terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Survey of pesticide residues in vineyard soils from the Denomination of Origin Ribeiro

Survey of pesticide residues in vineyard soils from the Denomination of Origin Ribeiro

Abstract

Vineyards from mild temperature, high humidity locations receive often treatments with fungicides to prevent damages produced by fungi responsible for mildium, oidium and botrytis infections. In addition, insecticides are also applied to vineyards to fight again pests, which affect directly, or indirectly (as vectors of different diseases), their productivity. A fraction of the above compounds reaches the soil of vineyards, either during application, or when released from the canopy of vines due to rain-wash-off. Thereafter, depending on soil conditions (pH, organic matter) and environmental variables (regimen of rain, slope of vineyards), they might persist in this compartment, be degraded and/or transferred to water masses, modifying the biodiversity of soils and/or affecting the quality of water reservoirs. 

In this presentation, the presence of residues for a suite of 50 pesticides in soils of vineyards from the D.O. Ribeiro, managed under different agronomic practices, was explored. Data on occurrence, temporal and spatial evolution are provided considering two sampling campaigns carried out at the end of summer, and the end of the next winter, taking soils at two different depths (0-5 and 5-20 cm). For some chiral compounds, i.e. myclobutanil, the potential existence of enantioselective soil degradation processes was assessed through their enantiomeric fractions in this matrix. Pesticide residues ranged from non-detected (organic vineyards) to several hundreds of ng g-1 in case of myclobutanil, fluopicolid and dimethomorph.

Acknowledgements: Funds received from AGACAL (project ref. AC2021E-02), and Xunta de Galicia (project ED431C2021/06) are acknowledged.

DOI:

Publication date: October 9, 2023

Issue: ICGWS 2023

Type: Poster

Authors

P. Blanco1, V. Fernández2, N. Calvo-Portela3, M. Ramil2, M.F. Alonso-Vega3 I. Rodríguez2

1 Estación de Viticultura e Enoloxía de Galicia (EVEGA-AGACAL), Ponte San Clodio s/n, 32428, Leiro-Ourense
2 Department of Analytical Chemistry, Nutrition and Food Sciences, IAQBUS – Institute of Research on Chemical and Biological Analysis, Universidade de Santiago de Compostela, R/Constantino Candeira SN, 15782 Santiago de Compostela, Spain
3 Área de Edafoloxía e Química Agrícola, Departamento de Bioloxía Vegetal e Ciencia do Solo, Facultade de Ciencias. Universidade de Vigo. 32004. Spain

Contact the author*

Keywords

soil, fungicides, insecticides, occurrence, liquid chromatography tandem mass spectrometry

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Combined use of leaf removal and natural shading to delay grape ripening in Manto negro (Vitis vinifera L.) under deficit irrigation 

The increasingly frequent heat waves during grape ripening pose challenges for premium wine grape production. This makes the development of irrigation and canopy management techniques of great importance to maximize yield and grape quality. A field experiment was carried out during 2021 and 2022 using Manto negro wine grapes to study the effect of two irrigation strategies and different light exposure levels on grape quality.

“Compost Application in the Vineyard: Effects on Soil Nutrition and Compaction”

The mechanization of pruning and harvesting in vineyards has increased the risk of soil compaction. To reclaim soil properties or avoid this degradation process, it is crucial to properly manage the soil organic matter, and the application of compost derived from the vines themselves is a strategy to achieve this. The objective of this study was to evaluate the properties of soil treated with different doses of compost applied both on the vine row and the inter rows of a Vitis vinifera crop.

Model-assisted analysis of the root traits underlying RSA genotypic diversity in Vitis: a promising approach for rootstock selection?

By dissecting the root system architecture (RSA) into its underpinning components (e.g. root emission, axial growth, radial growth, branching, root direction or tropism) and identifying the relationships between them, functional-structural 3D root models are promising tools for analyzing the diversity and complexity of root system phenotypes with Genotype × Environment interactions. The model parameters are assumed to be synthetic traits, less influenced by the environment, and consequently with less polygenic architectures than the integrative RSA traits they drive. Root models can serve as a basis for in silico development of root system ideotypes by highlighting the developmental processes and parameters that most likely influence RSA fitness.

Chemical profiling and sensory analysis of wines from resistant hybrid grape cultivars vs conventional wines

Recently, there has been a shift toward sustainable wine production, according to EU policy (F2F and Green Deal), to reduce pesticide usage, improve workplace health and safety, and prevent the impacts of climate change. These trends have gained the interest of consumers and winemakers. The cultivation of disease resistant hybrid grape cultivars (DRHGC), known as ‘PIWI’ grapes can help with these objectives [1]. This study aimed to profile white and red wines produced from DRHGC in South Tyrol (Italy). Wines produced from DRHGCs were compared with conventional wines produced by the same wineries. The measured parameters were residual sugars, organic acids, alcohol content, pigments and other phenolics by LC-QqQ/MS, colorimetric indexes (CIELab); and volatile profiles (HS-SPME-GCxGC-ToF/MS [2]).

Impact of toasting and botanical origin on oak wood (Q. sp.) volatilome using untargeted GCxGC-ToFMS analysis

Many works have been carried out to identify the key aroma volatile compounds of oak wood (e.g., whisky-lactone, furfural, maltol, eugenol, guaiacol, vanillin) using conventional gas chromatography coupled with olfactometry and mass spectrometry (GC-O-MS). Inspired by recent untargeted approaches in the field of food “omics”, this work aims to extend our knowledge on the impact of cooperage process on the volatile composition of oak wood using two-dimensional comprehensive gas chromatography coupled with time of flight mass spectrometry (GCxGC-ToFMS).