WAC 2022 banner
IVES 9 IVES Conference Series 9 WAC 9 WAC 2022 9 1 - WAC - Oral presentations 9 Evolution of chemical pattern related to Valpolicella aroma ‘terroir’ during bottle aging

Evolution of chemical pattern related to Valpolicella aroma ‘terroir’ during bottle aging

Abstract

Valpolicella is a famous Italian wine-producing region. Wines produced in its different sub-regions are believed to be aromatically different, as confirmed by recent studies in our laboratory. Aging is a very common practice in Valpolicella and it is required by the appellation regulation for periods up to four years require wines. The aim of this study was to investigate the evolution, during aging, of volatile chemical composition of Valpolicella wines obtained from grapes harvested in different sub-regions during different vintages.

Corvina and Corvinone grapes, the two main varieties of Valpolicella appellation, were harvested from five different vineyard blocks located in two sub-regions within Valpolicella during three consecutive vintages (2017-2019). Winemaking was performed under standardized conditions. An accelerated aging protocol was applied placing wines at 16°C and 40 °C for 30 days in epoxy resin sealed vials. Free volatile compounds as well as those obtained through hydrolysis of glycosidic precursors were analysed with gas chromatography mass spectrometry (GC-MS) coupled with SPE and SPME extractions.

Application of multivariate data analysis techniques to young wines allowed to identify volatile chemical patterns representing the unique aroma chemical signature of the geographical origin of each wine, regardless of vintages. In the case of aged wines, aroma signatures of individual geographical origin were preserved to a good extent after aging. In the case of Corvina, ageing slightly reduced the diversity associated with vineyard signature, conversely in Corvinone it seemed to have enhanced it. Terpenes were at the same times among the main drivers of vineyard signatures of both young and aged wines but also among the compounds most affected by ageing treatments. Highly relevant correlations were found between the decrease of some of the terpenes and the occurrence or increase of others. These transformations involve odor- active compounds with implications for floral and balsamic attributes. Despite the deep changes occurring during aging, aged wines retained an aroma chemical signature that was characteristic of their geographical origin.

DOI:

Publication date: June 9, 2022

Issue: WAC 2022

Type: Article

Authors

Giovanni Luzzini, Davide, Slaghenaufi, Maurizio, Ugliano

Presenting author

Giovanni Luzzini – Università di Verona

Università di Verona | Università di Verona

Contact the author

Keywords

 Red wine aroma – Terroir – Chemical signature of geographic identity – Valpolicella – Aging

Tags

IVES Conference Series | WAC 2022

Citation

Related articles…

Terroir zoning in appellation campo de borja (northeast Spain): Preliminary results

The components and methodology for characterization of the terroir have been described by Gómez-Miguel & Sotés (1993-2014, 2003) and Gómez-Miguel (2011) taking into account the full range of environmental factors (i.e: climate, lithology, vegetation, topography, soils, altitude, etc.), landscape variables (derived from photo-interpretation and a digital elevation model), and specific variables to the country’s viticulture (i.e: size and distribution of the vineyards, varieties, phenology, productivity, quality, designation regulations, etc.).

Evaluation of climate change impacts at the Portuguese Dão terroir over the last decades: observed effects on bioclimatic indices and grapevine phenology

In the last decades the growers of the Portuguese Dão winegrowing region (center of Portugal) are experiencing changes in climate that are influencing either grape phenology berry health and ripening. Aiming to study the relationships between climate indices (CI), seasonal weather and grapevine phenology, in this work long-term climate and phenological data collected at the experimental vineyard of the Portuguese Dão research centre between 1958 and 2019 (61 years) for the red variety Touriga Nacional, was analyzed. The trends over time for the classical temperature-based indices (Growing Season Temperature – GST -, Growing Degree Days – GDD, Huglin Index – HI and Cool Night Index – CI) presented a significantly positive slope while the Dryness Index (DI) showed a negative trend over the last 61 years. Regarding grapevine phenology, an average advance of 4.5 days per decade in the harvest day was observed throughout the last 61 years. Consequently, the weather conditions during the ripening period have changed, showing an increasing trend over time in the average temperature (higher magnitude in the maximum than in the minimum temperature) and a decrease in the accumulated rainfall. A regression analysis showed that ~50% of harvest date variability over years was explained by the temperature-based indices variability. These observed effects of climate change on bioclimatic indices and corresponding anticipation of harvest date can still be considered advantageous for the Dão terroir as it allows to achieve an optimal berry ripening before the common equinox rains and, therefore, avoid the potential negative impacts of the rainfall on berry health and composition.

Future scenarios for viticultural climatic zoning in Europe

Climate is one of the main conditioning factors of winemaking. In this context, bioclimatic indices are a useful zoning tool, allowing the description of the suitability of a particular region

The impact of differences in soil texture within a vineyard on vine development and wine quality

Marlborough Sauvignon Blanc has rapidly gained an international reputation for style and quality. The extent to which this can be attributed to the climate, soils or vineyard management is at present unclear. However, the young alluvial soils of the Wairau Plains are considered to play an important role in determining this unique wine style. Marked changes in soil texture occur on the Wairau Plains over short distances.

Macromolecular characterization of disease resistant red wine varieties (PIWI)

Pilzwiderstandsfähige (PIWI) are disease resistant Vitis vinifera interspecific hybrid varieties that are receiving increasing attention for ability to ripen in cool climates and their resistance to grapevine fungal diseases. Wines produced from these varieties have not been characterized, especially regarding their macromolecular composition. This study characterised and quantified colloid-forming molecules (proteins, polysaccharides and phenolics) of red PIWI wines produced in the UK. METHODS: In 2019 6 wines were made from the PIWI varieties Rondo, Cabernet Jura, Cabernet Cortis, Cabernet Noir, Regent and Cabertin grown at the Plumpton Rock Lodge Vineyard in Sussex (UK) and harvested at similar level of maturity (TSS, pH and TA). All juice was chaptalized to the same potential alcohol of 12%. Small scale winemaking (1L) was performed in quadruplicate using Bodum® coffee plungers to manage maceration [1]. Residual sugar content, pH, and titratable acidity were monitored during fermentation. For finished wines, the protein and polysaccharide content was measured by HPLC-SEC [2], while the total phenolic content was assessed using the Folin-Ciocalteau method [3]. The protein profile of the wines was further investigated by SDS-PAGE [4]. RESULTS: Fermentations (n=24) were all carried out to completion within 8 days.