Terroir 2020 banner
IVES 9 IVES Conference Series 9 Characterising the chemical typicality of regional Cabernet Sauvignon wines

Characterising the chemical typicality of regional Cabernet Sauvignon wines

Abstract

Aim: To define the uniqueness of Australian Cabernet Sauvignon wines by evaluation of the chemical composition (volatile aroma and non-volatile constituents) that may drive regional typicity, and to correlate this with comprehensive sensory analysis data to identify the most important compounds driving relevant sensory attributes.

Methods and Results: A range of specialised analytical methods have been optimised to quantify more than 70 volatile aroma compounds in Cabernet Sauvignon wine. These methods examine a diverse array of metabolites that originate from the grape, fermentation, maturation and oak maturation. Examination of a variety of non-volatile compounds such as tannins, basic chemistry and non-volatile secondary metabolites were also undertaken. These analytes were quantified in 2015 commercial Cabernet Sauvignon wines (n = 52) originating from Coonawarra, Margaret River, Yarra Valley and Bordeaux. Multivariate statistical analysis of chemical datasets and sensory ratings obtained by a trained descriptive analysis panel identified compounds driving aroma attributes that distinguished wines from the different regions. Some compounds, such as dimethyl sulfide, which arises from a grape amino acid and is described as ‘black currant or olive’ at low concentration and ‘canned vegetables’ at high concentration, were not statistically different amongst regions. In contrast, compounds such as 1,4-cineole (‘mint’ and ‘bay leaf’ aroma), 3-isobutyl-2-methoxypyrazine (‘green capsicum’ aroma) and 4-ethylphenol (‘earthy’ and ‘band-aid’ aroma) were able to differentiate the wines.

Conclusions: 

For the first time, this work has revealed various wine chemical constituents, both volatile and non-volatile, that have been linked with results from comprehensive sensory analysis to determine the important drivers of regional typicity of Australian Cabernet Sauvignon wines. Identifying these candidates will lead us to the next step of identifying which viticultural and/or winemaking practices can influence these compounds to meet target styles for wines of provenance.

Significance and Impact of the Study: Identifying the chemical markers that characterise Cabernet Sauvignon regional typicity will lead Australian producers one step closer to having the tools to preserve the ‘uniqueness’ of their regional wines. A greater understanding of chemical drivers of wine sensory traits will keep the industry at the forefront of the field internationally and will provide producers with knowledge that can be used for promoting their wines and enhancing sales.

DOI:

Publication date: March 17, 2021

Issue: Terroir 2020

Type: Video

Authors

Dimitra L. Capone1,2*, Paul Boss3, Lira Souza Gonzaga1,2, Susan E.P. Bastian1,2, David W. Jeffery1,2

1Australian Research Council Training Centre for Innovative Wine Production, Australia
2Department of Wine Science, The University of Adelaide, PMB 1, Glen Osmond, South Australia 5064, Australia
3CSIRO, Locked Bag 2, Glen Osmond, South Australia 5064, Australia

Contact the author

Keywords

Regional typicity, chemical markers, wine sensory traits, Cabernet Sauvignon

Tags

IVES Conference Series | Terroir 2020

Citation

Related articles…

The impact of sustainable management regimes on amino acid profiles in grape juice, grape skin flavonoids, and hydroxycinnamic acids

One of the biggest challenges of agriculture today is maintaining food safety and food quality while providing ecosystem services such as biodiversity conservation, pest and disease control, ensuring water quality and supply, and climate regulation. Organic farming was shown to promote biodiversity and carbon sequestration, and is therefore seen as one possibility of environmentally friendly production. Consumers expect organically grown crops to be free from chemical pesticides and mineral fertilizers and often presume that the quality of organically grown crops is different or higher compared to conventionally grown crops. Integrated, organic, and biodynamic viticulture were compared in a replicated field trial in Geisenheim, Germany (Vitis vinifera L. cv. Riesling). Amino acid profiles in juice, grape skin flavonoids, and hydroxycinnamic acids were monitored over three consecutive seasons beginning 7 years after conversion to organic and biodynamic viticulture, respectively. In addition, parameters such as soil nutrient status, yield, vigor, canopy temperature, and water stress were monitored to draw conclusions on reasons for the observed changes. Results revealed that the different sustainable management regimes highly differed in their amino acid profiles in juice and also in their skin flavonol content, whereas differences in the flavanol and hydroxycinnamic acid content were less pronounced. It is very likely that differences in nutrient status and yield determined amino acid profiles in juice, although all three systems showed similar amounts of mineralized nitrogen in the soil. Canopy structure and temperature in the bunch zone did not differ among treatments and therefore cannot account for the observed differences in favonols. A different light exposure of the bunches in the respective systems due to differences in vigor together with differences in berry size and a different water status of the vines might rather be responsible for the increase in flavonol content under organic and biodynamic viticulture.

Estimating bulk stomatal conductance of grapevine canopies

In response to changes in their environment, grapevines regulate transpiration using various physiological mechanisms that alter conductance of water through the soil-plant-atmosphere continuum. Expressed as bulk stomatal conductance at the canopy scale, it varies diurnally in response to changes in vapor pressure deficit and net radiation, and over the season to changes in soil water deficits and hydraulic conductivity of both soil and plant. It is necessary to characterize the response of conductance to these variables to better model how vine transpiration also responds to these variables. Furthermore, to be relevant for vineyard-scale modeling, conductance is best characterized using data collected in a vineyard setting. Applying a crop canopy energy flux model developed by Shuttleworth and Wallace, bulk stomatal conductance was estimated using measurements of individual vine sap flow, temperature and humidity within the vine canopy, and estimates of net radiation absorbed by the vine canopy. These measurements were taken on several vines in a non-irrigated vineyard in Bordeaux France, using equipment that did not interfere with ongoing vineyard operations. An inverted Penman-Monteith equation was then used to calculate bulk stomatal conductance on 15-minute intervals from July to mid-September 2020. Time-series plots show significant diurnal variation and seasonal decreases in conductance, with overall values similar to those in the literature. Global sensitivity analysis using non-parametric regression found transpiration flux and vapor pressure deficit to be the most important input variables to the calculation of bulk stomatal conductance, with absorbed net radiation and bulk boundary layer conductance being much less important. Conversely, bulk stomatal conductance was one of the most important inputs when calculating vine transpiration, further emphasizing the need for characterizing its response to environmental changes for use in vineyard water use modeling.

Adaptation to soil and climate through the choice of plant material

Choosing the rootstock, the scion variety and the training system best suited to the local soil and climate are the key elements for an economically sustainable production of wine. The choice of the rootstock/scion variety best adapted to the characteristics of the soil is essential but, by changing climatic conditions, ongoing climate change disrupts the fine-tuned local equilibrium. Higher temperatures induce shifts in developmental stages, with on the one hand increasing fears of spring frost damages and, on the other hand, ripening during the warmest periods in summer. Expected higher water demand and longer and more frequent drought events are also major concerns. The genetic control of the phenotypes, by genomic information but also by the epigenetic control of gene expression, offers a lot of opportunities for adapting the plant material to the future. For complex traits, genomic selection is also a promising method for predicting phenotypes. However, ecophysiological modelling is necessary to better anticipate the phenotypes in unexplored climatic conditions Genetic approaches applied on parameters of ecophysiological models rather than raw observed data are more than ever the basis for finding, or building, the ideal varieties of the future.

Elucidating vineyard site contributions to key sensory molecules: Identification of correlations between elemental composition and volatile aroma profile of site-specific Pinot noir wines

The reproducibility of elemental profile in wines produced across multiple vintages has been previously reported using grapes from a single scion clone of Vitis vinifera L. cv. Pinot noir. The grapevines were grown on fourteen different vineyard sites, from Oregon to southern California in the U.S.A., which span distances from approximately hundreds of meters to 1450 km, while elevations range from near sea level to nearly 500 m. In addition, sensorial (i.e. aroma, taste, and mouthfeel) and chemical (i.e. polyphenolic and volatile) differences across the different vineyard sites have also been observed among these wines at two aging time points. While strong evidence exists to support that grapes grown in different regions can produce wines with unique chemical and sensorial profiles, even when a single clone is used, the understanding of growing site characteristics that result in this reproducible differentiation continues to emerge. One hypothesis is that the elemental profile that a vineyard site imparts to the grape berries and the resulting wine is an important contributor to this differentiation in chemistry and sensory of wines. For example, various classes of enzymes that catalyze the formation of key aroma compounds or their precursors require specific metals. In this work, we begin to report correlations between elemental and volatile aroma profiles of site-specific Pinot noir wines, made under standardized winemaking conditions, that have been previously shown to be distinguished separately by these chemical analyses.

Effects of graft quality on growth and grapevine-water relations

Climate change is challenging viticulture worldwide compromising its sustainability due to warmer temperatures and the increased frequency of extreme events. Grafting Vitis vinifera L.