Macrowine 2021
IVES 9 IVES Conference Series 9 Evaluation of three alternative strategies for the long-term remediation of reductive off-odours in wines

Evaluation of three alternative strategies for the long-term remediation of reductive off-odours in wines

Abstract

Sulfur-like off-odours are a problem caused by the presence of free forms of volatile sulphur compounds (VSCs). H2S is the most frequently found above its odour threshold (1-10 µg/L), followed by methanethiol (MeSH). Recent evidences showed that the usual treatments to eliminate VSCs from wine e.g.: addition of Cu salts or micro-oxygenation only delay the occurrence of reductive off-odours. (Vela et al., 2017, 2018) The present work aims to assess the effectiveness of three alternative remediation strategies on the removal of VSCs:

1.- intensive oxygenation in the presence of a 3-mercaptopropyl-functionalized adsorbent (MPS);

2.- purging out with N2 the wine stored in reductive conditions; and,

3.- incubation with lees. The treatment with MPS consisted in the addition of 1 mM (of -SH groups) of the functionalized adsorbent to two different wines.

They were further saturated with air and, after three days, were centrifuged and analysed. The purge with N2 was applied to two different wines, which had been previously stored during 2 weeks at 50ºC under anoxia. They were purged at 100 mL/min during 60 min and analysed after the treatment. For lees treatment, three different types of lees were studied: fresh active lees, fresh inactive lees and commercial inactivated dry yeast. They were added (3,3 g/L) to wines with reductive off-odour, then they were incubated for 16 weeks at 25ºC, with weekly agitation. After the incubation, the wines were centrifugated to remove the lees. VSCs and redox potential of wines were analysed by GC-SCD (Ontañón et al., 2019) before and after each essay. Additionally, after the treatments an accelerated reductive aging was carried out (incubation at 50ºC under anoxia for 2 weeks) to assess the long-term effect of the treatments. Intensive oxygenation was very effective (-85% H2S BR after treatment and accelerated aging in both cases). Purge treatment was effective only in the short time, removing completely free H2S free and -70% BR-H2S. However, it was not effective in the long-term. The use of inactivated dry yeast was ineffective. The use of active or inactive fresh lees was effective only in some cases. In conclusion, oxidation with MPS provides the most effective treatment; purging was effective only in the short-term; and treatments with lees were not conclusive. Further studies to assess side effects of oxidation with MPS on wine characteristics should be carried out.

DOI:

Publication date: September 13, 2021

Issue: Macrowine 2021

Type: Article

Authors

Diego Sánchez-Gimeno

Diego Sánchez-Gimeno, Laboratory  of Aroma Analsis and Oenology (LAAE), Instituto Agroalimentario de Aragón –IA2-; Departamento de Química Analítica, Facultad de Ciencias, Universidad de Zaragoza, 50009. Zaragoza, Spain,Ignacio Ontañon, LAAE, –IA2- Universidad de Zaragoza Vicente Ferreira, LAAE, –IA2- Universidad de Zaragoza

Contact the author

Keywords

reduction, off-odours, vscs, lees, purge

Citation

Related articles…

Effect of multi-level and multi-scale spectral data source on vineyard state assessment

Currently, the main goal of agriculture is to promote the resilience of agricultural systems in a sustainable way through the improvement of use efficiency of farm resources, increasing crop yield and quality under climate change conditions. This last is expected to drastically modify plant growth, with possible negative effects, especially in arid and semi-arid regions of Europe on the viticultural sector. In this context, the monitoring of spatial behavior of grapevine during the growing season represents an opportunity to improve the plant management, winegrowers’ incomes, and to preserve the environmental health, but it has additional costs for the farmer. Nowadays, UAS equipped with a VIS-NIR multispectral camera (blue, green, red, red-edge, and NIR) represents a good and relatively cheap solution to assess plant status spatial information (by means of a limited set of spectral vegetation indices), representing important support in precision agriculture management during the growing season. While differences between UAS-based multispectral imagery and point-based spectroscopy are well discussed in the literature, their impact on plant status estimation by vegetation indices is not completely investigated in depth. The aim of this study was to assess the performance level of UAS-based multispectral (5 bands across 450-800nm spectral region with a spatial resolution of 5cm) imagery, reconstructed high-resolution satellite (Sentinel-2A) multispectral imagery (13 bands across 400-2500 nm with spatial resolution of <2 m) through Convolutional Neural Network (CNN) approach, and point-based field spectroscopy (collecting 600 wavelengths across 400-1000 nm spectral region with a surface footprint of 1-2 cm) in a plant status estimation application, and then, using Bayesian regularization artificial neural network for leaf chlorophyll content (LCC) and plant water status (LWP) prediction. The test site is a Greco vineyard of southern Italy, where detailed and precise records on soil and atmosphere systems, in-vivo plant monitoring of eco-physiological parameters have been conducted.

Impact of climate change on the viticultural climate of the Protected Designation of Origin “Jumilla” (SE Spain)

Protected Designation of Origin “Jumilla” (PDO Jumilla) is located in the Spanish provinces of Albacete and Murcia, in the South-eastern part of the Iberian Peninsula, where most of the models predict a severe impact of climate change in next decades. PDO Jumilla covers an area of 247,054 hectares, of which more than 22,000 hectares

Low-cost sensors as a support tool to monitor soil-plant heat exchanges in a Mediterranean vineyard

Mediterranean viticulture is increasingly exposed to more frequent extreme conditions such as heat waves. These extreme events co-occur with low soil water content, high air vapor pressure deficit and high solar radiant energy fluxes and result in leaf and berry sunburn, lower yield, and berry quality, which is a major constraint for the sustainability of the sector. Grape growers must find ways to proper and effectively manage heat waves and extreme canopy and berry temperatures. Irrigation to keep soil moisture levels and enable adequate plant turgor, and convective and evaporative cooling emerged as a key tool to overcome this major challenge. The effects of irrigation on soil and plant water status are easily quantifiable but the impact of irrigation on soil and canopy temperature and on heat convection from soil to cluster zone remain less characterized. Therefore, a more detailed quantification of vineyard heat fluxes is highly relevant to better understand and implement strategies to limit the effects of extreme weather events on grapevine leaf and berry physiology and vineyards performance. Low-cost sensor technologies emerge as an opportunity to improve monitoring and support decision making in viticulture. However, validation of low-cost sensors is mandatory for practical applicability. A two-year study was carried in a vineyard in Alentejo, south of Portugal, using low-cost thermal cameras (FLIR One, 80×60 pixels and FLIR C5, 160×120 pixels, 8-14 µm, FLIR systems, USA) and pocket thermohygrometers (Extech RHT30, EXTECH instruments, USA) to monitor grapevine and soil temperatures. Preliminary results show that low-cost cameras can detect severe water stress and support the evaluation of vertical canopy temperature variability, providing information on soil surface temperature. All these thermal parameters can be relevant for soil and crop management and be used in decision support systems.

Phenological characterization of a wide range of Vitis Vinifera varieties

In order to study the impact of climate change on Bordeaux grape varieties and to assess the adaptation capacities of candidates to the grape varieties of this wine region to the new climatic conditions, an experimental block design composed of 52 grape varieties was set up in 2009 at the INRAE Bordeaux Aquitaine center. Among the many parameters studied, the three main phenological stages of the vine (budburst, flowering and veraison) have been closely monitored since 2012. Observations for each year, stage and variety were carried out on four independent replicates. Precocity indices have been calculated from the data obtained over the 2012-2021 period (Barbeau et al. 1998). This work allowed to group the phenological behaviour of the grapevine varieties, not only based on the timing of the subsequent developmental stages, but also on the overall precocity of the cycle and the total length of the cycle between budburst and veraison. Results regarding the variability observed among the different grape varieties for these phenological stages are presented as heat maps.

Current climate change in the Oplenac wine-growing district (Serbia)

Serbian autochthonous vine varieties Smederevka (for white wines) and Prokupac (for rosé and red wines) are the primary representatives of typical characteristics of wines and terroir of numerous wine-growing areas in Serbia. In the past, these varieties were the leading vine varieties, however, as the result of globalization of winemaking and the trend of consumption of wines from widely prevalent vine varieties, they were replaced by introduced international varieties. Smederevka and Prokupac vine varieties are characterized by later time of grape ripening, and relative sensitivity to low temperatures. Climate conditions can be a restrictive factor for production of high-quality grapes and wine and for the spatial spreading of these varieties in hilly continental wine-growing areas.
This paper focuses on the spatial analysis of changes of main climate parameters, in particular, analysis of viticultural bioclimatic indices that were determined for the purposes of viticulture zoning of wine-growing areas in the period 1961-2010, and those same parameters determined for the current, that is, referential climate period (1988-2017). Results of the research, that is, analysis of climate changes indicate that the majority of examined climate parameters in the Oplenac wine-growing district improved from the perspective of Smederevka and Prokupac vine varieties. These studies of climate conditions indicate that changes of analyzed climate parameters, that is, bioclimatic indices will be favorable for cultivation of varieties with later grape ripening times and those more sensitive to low temperatures, such as the autochthonous vine varieties Smederevka and Prokupac, therefore, it is recommended to producers to more actively plant vineyards with these varieties in the territory of the Oplenac wine-growing district.