WAC 2022 banner
IVES 9 IVES Conference Series 9 WAC 9 WAC 2022 9 3 - WAC - Posters 9 Impact of aging on dimethyl sulfide (DMS) in Corvina and Corvinone wines

Impact of aging on dimethyl sulfide (DMS) in Corvina and Corvinone wines

Abstract

Dimethyl sulfide (DMS) is a low molecular weight sulfur compound produced in wine during aging by the chemical degradation of S-Methyl-L-methionine (SMM). Investigating the aromatic profile of Amarone commercial wines from different wineries, it was found that DMS presented a high variation in concentration across wine samples ranging from 2.88 to 64.34 μg/L, which potentially can affect the perceived aroma. Therefore, in order to investigate this variation, the influence of grape variety, withering, precursor, and vintage on DMS formation was studied. To achieve this a set of experimental wines, vintage 2017, 2018 and 2019 made with Corvina and Corvinone (fresh and withered) grapes from five different vineyards was submitted to accelerated aging. Samples in duplicate were kept at 45 °C for 24, 48, and 96 days, and then analyzed by HS-SPME GC-MS to determine their DMS content. Results showed minor increases in all samples at 24 and 48 days, whereas a considerable accumulation of DMS occurred at 96 days with concentrations approaching values around 120 μg/L. Additionally, it was observed that wines made from withered grapes presented higher concentrations respect to those made with fresh grapes, while the grape variety did not show a significant difference. The precursor influence in the wines was explored as well through the correlation between DMS concentration and primary amino acid nitrogen (PAN) content in wines (before aging). PAN content was measured at 340 nm in an automatic analyzer. In wines from vintage 2017, a good correlation (R2=0.7742) was found between the DMS (concentration of DMS at 96 days minus initial concentration) and PAN. While for wines from vintage 2018 and 2019, the correlation was 0.5581 and 0.4043, respectively. Finally, in order to further elucidate additional factors related to the variability in the ability of wines to generate DMS during aging, the influence of pH was also investigated. For this, two sets of wine, one spiked with SMM, were submitted to accelerated aging (one month, 45 °C), in which pH was adjusted to 3 and 4. Results showed an increase in DMS of 10% in the samples with pH 4, which could be explained by the stability of SMM in acid conditions, therefore, at a higher pH, the precursor could be more prone to release DMS.  Concluding, this study points out PAN as a potential tool to predict the production of DMS during aging. As well as providing some indications of the influence of withering in DMS production.

DOI:

Publication date: June 27, 2022

Issue: WAC 2022

Type: Article

Authors

Jessica Anahi, Samaniego Solis, Giovanni, Luzzini, Davide, Slaghenaufi, Maurizio, Ugliano

Presenting author

Jessica Anahi, Samaniego Solis – University of Verona

Giovanni, Luzzini | University of Verona, Davide, Slaghenaufi | University of Verona, Maurizio, Ugliano | University of Verona

Contact the author

Keywords

DMS, aging, Amarone, Corvina, Corvinone

Tags

IVES Conference Series | WAC 2022

Citation

Related articles…

Consistency of the hydraulic traits and stomatal responses in grapevines with contrasting hydraulic vulnerability

Different from wild species in arid and semiarid conditions, cultivated species are very sensitive to drought and, beyond some stress thresholds, food production is not possible

Oenological potential of indigenous greek grape varieties and their clones

Vine clone selection aims at the survival of clones with particularly desireable attributes for the production of high quality wines. The purpose of this research was to study the enological potential of the clones of Greek indigenous grape varieties over two vintages, 2018 and 2019.
METHODS: Two clones of the white grape varieties Moschofilero (E26 and E27), Assyrtiko (E11 and 16), Roditis (25E16 and 02E1E21) and two clones of the red grape varieties Xinomavro (19 and E2E30) and Agiorgitiko (03E40 and 41E47) were vinified under the same protocol for the white wines and common for the red wines in 2018 and 2019. The resulting products were studied for several enological parameters such as alcohol content, volatile acidity, pH, total phenolics, anthocyanins and tannins for the red wines, as well as browning tests for the white wines. The aroma profile of these ten samples was investigated through sensory analysis with intensity rating of individual attributes on a five-point scale by a trained panel.

Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

During the tasting of a fine, old wine, the aromas generated in the glass are intertwined in an intimate, complex manner, expressing the fragrance of the aging bouquet. This aging bouquet, which develops during bottle storage through a complex transformation process, may result in a broad palette of nuances. Among these, undergrowth, truffle, toasted, spicy, licorice, fresh red- and black-berry fruit and mint descriptors were recently identified as features of its olfactory representation for red Bordeaux wines. Although a targeted chemical approach focusing on volatile sulfur compounds revealed the role played by dimethyl sulfide, 2-furanmethanethiol, and 3-sulfanylhexanol as molecular markers of the typicality of the wine aging bouquet of red Bordeaux wines, its chemical transcription has only partially been elucidated.

UNTARGETED METABOLOMICS ANALYSES TO IDENTIFY A NEW SWEET COMPOUND RELEASED DURING POST-FERMENTATION MACERATION OF WINE

The gustatory balance of dry wines is centered on three flavors, sourness, bitterness and sweetness. Even if certain compounds were already identified as contributing to sweetness, some taste modifications remain largely unexplained1,2. Some empirical observations combined with sensory analyzes have shown that an increase of wine sweetness occurs during post-fermentation maceration³. This step is a key stage of red winemaking during which the juice is left in contact with the marc, that contains the solid parts of the grape (seeds, skins and sometimes stems). This work aimed to identify a new taste-active compound that contributes to this gain of sweetness.

The effect of rootstock on water relations and gas exchange of Vitis vinifera cv. Xinomavro

The effect of two rootstocks of different drought tolerance (1103 Paulsen and 3309 Couderc) on sap flow, water relations and gas exchange of cv. Xinomavro (Vitis vinifera L.) was investigated during the 2005 season in Naoussa, Greece. Soil was maintained at field capacity for both rootstock treatments until mid July when a restricted water regime was applied by irrigation cutoff. Sap flow diurnals for the Xinomavro-1103P combination showed a rapid decrease of flow after midday, under water stress conditions.