Macrowine 2021
IVES 9 IVES Conference Series 9 Influence of the different cork stoppers and sulfur dose in champagne quality

Influence of the different cork stoppers and sulfur dose in champagne quality

Abstract

As is well known, Champagne is a product of the highest quality recognized in the international market. Champagne is a type of sparkling wine made in the Champagne region (France) using the traditional method of champenoise. Aging in the bottle is the final stage before being consumed, and it is considered a time of maturation in which many chemical and sensory changes occur (1). In addition, the stoppers have a very important influence on the quality of the product during bottle aging (2). Today there are different types of corks with different types of oxygen permeabilities (3). This oxygen transfer rate (OTR) through the cork can cause changes in the color, in the aromatic composition and in the organoleptic sensations of the Champagne, causing a loss of its quality (3, 4). For all these reasons, the main objective of this work is to evaluate the effect of different types of cork stoppers in Champagne with different doses of sulfur (added in bottling) for a year. To carry out the study, five types of corks (C1, C2, C3, C4 and C5) with increasing OTRs values and the control with sheet metal closure (Control), and three different doses of sulfur (0, 10 and 20 mg/L) were used. Of all of them, the basic parameters, color and Cielab coordinates, CO2 pressure, aromatic composition (fermentative, oxidative and reduction aromas), and sensory analysis were analyzed at each of the four sampling points. The analysis times were after bottling (T0) and after 3, 6, 12 months of aging in the bottle (T3, T6, T12). The results showed that the parameter ‘time’ was the main factor in producing differences between the samples, followed by the doses of sulfur and type of cork. In general, the basic parameters of champagne did not show significant differences except for total sulfur content. In general, the color, the CO2 parameters and especially the aromatic composition changed over time, showing the main changes after 12 months in the bottle. The fermentation aromas were decreasing, and the oxidation and reduction aromas were increasing over time. The samples with the highest dose of sulfur (20 mg/L) were less evolved, however they showed greater reductions. In addition, C5 and C3 corks with were the corks that best preserved Champagne in relation to the preservation of fermentative aromas, and in achieving a better balance between oxidation-reduction conditions, after 12 months of aging. However, the C2 was the cork that had the worst preservation of fermentative aromas and the greatest oxidation caused the Champagne. Finally, the sensory analysis on time 12 months corroborated analytics, the best valued Champagne being those closed with C3 and C5 corks, and the worst with C2. Therefore, a good choice about the type of cork and the dose of sulfur in bottling can prolong its optimal moment of consumption in time, while preserving its quality.

DOI:

Publication date: September 14, 2021

Issue: Macrowine 2021

Type: Article

Authors

Ana Maria Mislata 

1. VITEC – Centre Tecnològic del Vi, Ctra. Porrera Km 1, 43730 Falset (Tarragona), Spain 2. Instrumental Sensometry (i-Sens), Department of Analytical Chemistry and Organic  Chemistry, Campus Sescelades, Universitat Rovira i Virgili, Tarragona, 43007, Spain ,Michelle Rodríguez 2; Christophe Loisel 3; Miquel Puxeu 1; Enric Nart 1; Sergi De Lamo 1; Montserrat Mestres 2 and Raúl Ferrer-Gallego 1  1. VITEC – Centre Tecnològic del Vi, Ctra. Porrera Km.1, 43730 Falset (Tarragona), Spain 2. Instrumental Sensometry (i-Sens), Department of Analytical Chemistry and Organic  Chemistry, Campus Sescelades, Universitat Rovira i Virgili, Tarragona, 43007, Spain 3. DIAM Bouchage SAS-Espace Tech Ulrich, 66400 Ceret, France

Contact the author

Keywords

champagne, corks, sulfurous, otr, color, aromatic compounds, sensory analysis

Citation

Related articles…

Vineyards and clay minerals: multi-technique analytical approach and correlations with soil properties

Purpose of this research is to quantitatively assess the mineral component of vineyard soils, with particular attention to the mineralogical analysis of clays, which represent an element of high importance in the vineyard culture as well as in general agriculture. An X-ray diffraction (XRD) / thermogravimetric (TG) multi-technique analytical approach was developed, tested on soil samples taken from vineyards around the world. This codified analytical procedure was necessary to obtain precise qualitative and quantitative mineralogical data, globally comparable to distinguish the geopedological identity of the vineyards. Soil samples from vineyards of various locations were analysed, in very different geological conditions. The bulk-rock quantitative phase analysis (QPA) was obtained by the Rietveld method while the detailed composition of the clay-sized fraction was determined by modelling of the oriented X-ray diffraction patterns. The research provided a precise classification of the mineral component of soils, distinguishing the mineral phases of the clays and the so-called mixed-layer clay minerals. We found that the content in mixed layers can be directly correlated with the water retention and the cation exchange capacity ​​of the soil, while the presence of other clayey minerals and phyllosilicates in this research did not affect this CEC parameter, which codes the fertility level of the soils. The study demonstrates that terroir, in particular soils formed in complex or very different geological conditions, can only be effectively interpreted by properly analysing its mineral phases, in particular the mixed-layer clay component. These are characteristic abiotic ecological indicators, which may have specific eco-physiological influences on the plant.

Underpinning terroir with data: rethinking the zoning paradigm

Agriculture, natural resource management and the production and sale of products such as wine are increasingly data-driven activities. Thus, the use of remote and proximal crop and soil sensors to aid management decisions is becoming commonplace and ‘Agtech’ is proliferating commercially; mapping, underpinned by geographical information systems and complex methods of spatial analysis, is widely used. Likewise, the chemical and sensory analysis of wines draws on multivariate statistics; the efficient winery intake of grapes, subsequent production of wines and their delivery to markets relies on logistics; whilst the sales and marketing of wines is increasingly driven by artificial intelligence linked to the recorded purchasing behaviour of consumers. In brief, there is data everywhere!

Opinions will vary on whether these developments are a good thing. Those concerned with the ‘mystique’ of wine, or the historical aspects of terroir and its preservation, may find them confronting. In contrast, they offer an opportunity to those interested in the biophysical elements of terroir, and efforts aimed at better understanding how these impact on vineyard performance and the sensory attributes of resultant wines. At the previous Terroir Congress, we demonstrated the potential of analytical methods used at the within-vineyard scale in the development of Precision Viticulture, in contributing to a quantitative understanding of regional terroir. For this conference, we take this approach forward with examples from contrasting locations in both the northern and southern hemispheres. We show how, by focussing on the vineyards within winegrowing regions, as opposed to all of the land within those regions, we might move towards a more robust terroir zoning than one derived from a mixture of history, thematic mapping, heuristics and the whims of marketers. Aside from providing improved understanding by underpinning terroir with data, such methods should also promote improved management of the entire wine value chain.

Evolution of the amino acids content through grape ripening: Effect of foliar application of methyl jasmonate with or without urea

The parameters that determine the grape quality, and therefore the optimal harvest time, suffer variations during berry ripening, related to climate change, with the widely known problem of the gap between technological and phenolic maturities. However, there are few studies about its incidence on grape nitrogen composition. For this reason, the use of an elicitor, methyl jasmonate (MeJ), alone or with urea, is proposed as a tool to reduce climatic decoupling, allowing to establish the harvest time in order to achieve the optimum grape quality. The aim was to study the effect of MeJ and MeJ+Urea foliar applications on the evolution of Tempranillo amino acids content throughout the grape maturation. Three treatments were foliarly applied, at veraison and 7 days later: control (water), MeJ (10 mM) and MeJ+Urea (10 mM+6 kg N/ha). Grape samples were taken at five stages of maturation: day before the first and second applications, 15 days after the second application (pre-harvest), harvest day, and 15 days after harvest (post-harvest). The amino acids analysis of the samples was carried out by HPLC. Results showed that the evolution of amino acids was similar regardless of the treatment; however, foliar applications influenced the nitrogen compounds content, i.e., there was no qualitative effect but quantitative one. Most of the amino acids reached their maximum concentration in pre-harvest, being higher in grapes from the treatments than in the control. In general, no differences in grape amino acids content were observed between MeJ and MeJ+Urea treatments. Foliar applications with MeJ and MeJ+Urea enhanced the grape amino acids content, without affecting their profile, helping to optimize their quality and allowing to establish a more complete grape ripening standard. Therefore, MeJ and MeJ+Urea foliar applications can be a simple agronomic practice, which has shown promising results in order to enhance the grape quality.

Local ancient grapevine cultivars to face future viticulture

Among the different strategies to cope with the negative impacts of climate change on viticulture, the exploitation of genetic diversity is one of the most promising to adapt to new conditions and maintain wine production and quality. One of the biggest concerns in the context of climate change is to improve water use efficiency (WUE). In this way, the use of genotypes that present a better response to drought and high WUE is a key issue. In this work, physiological performance analysis was conducted to compare the water deficit stress (WDS) responses of local and widespread grapevines cultivars. Leaf gas exchange, water use efficiency (WUE) at different levels (leaf and long-term WUE (∆13C)), leaf osmotic adjustment and other water relations parameters were determined in plants under well-watered and WDS conditions alongside assessment of the levels of foliar hormones concentrations. Results denote that local cultivars displayed better physiological performance under WDS as compared to the widely-distributed ones. he results corroborate the hypothesis that better stomatal control allows increasing leaf WUE under drought as occurred in the local Callet cv.; but the minority local cultivar Escursac cv. showed high WUE under both treatments. In this case, high WUE can be related to maintaining higher photosynthetic activity under drought. The different mechanisms underlying the better performance under WDS and high WUE of minority local cultivars are discussed.

The interplay between grape ripening and weather anomalies – A modeling exercise

Current climate change is increasing inter- and intra-annual variability in atmospheric conditions leading to grapevine phenological shifts as well altered grape ripening and composition at ripeness. This study aims to (i) detect weather anomalies within a long-term time series, (ii) model grape ripening revealing altered traits in time to target specific ripeness thresholds for four Vitis vinifera cultivars, and (iii) establish empirical relationships between ripening and weather anomalies with forecasting purposes. The Day of the Year (DOY) to reach specific grape ripeness targets was determined from time series of sugar concentrations, total acidity and pH collected from a private company in the period 2009-2021 in North-Eastern Italy. Non-linear models for the DOY to reach the specified ripeness thresholds were assessed for model efficiency (EF) and error of prediction (RMSE) in four grapevine cultivars (Merlot, Cabernet Sauvignon, Glera and Garganega). For each vintage and cultivar, advances or delays in DOY to target specified ripeness thresholds were assessed with respect to the average ripening dynamics. Long-term meteorological series monitored at ground weather station by means of hourly air temperature and rainfall data were analyzed. Climate statistics were obtained and for each time period (month, bimester, quarter and year) weather anomalies were identified. A linear regression analysis was performed to assess a possible correlation that may exist between ripening and weather anomalies. For each cultivar, ripeness advances or delays expressed in number of days to target the specific ripening threshold were assessed in relation to registered weather anomalies and the specific reference time period in the vintage. Precipitation of the warmest month and spring quarter are key to understanding the effect of climate change on sugar ripeness. Minimum temperatures of May-June bimester and maximum temperatures of spring quarter best correlate with altered total acidity evolution and pH increment during the ripening process, respectively.