terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Survey of pesticide residues in vineyard soils from the Denomination of Origin Ribeiro

Survey of pesticide residues in vineyard soils from the Denomination of Origin Ribeiro

Abstract

Vineyards from mild temperature, high humidity locations receive often treatments with fungicides to prevent damages produced by fungi responsible for mildium, oidium and botrytis infections. In addition, insecticides are also applied to vineyards to fight again pests, which affect directly, or indirectly (as vectors of different diseases), their productivity. A fraction of the above compounds reaches the soil of vineyards, either during application, or when released from the canopy of vines due to rain-wash-off. Thereafter, depending on soil conditions (pH, organic matter) and environmental variables (regimen of rain, slope of vineyards), they might persist in this compartment, be degraded and/or transferred to water masses, modifying the biodiversity of soils and/or affecting the quality of water reservoirs. 

In this presentation, the presence of residues for a suite of 50 pesticides in soils of vineyards from the D.O. Ribeiro, managed under different agronomic practices, was explored. Data on occurrence, temporal and spatial evolution are provided considering two sampling campaigns carried out at the end of summer, and the end of the next winter, taking soils at two different depths (0-5 and 5-20 cm). For some chiral compounds, i.e. myclobutanil, the potential existence of enantioselective soil degradation processes was assessed through their enantiomeric fractions in this matrix. Pesticide residues ranged from non-detected (organic vineyards) to several hundreds of ng g-1 in case of myclobutanil, fluopicolid and dimethomorph.

Acknowledgements: Funds received from AGACAL (project ref. AC2021E-02), and Xunta de Galicia (project ED431C2021/06) are acknowledged.

DOI:

Publication date: October 9, 2023

Issue: ICGWS 2023

Type: Poster

Authors

P. Blanco1, V. Fernández2, N. Calvo-Portela3, M. Ramil2, M.F. Alonso-Vega3 I. Rodríguez2

1 Estación de Viticultura e Enoloxía de Galicia (EVEGA-AGACAL), Ponte San Clodio s/n, 32428, Leiro-Ourense
2 Department of Analytical Chemistry, Nutrition and Food Sciences, IAQBUS – Institute of Research on Chemical and Biological Analysis, Universidade de Santiago de Compostela, R/Constantino Candeira SN, 15782 Santiago de Compostela, Spain
3 Área de Edafoloxía e Química Agrícola, Departamento de Bioloxía Vegetal e Ciencia do Solo, Facultade de Ciencias. Universidade de Vigo. 32004. Spain

Contact the author*

Keywords

soil, fungicides, insecticides, occurrence, liquid chromatography tandem mass spectrometry

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Inert gases persistence in wine storage tank blanketing

It is common to find tanks in the winery with wine below their capacity due to wine transfers between tanks of different capacities or the interruption of operations for periods of a few days. This situation implies the existence of an ullage space in the tank with prolonged contact with the wine causing its absorption/oxidation. Oxygen uptake from the air headspace over the wine due to differences in the partial pressure of O2 can be rapid, up to 1.5 mL of O2 per liter of wine in one hour and 100 cm2 of surface area1 and up to saturation after 4 hours.

Association between dietary pattern and wine consumption and Alzheimer’s disease in a cohort from La Rioja (Spain)

Addressing modifiable risk factors is the most promising strategy to prevent/delay Alzheimer Disease (AD)[1]. The aim of the study was to establish the connections between dietetic habits, wine consumption and AD. Thus, 98 volunteers were recruited: 50 diagnosed as AD and 48 healthy/controls. The Food Frequency Questionnaire (FFQ) was used for dietary patterns assessment and, based on these data, the Mind Diet Score was calculated. (Poly)phenol metabolites (especially derived from wine consumption) were analyzed by UPLC-QqQ-MS/MS in 24-h urine samples to confirm dietary (poly)phenol consumption.

Effect of riboflavin on the longevity of white and rosé wines

Light is a fundamental part at sales points which influences in the conservation of wines, particularly in those that are sold in transparent glass bottles such as rosé wines and increasingly white wines. The photochemical effect known as “light-struck taste” can cause changes in the aromatic characteristics of the wine. This “light-struck taste” is due to reactions triggered by the photochemical sensitivity of riboflavin (RBF).

Viticultural heritage in mountain territories of Catalonia: prospecting in the region of Osona, northern Spain

The recovery of ancestral or minority vine varieties has been gaining great interest in recent years, among other reasons because it is likely that some of these varieties, due to the fact that they are found in relict areas, have a greater potential for adaptation to external factors (biotic or abiotic) and can minimize the effects that climate change is causing in viticulture. Varieties that can be grown at altitude are currently being sought to combat rising temperatures and prolonged extreme drought conditions. In Catalonia, the Pyrenean expansion of vineyard cultivation is documented from the 10th century and has been related to the “small climatic optimum” (9th-12th centuries) and also to seigniorial power.[1] But different adverse climatic periods and the arrival of Phylloxera by the late 19th century made many of these crops disappear.[2]

Identification of several glycosidic aroma precursors in six varieties of winemaking grapes and assessment of their aroma potential by acid hydrolysis

In winemaking grapes, it is known that most aroma compounds are present as non-volatile precursors, such as glycosidic precursors. In fact, there is strong evidence supporting the connection between the content of aroma precursors and the aromatic quality of wine [1]. Acid hydrolysis is preferred to reveal the aroma potential of winemaking grapes, as it predicts more accurately the chemical rearrangements occurring during fermentation in acidic environments [2]. In this study, a method involving a fast fermentation followed by acid hydrolysis at 75ºC was used to evaluate the accumulation of aroma compounds over time in fractions obtained from six different varieties of winemaking grapes.