IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Optimization and validation of a fully automated HS-SPME method for determination of VCCs and its application in wines submitted to accelerated ageing

Optimization and validation of a fully automated HS-SPME method for determination of VCCs and its application in wines submitted to accelerated ageing

Abstract

Wine aroma is a complex gaseous mixture composed of various compounds; some of these molecules derive directly from the grapes while most of them are released and synthetized during fermentation or are due to ageing reactions. Among the latter class of compounds, carbonyls are the principal products of oxidation reactions which take place during the storing time. Volatile carbonyl compounds (VCCs) are related to aromatic nuances of vanilla, caramel, butter, honey, potato, orange, lemon, violets, cider and plum, which are pleasant scents characteristics of oxidized wines. However, apart from cases where it is a deliberate process, oxidation is commonly undesired and the presence of a relevant content of carbonyls is related to aroma defects. Because of that, monitoring the concentration of VCCs could be added as a quality control for the evaluation of a complete fermentation, correct winemaking style, and proper bottling and storage. In this research an HS-SPME method1 was optimized and validated with the aim to be used as a tool to achieve this goal. The use of a solvent-free extraction allowed to maximize the coherence to the Green Analytical Chemistry principles with a simultaneous achievement in performance, reliability and robustness. In this method, all sample preparation steps were automated using the autosampler minimizing the human time consumption to enhance the scalability to routine analysis. As many as 46 VCCs (mainly linear aldehydes, Strecker aldehydes, unsaturated aldehydes, ketones, and many other) were the analytes under investigation. All compounds showed a good linearity spanning from approximately 0.1 to 100 µg/L (R2>0.99). Intra-day and 5 days inter-days repeatability showed an RSD

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article

Authors

Piergiovanni Maurizio1, Carlin Silvia2, Lotti Cesare2, Vhrovsek Urska2 and Mattivi Fulvio1,2

1Center Agriculture Food Environment (C3A), University of Trento, via Edmund Mach 1, San Michele all’Adige (TN) Italy
2Center Research and Innovation, Edmund Mach Foundation, Italy3Affiliation of the third 

Contact the author

Keywords

Carbonyls, oxidation, accelerated ageing, HS-SPME, quality control

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Training system and its influence on iso-anisohydric behavior of cv. Syrah

Water use efficiency is one of the most valued objectives in vine growing in mediterranean climates (de la fuente et al., 2015). Due to this, the grape growers provide different adaptation strategies according to their efficient consumption against the presumable water deficit generated under these environmental conditions. The use of non-positioned shoot systems (like sprawl, bush, etc.) Can help to achieve this objective.

Effects of oak barrel aging monitored by 1H-NMR metabolomics

The study of wine evolution during barrel aging is an important aspect of wine quality. Our previous works have shown that wine metabolome monitoring by

1H-NMR approaches allows determining the impact of different winemaking processes including traitements using enzymes or finning agents [1].

Selecting varieties best adapted to current and future climate conditions based on ripening traits

Aim: The aim of this study was to quantify key berry sugar accumulation traits and characterize their plasticity in response to climate variation from data collected from different cultivars over seven years from an experimental vineyard.

Intravarietal diversity: an opportunity for climate change adaptation

Merlot grapevine is the second wine cultivar most planted in the world and especially in the Bordeaux wine region. This cultivar has many advantages in producing high quality wine; however, in the last decade, climate change has increased the sugar concentration in berries at harvest and shortened the maturation cycle. If this has been up to now a great opportunity to improve wine quality profile, we are touching the tipping point. High sugar concentration at harvest induces high alcool content in wine which can negatively impact wine quality. There are many viticultural and oenological practices possible to limit this effect. In this study we focus on plant material through intra-varietal diversity of Merlot cultivar.

Les micro-zones et les technologies traditionnelles de la viniculture en Géorgie

La Géorgie est un pays d’une tradition très ancienne de viticulture et de viniculture. Là, dans les micro zones spécifiques, en précisant le lieu on produit de différents types du vin d’une

IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Optimization and validation of a fully automated HS-SPME method for determination of VCCs and its application in wines submitted to accelerated ageing

Optimization and validation of a fully automated HS-SPME method for determination of VCCs and its application in wines submitted to accelerated ageing

Abstract

Content of the article

References

Section for all references

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: typeofthepublication

Authors

author1, author2, author3

Presenting author

Description

List of affiliations ¹ ² ³

Contact the author

Email address (with mailto: link)

Keywords

List of different keywords (keyword1, keyword2, keyword3)

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Distribution of fungicide-resistant Botrytis cinerea mutations in the Tokaj and Eger wine regions

Botrytis cinerea is one of the most widespread host-specific fungal pathogens, causing significant yield losses and economic damage to vineyards every year.

Uve e vini in vulcaniti basiche anorogeniche dei lessini meridionali, impronta petrochimica e assimilazione di metalli pesanti

Nel 2009 sono stati prelevati e analizzati mediante XRF (X-ray fluorescence) campioni di suolo, in vigneti sperimentali siti nelle province di Vicenza e di Ancona. Sono stati inoltre determinati in 2 campioni di mosto e 2 di vino delle varietà Verdicchio e Refosco dal peduncolo rosso, ed in 2 di uva Refosco dal peduncolo rosso, gli elementi in traccia mediante ICP-MS (Inductively coupled plasma-mass spectrometry).

Relations between soil characteristics and must and wine composition in different terroirs of Emilia Romagna (Italy)

The under-way zoning works of the Emilia viticulture have pointed out a huge variability of the features of the soils, which belong to this area.

Changing the scale of characterization of a wine area: from a single protected designation of origin to a vineyard Loire Valley observatory (viLVO)

Terroir is increasingly important today in wine markets. In a large wine production area such as the Loire Valley, the whole territories/terroirs can be distinguished according to different combinations of geological, soil, climatic and landscape features but are also characterized by their differences and likenesses in terms of combinations of terroir units and practices.

Methodological approach to zoning

An appellation or geographic indication should be based on the terroir concept in order to ensure its integrity. The delimitation of viticultural terroirs must include two consecutive or parallel steps, namely (a) the characterisation of the environment and identification of homogenous environmental units (basic terroir units, natural terroir units) taking all natural factors into account, as well as (b) the characterisation of the viticultural and oenological potential of these units over time.