Macrowine 2021
IVES 9 IVES Conference Series 9 Evaluation of three alternative strategies for the long-term remediation of reductive off-odours in wines

Evaluation of three alternative strategies for the long-term remediation of reductive off-odours in wines

Abstract

Sulfur-like off-odours are a problem caused by the presence of free forms of volatile sulphur compounds (VSCs). H2S is the most frequently found above its odour threshold (1-10 µg/L), followed by methanethiol (MeSH). Recent evidences showed that the usual treatments to eliminate VSCs from wine e.g.: addition of Cu salts or micro-oxygenation only delay the occurrence of reductive off-odours. (Vela et al., 2017, 2018) The present work aims to assess the effectiveness of three alternative remediation strategies on the removal of VSCs:

1.- intensive oxygenation in the presence of a 3-mercaptopropyl-functionalized adsorbent (MPS);

2.- purging out with N2 the wine stored in reductive conditions; and,

3.- incubation with lees. The treatment with MPS consisted in the addition of 1 mM (of -SH groups) of the functionalized adsorbent to two different wines.

They were further saturated with air and, after three days, were centrifuged and analysed. The purge with N2 was applied to two different wines, which had been previously stored during 2 weeks at 50ºC under anoxia. They were purged at 100 mL/min during 60 min and analysed after the treatment. For lees treatment, three different types of lees were studied: fresh active lees, fresh inactive lees and commercial inactivated dry yeast. They were added (3,3 g/L) to wines with reductive off-odour, then they were incubated for 16 weeks at 25ºC, with weekly agitation. After the incubation, the wines were centrifugated to remove the lees. VSCs and redox potential of wines were analysed by GC-SCD (Ontañón et al., 2019) before and after each essay. Additionally, after the treatments an accelerated reductive aging was carried out (incubation at 50ºC under anoxia for 2 weeks) to assess the long-term effect of the treatments. Intensive oxygenation was very effective (-85% H2S BR after treatment and accelerated aging in both cases). Purge treatment was effective only in the short time, removing completely free H2S free and -70% BR-H2S. However, it was not effective in the long-term. The use of inactivated dry yeast was ineffective. The use of active or inactive fresh lees was effective only in some cases. In conclusion, oxidation with MPS provides the most effective treatment; purging was effective only in the short-term; and treatments with lees were not conclusive. Further studies to assess side effects of oxidation with MPS on wine characteristics should be carried out.

DOI:

Publication date: September 13, 2021

Issue: Macrowine 2021

Type: Article

Authors

Diego Sánchez-Gimeno

Diego Sánchez-Gimeno, Laboratory  of Aroma Analsis and Oenology (LAAE), Instituto Agroalimentario de Aragón –IA2-; Departamento de Química Analítica, Facultad de Ciencias, Universidad de Zaragoza, 50009. Zaragoza, Spain,Ignacio Ontañon, LAAE, –IA2- Universidad de Zaragoza Vicente Ferreira, LAAE, –IA2- Universidad de Zaragoza

Contact the author

Keywords

reduction, off-odours, vscs, lees, purge

Citation

Related articles…

Global warming effects on grape growing climate zones within the Rioja Appllation (DOCa Rioja) in north Spain

Aims: The aims of this work were (1) to assess the changes in some of the main bioclimatic indices used for climate viticultural zoning within the Rioja Appellation area in the north of Spain between 1950-2014 (60 years), and (2) to carry out a comprehensive sociological evaluation among grapegrowers and winemakers of this region, to better understand the impact of climate change on their activity, their degree of concern about it and the potential adaptation measures they would be willing to adopt to cope with it in future years.

Mobile device to induce heat-stress on grapevine berries

Studying heat stress response of grapevine berries in the field often relies on weather conditions during the growing season. We constructed a mobile heating device, able to induce controlled heat stress on grapes in vineyards. The heater consisted of six 150 W infrared lamps mounted in a profile frame. Heating power of the lamps could be controlled individually by a control unit consisting of a single board computer and six temperature sensors to reach a pre-set temperature. The heat energy applied to individual berries within a cluster decreases by the squared distance to the heat source, enabling the establishment of temperature profiles within individual clusters. These profiles can be measured by infrared thermography once a steady state has been reached. Radiant flux density received by a berry depending on the distance was calculated based on a view factor and measured lamp surface temperature and resulted to 665 Wm-2 at 7cm. Infrared thermography of the fruit surface was in good agreement with measurements conducted with a thermocouple inserted at epidermis level. In combination with infrared thermography, the presented device offers possibilities for a wide range of applications like phenotyping for heat tolerance in the field to proceed in the understanding of the complex response of plants to heat stress. Sunburn necrosis symptoms were artificially induced with the aid of the device for cv. Bacchus and cv. Sylvaner in the 2020 and 2021 growing season. Threshold temperatures for sunburn induction (LT5030min) were derived from temperature data of single berries and visual sunburn assessment, applying logistic regression. A comparison of threshold temperatures for the occurrence of sunburn necrosis confirmed the higher susceptibility of cv. Bacchus. The lower susceptibility of cv. Sylvaner did not seem to be related to its phenolic composition, rendering a thermoprotective role of berry phenolic compounds unlikely.

The importance of rural extension and advisory services to achieve a sustainable viticulture in a climate change scenario

A healthy and dynamic agricultural sector is an important foundation of rural development, generating strong bonds to other economic sectors.

The informative potential of remote and proximal sensing application on vertical- and overhead-trained vineyards in Northeast Italy

The application of remote and proximal sensing in viticulture have been demonstrated as a fast and efficient method to monitor vegetative and physiological parameters of grapevines. The collection of these parameters could be highly valuable to derive information on associated yield and quality traits in the vineyard. However, to leverage the informative potential of the sensing systems, a series of preliminary evaluations should be carried out to standardize working protocols for the specific features of a winegrowing area (e.g., pedoclimate, topography, cultivar, training system). This work aims at evaluating remote and proximal sensing systems for their performance and suitability to provide information on the vegetative, physiological, yield and qualitative aspects of vines and grapes as a function of different training systems in the Valpolicella wine region (Verona, Italy).

Impact of dried stems in winemaking on Veneto Passito wines

The use of stems during fermentation is generally avoided due to the herbaceous off-odors they can impart to the wine. [1].