terclim by ICS banner
IVES 9 IVES Conference Series 9 CONTRIBUTION OF VOLATILE THIOLS TO THE AROMA OF RIESLING WINES FROM THREE REGIONS IN GERMANY AND FRANCE (RHEINGAU, MOSEL, AND ALSACE)

CONTRIBUTION OF VOLATILE THIOLS TO THE AROMA OF RIESLING WINES FROM THREE REGIONS IN GERMANY AND FRANCE (RHEINGAU, MOSEL, AND ALSACE)

Abstract

Riesling wines are appreciated for their diverse aromas, ranging from the fruity fresh characters in young vintages to the fragrant empyreumatic notes developed with aging. Wine tasters often refer to Riesling wines as prime examples showcasing terroir, with their typical aroma profiles reflecting the geographical provenance of the wine. However, the molecular basis of the distinctive aromas of these varietal wines from major Riesling producing regions in Europe have not been fully elucidated. In this study, new lights were shed on the chemical characterization and the sensory contribution of volatile thiols to Riesling wines from Rheingau, Mosel, and Alsace. First, Riesling wines (n = 46) from the three regions were collected and assessed for their aroma typicality by an expert panel. Based on sensory assessment, selected wines were examined for their global aroma profile by sensory guided odorant screening techniques (preparative high pressure liquid chromatography; gas chromatography–mass spectrometry/olfactometry (GC–MS/O); sensory evaluation), and several odorous zones (OZs) of interest resembling the original olfactory notes (citrus, tropical fruits etc.) of the initial wines were noted. The aroma descriptors, linear retention index, and mass spectra of the suspected chromatography peaks and their accompanying OZs of interest revealed the presence and importance of volatile thiols in Riesling wines analysed. Hence, selective silver ion solid phase extraction and multidimensional GC–MS/O were applied for further characterization of targeted thiol-relevant OZs, allowing tentative identification of unknown thiols, with one new mercapto monoterpenoid confirmed by orthogonal approach. Following the sensory guided qualitative screening efforts, a new and highly sensitive quantitation method based on chemical derivatization and liquid chromatography quadrupole Orbitrap high-resolution MS was developed for the analysis of a substantial number of known and newly identified volatile thiols in the wine set. Quantitative results confirmed the relevance of 13 odorous thiols in Riesling, with several of them presented at concentrations well over their perception thresholds, as 3-sulfanylhexanol for instance. Thus, the combination of the chemical analysis of thiols and the sensory evaluation made it possible to draw up regional profiles according to the origin of the wines.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Emilio De Longhi1,2,3, Liang Chen1, 2, †, Pascaline Redon1, 2, Christoph Schüssler4, Rainer Jung4, Claus Patz5, Doris Rau-Hut3, Philippe Darriet1,2

1. Université de Bordeaux, Bordeaux INP, INRAE, OENO, UMR 1366, ISVV, F-33140 Villenave d’Ornon, France
2. Bordeaux Sciences Agro, Bordeaux INP, INRAE, OENO, UMR 1366, ISVV, F-33170 Gradignan, France
3. Hochschule Geisenheim University, Department of Microbiology and Biochemistry, Von-Lade-Str. 1, 65366 Geisenheim, Germany
4. Hochschule Geisenheim University, Department of Enology, Von-Lade-Str. 1, 65366 Geisenheim, Germany
5. Hochschule Geisenheim University, Department of Beverage Research, Von-Lade-Str. 1, 65366 Geisenheim, Germany †Current address: E. & J. Gallo Winery, 600 Yosemite Boulevard, Modesto, CA 95354, United States

Contact the author*

Keywords

Riesling wine aroma, Volatile thiols, Identification, Quantitation

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

FUNCTIONALIZED MESOPOROUS SILICA IS A VIABLE ALTERNATIVE TO BENTONITE FOR WINE PROTEIN STABILIZATION

The presence of grape-derived heat unstable proteins can lead to haze formation in white wines [1], an instability prevented by removing these proteins by adding bentonite, a hydrated aluminum silicate that interacts electrostatically with wine proteins leading to their flocculation. Despite effective, using bentonite has several drawbacks as the costs associated with its use, the potential negative effects on wine quality, and its environmental impact, so that alternative solutions are needed.

EFFECTS OF WINEMAKING FACTORS AND AGEING ON THE POLYPHENOLIC AND COLORIMETRIC PROFILES IN RED WINES PRONE TO COLOUR INSTABILITY

The effects of (A) grape freezing, and (B) malolactic fermentation, have been evaluated on the chemical and colorimetric profiles of red wines from Schiava grossa cv. grapes, thus prone to colour instability. The aim was to observe if specific variables (e.g. grape freezing) could improve the extraction and stability of pigments. The samples were studied from musts up to twelve months in bottle. The study was conducted with independent parallel micro-vinifications (12 = 4 theses x 3 replicates) under strictly-controlled conditions.

METABOLIC INTERACTIONS OF SACCHAROMYCES CEREVISIAE COCULTURES: A WAY TO EXTEND THE AROMA DIVERSITY OF CHARDONNAY WINE

Yeast co-inoculations in winemaking have been investigated in various applications, but most often in the context of modulating the aromatic profiles of wines. Our study aimed to characterize S. cerevisiae interactions and their impact on wine by taking an integrative approach. Three cocultures and corresponding pure cultures of S. cerevisiae were characterized according to their fermentative capacities, the chemical composition and aromatic profile of the associated Chardonnay wines. The various strains studied within the cocultures showed different behaviors regarding their development.

NEW INSIGHTS INTO VOLATILE SULPHUR COMPOUNDS SCALPING ON MICROAGGLOMERATED WINE CLOSURES

The evolution of wine during bottle ageing has been of great interest to ensure consistent quality over time. While the role of wine closures on the amount of oxygen is well-known [1], closures could also play other roles such as the scalping phenomenon of flavour compounds. Flavour scalping has been described as the sorption of flavour compounds by the packaging material, which could result in losses of flavour intensity. It has been reported in the literature that volatile sulphur compounds (VSC) can be scalped on wine closures depending on the type of closure (traditional and agglomerated cork, screw-cap, synthetic [2]).

INVESTIGATING TERROIR TYPICITY: A COMPREHENSIVE STUDY BASED ON THE AROMATIC AND SENSORIAL PROFILES OF RED WINES FROM CORBIÈRES APPELLATION

Volatile compounds play a significant role on the organoleptic properties defining wines quality. This particular role was exploited in several studies with the aim to differentiate wines from a more or less extensive production area, according to their sensory profile [1], as well as their chemical composition [2,3] (Di Paola-Naranjo et al., 2011; Kustos et al., 2020). Indeed, since aroma compounds development in grapes depends primarily on the environmental conditions of the vines and grapes (soil and climate), it is conceivable that these parameters craft the aromatic signature of the wine produced, in relation to its origin (Van Leeuwen et al., 2020). In this work, a general study on the aromatic and sensorial profile of wines produced in five sub-regions of the Corbières denomination, a renowned red grape varieties viticultural region in South France, was reported.