The effects of antioxidants and gas sparging on New Zealand white wines

Abstract

AIM: This study aims to investigate the effects of different conditions of grape processing or fermentation on the aroma profile of New Zealand white wines.

METHODS: Experiments have been designed to study how glutathione and ascorbic acid impact on the aroma compounds of Sauvignon Blanc and Pinot Gris wines. Attention was also paid to the effectiveness of two gas sparging regimes (oxygen and nitrogen), applied during fermentation, on the removal of reductive sulfur aromas in Sauvignon Blanc wines.

RESULTS: Additions of glutathione to the grape juices increased the levels of polyfunctional mercaptans in the finished wines. The lowest levels of polyfunctional mercaptan compounds were found in the wines with little supplementary antioxidants added. A high level of the joint combination of ascorbic acid and glutathione provided the wines with even higher production of polyfunctional mercaptans. Increasing the amount of elemental sulfur addition to the grape must before pressing led to an increase in the formation of several thiol compounds, including some unwanted reductive compounds. Few changes were observed in the concentrations of aroma compounds when the juices were sparged with nitrogen during fermentation. Additions of oxygen during fermentation led to some decrease in the concentration of polyfunctional mercaptans for the 10 mg/L sulfur additions, but did not significantly remove reductive aroma compounds. 

CONCLUSIONS

This study has demonstrated a positive benefit to the formation of polyfunctional mercaptans with passionfruit/ tropical aromas, from additions of glutathione and ascorbic acid at harvest. The oxygen or nitrogen applied during fermentation did not result in the removal of undesirable reductive aroma compounds. Further trials are needed to examine increased oxygen as well as nitrogen dosages during fermentation, and their effects on reductive compounds.

DOI:

Publication date: September 15, 2021

Issue: Macrowine 2021

Type: Article

Authors

Xiaotong Lyu 

School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland, New Zealand,Leandro Dias ARAUJO, School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland, New Zealand Siew-Young QUEK, School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland, New Zealand Wessel. J. DU TOIT, Institute for Grape and Wine Sciences/Department of Viticulture and Oenology, Stellenbosch University, Private Bag X1, Matieland 7602, South Africa Paul. A. KILMARTIN*, School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland, New Zealand

Contact the author

Keywords

sauvignon blanc, pinot gris, antioxidants, glutathione, ascorbic acid, reductive compounds, oxygen, nitrogen, polyfunctional mercaptans

Citation

Related articles…

Application of organic carbon status indicators on vineyard soils: the case study of DOC Piave (Veneto region, Italy)

According to the Kyoto Protocol objectives, it’s necessary to identify alternative carbon dioxide sinks, and vineyard soils could be a significant opportunity.

An overview of geological influences on South African vineyards

The role of soils and bedrock geology has long been acknowledged as a fundamental component of terroir. In South Africa the influence of geology is misunderstood and some important geological components will be highlighted in this paper.

Wine odors: chemicals, physicochemical and perceptive processes involved in their perception

The odors of wines are diverse, complex and dynamic and much research has been devoted to the understanding of their chemical bases. However, while the “basic” chemical part of the problem, namely the identity of the chemicals responsible for the different odor nuances, was satisfactorily solved years ago, there are some relevant questions precluding a clear understanding. These questions are related to the physicochemical interactions determining the effective volatilities of the odorants and, particularly, to the perceptual interactions between different odor molecules affecting in different ways to the final sensory outputs.

First identification of a glycosylated fraction involved in mushroom-off-flavor in grapes: influence of B. cinerea, powdery mildew and C. subabruptus

An organoleptic defect, called fresh mushrooms off-flavor, appeared in wines and spirits since the 2000’s. Numerous researches demonstrated that octen-3-one, octan-3-ol and octen-3-ol

Starmerella bacillaris grape treatment as a sustainable approach to manage Botrytis cinerea during the withering process

Growing concerns over the environmental and health risks posed by chemical pesticides have highlighted the need to reduce their use in the agri-food sector.