the consistently higher environmental pressure driven by climate change.