WAC 2022 banner
IVES 9 IVES Conference Series 9 WAC 9 WAC 2022 9 4 - WAC - Posters 9 The development of a simple electrochemical method based on molecularly imprinted polymers for the selective determination of caffeic acid in wine

The development of a simple electrochemical method based on molecularly imprinted polymers for the selective determination of caffeic acid in wine

Abstract

Caffeic acid (CA) is an antioxidant of great importance in the food sector, such as wine, where it acts as a marker of wine ageing, as well as in the health sector due to its antioxidant properties and beneficial effects including the prevention of inflammation, cancer, neurodegenerative diseases, and diabetes. A simple and fast electrochemical method was developed for the determination of caffeic acid in a hydroalcoholic medium, based on a molecular imprinted polymer (MIP) in order to highlight the specificity and selectivity of the polymer. A MIP specific to CA was synthesized by the radical polymerization process, using N-phenylacrylamide (N-PAA), tetraethoxysilane (TEOS), ethylene glycol dimerhacrylate (EGDMA) and azobisisobutyronitrile (AIBN) in the presence of CA as template molecule and under thermal conditions (60°C). Screen-printed carbon electrodes were used in the electrochemical measurements without any pre-treatment or modification of their surface, in order to ensure the simplicity of the method. Cyclic voltammograms were applied at a scan rate of 50mV/s, from -0.4 to 0.8 V, and showed that, at pH3, the polymer presented good stability and repeatability regarding CA determination. In addition, it exhibited high selectivity towards CA compared to other interferents with similar structures. Furthermore, the polymer was successfully tested for the detection of CA in wine.

DOI:

Publication date: June 27, 2022

Issue: WAC 2022

Type: Article

Authors

Marie EL HACHEM, Elias Bou-Maroun, Richard G. Maroun, Philippe Cayot, Maher Abboud

Presenting author

Marie EL HACHEM – UMR PAM, Procédés Alimentaires et Microbiologiques, Bourgogne Franche-Comté University, AgroSup Dijon, France

UMR PAM, Procédés Alimentaires et Microbiologiques, Bourgogne Franche-Comté University, AgroSup Dijon, France | Centre d’Analyses et de Recherche, Laboratoire CTA, UR TVA, Faculty of Sciences, Saint Joseph University, Beirut, Lebanon | UMR PAM, Procédés Alimentaires et Microbiologiques, Bourgogne Franche-Comté University, AgroSup Dijon, France | UEGP Unité Environnement, Génomique et Protéonique, Faculty of Sciences, Saint Joseph University, Beirut, Lebanon, ,

Contact the author

Keywords

Caffeic acid- health benefits-electrochemistry-molecularly imprinted polymer-screen-printed carbon electrodes

Tags

IVES Conference Series | WAC 2022

Citation

Related articles…

Survey of winegrape irrigation practices in the Sacramento-San Joaquin Valley of California

In California vineyards, irrigation is considered as one of the most important decisions growers will make. Recent research has revealed that decisions of when to begin irrigation and how much water to apply have considerable consequences for final grape quality and hence wine quality. However, it is unclear whether and to what extent the average winegrape grower uses objective data to begin irrigating or to determine the amount of water to apply.

Impact of reduction alcohol techiniques in the aromatic chemical profile of rosé Tempranillo wines

Studying the impact of reducing alcohol techniques in the chemical composition of the aromatic profile of rosé Tempranillo wines from the spanish region of Castilla-La Mancha INTRODUCTION: In the last decades there has been an increseasing demand of wines with low or non-existing alcohol concentration due to the negative effects that alcohol has in health. In spite of that, there are not laws that protect these products, and there is also a great difficulty in the elaboration of these type of wines due to the increasing temperatures because of climate change. This is why the oenological industry has made great advances in the development of different techniques that could satisfy consumers’ demands without modifying wine quality. The most used techniques have been post-fermentative ones.

Cascading effects of spring weather conditions into grape berry ripening

The effects of climate change on viticulture are complex due to interactions among factors and cascading effects.

Sensory and chemical effects of postharvest grape cooling on wine quality

Wine cellars are affected by seasonally fluctuating workloads and face challenges especially in the harvest period connected to the required timely processing of the harvested grapes.

Relation between phenolic content, antioxidant capacity, oxygen consumption rate of diverse tannins

The work was aimed at comparing some analytical methods used to characterize oenological tannins and the measure of oxygen consumption rate (OCR), in order to provide oenologists with a rapid method to test the antioxidant capacity of tannin based products and a tool to choose the best suited product for each purpose.