WAC 2022 banner
IVES 9 IVES Conference Series 9 WAC 9 WAC 2022 9 1 - WAC - Oral presentations 9 Evolution of chemical pattern related to Valpolicella aroma ‘terroir’ during bottle aging

Evolution of chemical pattern related to Valpolicella aroma ‘terroir’ during bottle aging

Abstract

Valpolicella is a famous Italian wine-producing region. Wines produced in its different sub-regions are believed to be aromatically different, as confirmed by recent studies in our laboratory. Aging is a very common practice in Valpolicella and it is required by the appellation regulation for periods up to four years require wines. The aim of this study was to investigate the evolution, during aging, of volatile chemical composition of Valpolicella wines obtained from grapes harvested in different sub-regions during different vintages.

Corvina and Corvinone grapes, the two main varieties of Valpolicella appellation, were harvested from five different vineyard blocks located in two sub-regions within Valpolicella during three consecutive vintages (2017-2019). Winemaking was performed under standardized conditions. An accelerated aging protocol was applied placing wines at 16°C and 40 °C for 30 days in epoxy resin sealed vials. Free volatile compounds as well as those obtained through hydrolysis of glycosidic precursors were analysed with gas chromatography mass spectrometry (GC-MS) coupled with SPE and SPME extractions.

Application of multivariate data analysis techniques to young wines allowed to identify volatile chemical patterns representing the unique aroma chemical signature of the geographical origin of each wine, regardless of vintages. In the case of aged wines, aroma signatures of individual geographical origin were preserved to a good extent after aging. In the case of Corvina, ageing slightly reduced the diversity associated with vineyard signature, conversely in Corvinone it seemed to have enhanced it. Terpenes were at the same times among the main drivers of vineyard signatures of both young and aged wines but also among the compounds most affected by ageing treatments. Highly relevant correlations were found between the decrease of some of the terpenes and the occurrence or increase of others. These transformations involve odor- active compounds with implications for floral and balsamic attributes. Despite the deep changes occurring during aging, aged wines retained an aroma chemical signature that was characteristic of their geographical origin.

DOI:

Publication date: June 9, 2022

Issue: WAC 2022

Type: Article

Authors

Giovanni Luzzini, Davide, Slaghenaufi, Maurizio, Ugliano

Presenting author

Giovanni Luzzini – Università di Verona

Università di Verona | Università di Verona

Contact the author

Keywords

 Red wine aroma – Terroir – Chemical signature of geographic identity – Valpolicella – Aging

Tags

IVES Conference Series | WAC 2022

Citation

Related articles…

Impact of some agronomic practices on grape skins anthocyanin content

Wine colour is the first quality characteristic to be assessed, especially regarding red wines. Anthocyanins are very well known to be the main responsible compounds for red wine colour. Red cultivars can synthesize and accumulate anthocyanins in berry skin to express their colour. However, anthocyanin accumulation is often influenced by a series of factors, such as genetic regulation, phytohormones, environmental conditions and viticultural management.

Varieties and rootstocks: an important mean for adaptation to terroir

A large genetic diversity exists among V. vinifera varieties, but also among cultivated rootstocks. This diversity is important to adapt plant material to different environmental conditions

Better understand the soil wet bulb formation with subsurface or aerial drip irrigation in viticulture

The gradual change in rainfall patterns experienced in the south of France vineyards, especially around the Mediterranean sea, means that the vines are increasingly subject to summer drought. The winegrowers developped the use of irrigation techniques to ensure the maintenance of competitive yields in the production of wines under Protected Geographical Indication label. In practice, drip irrigation pipes can be installed above the ground or buried into the soil as well as at different distances from the vine row. The objective of this study was to examine the profiles of the wet bulbs of the soil obtained from two drip irrigation systems : aerial drip located under the vine row and subsurface drip placed in the middle of the inter-row. This experiment took place over two consecutive seasons (2020-2021) on a 3.4 ha Viognier plot in the Mediterranean region (PGI Oc, France) on sandy clay soil. The annual rainfalls were less than 400 mm. Soil water content probes were installed at different depths (20 – 40 – 60 – 80 cm) and at different lateralities from the vine row (30 – 60 – 90 – 120 cm) to control the formation of the soil wet bulb during irrigation. The mapping and the analysis of the data allowed a better understanding and differentiation of the water percolation when irrigating with subsurface or aerial drip. For the same amount of water and without differences of vine water status, it is shown that in a subsurface drip irrigation situation, the size of the wet bulb formed is larger than in aerial drip irrigation system.

Temperature variability assessment at vineyard scale: control of data accuracy and data processing protocol

Climatic variability studies at fine scale have been developed in recent years with the reduction of material cost and the development of competitive miniaturized sensors. This work is forming part the LIFE-ADVICLIM project, of which one of the objectives is to model spatial temperature variability at vineyard scale. In the Bordeaux pilot site, a large network of data loggers has been set up to record temperature close to the vine canopy. The reduced distance between plant foliage and measurement equipment raises specific issues and leads to an increased rate of outliers compared to data retrieved from classical weather stations. Some of these were detected during data analysis, but others could not be easily identified. The present study aims to address the issue of data quality control and provide recommendations for data processing in climatic studies at fine scale.

Pruned vine biomass exclusion from a clay loam vineyard soil – examining the impact on physical/chemical properties

The wine industry worldwide faces increasing challenges to achieve sustainable levels of carbon emission mitigation. This project seeks to establish the feasibility of harvesting winter pruned vineyard biomass (PVB) for potential use in carbon footprint reduction, through its use as a renewable biofuel for energy production. In order to make this recommendation, technical issues such as the potential environmental impact, chemical composition and fuel suitability, and logistical challenges of harvesting biomass needs to be understood to compare with the results from similar studies. Of particular interest is the role PVB plays as a carbon source in vineyard soils and what effect annual removal might have on soil carbon sequestration. A preliminary trial was established in the Waite Campus vineyard (University of Adelaide) to test current management strategies. Vines are grown in a Eutrophic, Red Dermosol clay loam soil with well managed midrow swards. A comparison was undertaken of mid-row treatments in two 0.25 Ha blocks (Shiraz and Semillon), including annual cultivation for seed bed preparation, the deliberate exclusion of PVB (25 years) and incorporation of PVB (13 years) at an average of 3.4 and 5.5 Mg/Ha-1 for Shiraz and Semillon respectively. In both 0-10cm and 10-30cm soil core sample depths, combined soil carbon % measures in the desired range of 1.80 to 3.50, were not significantly different between treatments or cultivars and yielded an estimated 42 Mg/ha-1 of sequestered soil carbon. Other key physical and chemical measures were likewise not significantly different between treatments. Preliminary results suggest that in a temperate zone vineyard, managed such as the one used in this study, there is no long term negative impact on soil carbon sequestration through removing PVB. This implies that growers could confidently harvest PVB for use in several end fates including as a bio fuel.