Macrowine 2021
IVES 9 IVES Conference Series 9 Characterization of tannins and prevention of light-struck taste: the enofotoshield project

Characterization of tannins and prevention of light-struck taste: the enofotoshield project

Abstract

AIM: Hydrolysable tannins resulted effective against the formation of light-struck taste (LST) in model wine [1]. The first activity of Enofotoshield project is to evaluate the effectiveness of tannins in limiting the LST in white wine. Therefore, tannins of different origin were characterized in terms of their chemical composition as well as their ability in preventing the appearance of LST that was firstly screened in model wine.

METHODS: Fifteen commercial tannin-based formulas of different origin (grape skin and seeds, tea, oak, chestnut, cherry, acacia, quebracho, tara, nut gall, lemon) and extraction treatment (e.g. water, solvent) were considered. They were characterized in terms of total phenolics (Folin-Ciocalteau index and 280 nm; TPI), antioxidant capacity (DPPH assay), relative amounts of oxidized phenols, ellagitannins and proanthocyanidins content, the latter two for hydrolysable and condensed tannins, respectively. The oxygen consumption rate was assessed for all the formulas with and without sulfur dioxide. The impact on astringency and bitterness was also evaluated. The effectiveness against the appearance of LST was assessed in model wine solution added with the two actors of LST, riboflavin and methionine (Met), in both oxic and anoxic conditions.

RESULTS: The tannin-based formulas showed a wide content of phenolics ranging from 462±28 to 1019±57 mg gallic acid/g powder for cherry tannins and gall nut tannins, respectively. Similarly, the antioxidant capacity strongly varied from 3.70±0.23 mM Trolox/g powder for grape skin tannins to 10.94±1.28 mM Trolox/g powder for nut gall tannins. Considering the ratio among the antioxidant capacity and TPI, tara tannins showed the greatest value. The oxygen consumption rate also differed and it was the lowest and the highest in the presence of and nut gall and chestnut tannins, respectively, when sulfur dioxide was not added. None of them affected both bitterness and astringency in white wine (up to 80 mg/L). Met decreased in all the conditions tested due to the light exposure and an increase of Met sulfoxide, the major compound deriving from Met oxidation [2], was observed. Sniffing trials showed the ability of most of these formulas in preventing the LST; some of the tested tannin preparations revealed only little differences in LST perception between oxic and anoxic conditions.

CONCLUSIONS

Tannins can effectively prevent the appearance of LST. The tannin-based formulas with the best performances in terms of LST prevention and lowest impact on wine properties will be employed at bottling for the wine production at industrial scale.

DOI:

Publication date: September 14, 2021

Issue: Macrowine 2021

Type: Article

Authors

Daniela Fracassetti

Department of Food, Environmental and Nutritional Sciences (DeFENS), Università degli Studi di Milano, Via G. Celoria 2, 20133 Milan, Italy,Natalia, MESSINA, Department of Food, Environmental and Nutritional Sciences (DeFENS), Università degli Studi di Milano  Rebecca, BODON, Department of Food, Environmental and Nutritional Sciences (DeFENS), Università degli Studi di Milano Alberto, SALIGARI, Department of Food, Environmental and Nutritional Sciences (DeFENS), Università degli Studi di Milano Antonio, TIRELLI, Department of Food, Environmental and Nutritional Sciences (DeFENS), Università degli Studi di Milano

Contact the author

Keywords

methionine, oenological tannins, off-flavors, oxygen, phenols, riboflavin

Citation

Related articles…

Under-vine management effects on grapevine production, soil properties and plant communities in South Australia

Under-vine (UV) management has traditionally consisted of synthetic herbicide use to limit competition between weeds and grapevines. With growing global interest towards non-synthetic chemical use, this study aimed to capture the effects of alternative UV management at two commercial Shiraz vineyards in South Australia, where the sole management variables were UV management since 2016. In adjacent treatment blocks, cultivation (CU) was compared to spontaneous vegetation (SV) in McLaren Vale (MV), and herbicide was compared to SV in Eden Valley (EV). Soil water infiltration rates were slower and grapevine stem water potential was lower in CU compared to SV in MV, with the latter having a plant community dominated by soursob (Oxalis pes-caprae) during winter; while in EV, there was little separation between the treatments. Yields were affected at both sites, with SV being higher in MV and HE being higher in EV. In MV, the only effect on grape must was a lower 13C:12C isotope ratio in CU, indicating greater grapevine water stress. In the grape must at EV, SV had higher total soluble solids, total phenolics, anthocyanins, and yeast available nitrogen; and lower pH and titratable acidity. Pruning weights were not affected by the treatments in MV, while they were higher in HE at EV. Assessments revealed that the differing soil types at the two sites were likely the main determinants of the opposing production outcomes associated with UV management. In the silty loam soil of MV, the higher yields in SV were likely due to more plant-available water, as a potential result of the continuous soil bio-pores formed by winter UV vegetation. Conversely, in the loamy sand soils of EV with a lower cation exchange capacity, the lower yields and pruning weights in SV suggest the UV vegetation competed significantly with the grapevines for available water and nutrients.

Short-term relationships between climate and grapevine trunk diseases in southern French vineyards

[lwp_divi_breadcrumbs home_text="IVES" use_before_icon="on" before_icon="||divi||400" module_id="publication-ariane" _builder_version="4.19.4" _module_preset="default" module_text_align="center" module_font_size="16px" text_orientation="center"...

Influence of climatic conditions on grape composition of Tempranillo in La Mancha DO (Spain)

The aim of this work was to analyze the variability in grape composition of the Tempranillo cultivar related to climatic conditions, in La Mancha Designation of Origin. Grape composition (sugar content, total acidity, pH, malic acid, and total and extractable anthocyanins) recorded during ripening, were analysed for the period 2000-2019. The weather conditions at daily time scale, recorded during the same period, were also evaluated. The relationships between grape parameters with climatic variables related to temperature and to water deficits, referring different periods between phenological events along the growing cycle, were evaluated using regression analysis. High variability in grape composition was observed in the period analysed. Total acidity varied between 3.7 and 7.3 gL-1 while malic acid varied between 1.2 and 4 gL-1. The extractable anthocyanins ranged between 526 and 972 mgL-1, and total anthocyanins ranged between 922 and 1388 mgL-1, being the lowest values recorded in the hottest year (2017). Total acidity decreased 0.77 gL-1 for an increase of 100 GDD, while malic acid decrease in 0.42 gL-1 for the same GDD increase, being the period between veraison and harvest the one that seemed to have higher influence on acidity. In addition, it was confirmed that increasing water deficits decreased acidity. Total and extractable anthocyanins increased in about 210 and 105 mgL-1, respectively, with an increase of 100 GDD from veraison to harvest, and the increase in water deficits favour the increase of anthocyanins, both total and extractable anthocyanins. Total and extractable anthocyanins concentration increased in 35 and 22 mgL-1 per an increase of 10 mm in the water deficit. These results can be of interest to understand the potential changes that grapes composition may suffer under future warmer climates.

The plantation frame as a measure of adaptation to climate change

The mechanization of vineyard work originally led to a reduction in planting densities due to the lack of machinery adapted to the vineyard. The current availability of specific machinery makes it possible to establish higher planting densities. In this work, three planting densities (1.40×0.80 m, 1.80×1 m and 2.20×1.20 m, corresponding to 8928, 5555 and 3787 plants/ha respectively) were studied with four varieties autochthonous of Galicia (northwestern Spain): Albariño and Treixadura (white), Sousón and Mencía (red). The vines were trained in a vertical shoot positioning system using a single Royat cordon, and pruned to spurs with two buds each. Agronomic data (yield, pruning wood weight, Ravaz index) and oenological data in must were collected. The higher planting density (1.40×0.80 m) had no significant effect on grape yield per vine in white varieties, although production per hectare was much higher due to the greater number of plants. In red varieties, this planting density resulted in a significantly lower production per vine, compensated by the greater number of plants. In addition, it significantly reduced the Brix degree in the must of the Albariño, Treixadura and Sousón varieties, and increased the total acidity in the latter two and Mencía. It also caused an increase in extractable and total anthocyanins and IPT in red grapes. The effects of high planting density on grapes are of great interest for the adaptation of varieties in the context of climate change. In the future, it could be advisable to modify the limits imposed by the appellations of origin on the planting density of these varieties in order to obtain more balanced wines.

Adaptation to soil and climate through the choice of plant material

Choosing the rootstock, the scion variety and the training system best suited to the local soil and climate are the key elements for an economically sustainable production of wine. The choice of the rootstock/scion variety best adapted to the characteristics of the soil is essential but, by changing climatic conditions, ongoing climate change disrupts the fine-tuned local equilibrium. Higher temperatures induce shifts in developmental stages, with on the one hand increasing fears of spring frost damages and, on the other hand, ripening during the warmest periods in summer. Expected higher water demand and longer and more frequent drought events are also major concerns. The genetic control of the phenotypes, by genomic information but also by the epigenetic control of gene expression, offers a lot of opportunities for adapting the plant material to the future. For complex traits, genomic selection is also a promising method for predicting phenotypes. However, ecophysiological modelling is necessary to better anticipate the phenotypes in unexplored climatic conditions Genetic approaches applied on parameters of ecophysiological models rather than raw observed data are more than ever the basis for finding, or building, the ideal varieties of the future.