terclim by ICS banner
IVES 9 IVES Conference Series 9 MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

Abstract

From the chemical angle, Champagne wines are complex hydro-alcoholic mixtures supersaturated with dissolved carbon dioxide (CO₂). During the pouring process and throughout the several minutes of tasting, the headspace of a champagne glass is progressively invaded by many chemical species, including gas-phase CO₂ in large majority. CO₂ bubbles nucleated in the glass and collapsing at the champagne surface act indeed as a continuous paternoster lift for aromas throughout champagne or sparkling wine tasting [1]. Nevertheless, inhaling a gas space with a concentration of gaseous CO₂ close to 30% and higher triggers a very unpleasant tingling sensation, the so-called “carbonic bite”, which might completely perturb the perception of the wine’s bouquet. Therefore, to enhance the champagne tasting experience, monitoring gas-phase CO₂ in the headspace of champagne glasses has become a topic of interest over the last dozen years [2-5].

Based on the Tunable Diode Laser Absorption Spectroscopy (TDLAS), a CO₂-Diode Laser Sensor (CO₂- DLS) with two distributed feedback (DFB) diode lasers emitting at 4986.0 and 3728.6 cm-1 was deve- loped to allow the fine monitoring of gas-phase CO₂ over a large concentration range from 0.5% to 100%. Moreover, to perform the simultaneous spatial mapping of CO₂ along a multipoint array in the headspace of champagne glasses, two couples of galvanometric mirrors were combined with a couple of parabolic mirrors symmetrically positioned on either side of the glass headspace [4,5]. Thereby, the CO₂-DLS shows a very high temporal resolution thus enabling an accurate monitoring and mapping of gas-phase CO₂ in the headspace of glasses.

Real-time monitoring of gas-phase CO₂ was thus performed with the CO₂-DLS, under static tasting conditions, in the headspace of several types of champagne glasses showing distinct shapes and volume capacities (including the 21 cL INAO glass, a worldwide reference for sensory evaluation). Moreover, a brand-new glass recently proposed as a universal glass for the tasting of still and sparkling wines (the 45 cL ŒnoXpert) was also examined. A kind of CO₂ fingerprint, evolving in space and time, was unveiled for each glass type. After a strong increase of the gas-phase CO₂ concentration observed within the several seconds of the pouring step, a vertical stratification of CO₂ was unveiled in the headspace of glasses, with decreasing CO₂ concentrations while moving away from the champagne surface, and as time elapses.

1. Liger-Belair G., Cilindre C., Cilindre C., Gougeon D. R., Lucio M., Gegefügi I., Jeandet P., Schmitt-Kopplin P., Unraveling different chemical fingerprints between a champagne wine and its aerosols, Proceedings of the National Academy of Sciences of the United States of America, 2009, 106, 16545-16459
2. Cilindre C., Conreux, A., Liger-Belair G., Simultaneous monitoring of gaseous CO₂ and ethanol above champagne glasses via micro-gas chromatography (μGC), Journal of Agricultural and Food Chemistry, 2011, 59, 7317-7323
3. Moriaux A.-L., Vallon R., Cilindre C., Parvitte B., Liger-Belair G. and Zéninari V., Development and validation of a diode laser sensor for gas-phase CO₂ monitoring above champagne and sparkling wines, Sensors and Actuators B: Chemical, 2018, 257, 745-752
4. Moriaux A.-L., Vallon R., Cilindre C., Polak F., Parvitte B., Liger-Belair G. and Zéninari V., A first step towards the mapping of gas-phase CO₂ in the headspace of champagne glasses, Infrared Physics & Technology, 2020, 109, 103437
5. Moriaux A.-L., Vallon R., Lecasse F., Chauvin N., Parvitte B., Zéninari V., Liger-Belair G., Cilindre C., How does gas-phase CO₂ evolve in the headspace of champagne glasses? Journal of Agricultural and Food Chemistry, 2021, 69, 2262-2270

 

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Vincent Alfonso¹, Florian Lecasse¹, Raphaël Vallon¹, Clara Cilindre¹, Bertrand Parvitte¹, Virginie Zéninari¹ And Gé-Rard Liger-Belair¹

1. GSMA, UMR CNRS 7331, Université de Reims Champagne-Ardenne, 51697 Reims Cedex 2, France

Contact the author*

Keywords

TDLAS, Champagne, CO₂, Effervescence

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

SENSORY CHARACTERIZATION OF COGNAC EAUX-DE-VIE AGED IN BARRELS REPRESENTING DIFFERENT TOASTING PROCESS

Cognac is an outstanding french wine spirit appreciated around the world and produced exclusively in the Nouvelle-Aquitaine region, and more precisely in the Cognac area. According to AOC regulations (Appellation D’origine Controlée), the spirit required at least 2 years of continuous ageing in oak barrels to be granted the title of Cognac. The oak wood will import color, structure and organoleptic complexity. The different steps during barrel-making process, such as seasoning and toasting, influence the above quality attributes in both wines and spirits.

NEUROPROTECTIVE AND ANTI-INFLAMMATORY PROPERTIES OF HYDROXYTYROSOL: A PROMISING BIOACTIVE COMPONENT OF WINE

Hydroxytyrosol (HT) is a phenolic compound present in olives, virgin olive oil and wine. HT has attracted great scientific interest due to its biological activities which have been related with the ortho-dihydroxy conformation in the aromatic ring. In white and red wines, HT has been detected at concentrations ranging from 0.28 to 9.6 mg/L and its occurrence has been closely related with yeast metabolism of aromatic amino acids by Ehrlich pathway during alcoholic fermentation. One of the most promising properties of this compound is the neuroprotective activity against pathological mechanisms related with neurode-generative disorders including Alzheimer’s and Parkinson’s disease.

EFFECTS OF WINEMAKING FACTORS AND AGEING ON THE POLYPHENOLIC AND COLORIMETRIC PROFILES IN RED WINES PRONE TO COLOUR INSTABILITY

The effects of (A) grape freezing, and (B) malolactic fermentation, have been evaluated on the chemical and colorimetric profiles of red wines from Schiava grossa cv. grapes, thus prone to colour instability. The aim was to observe if specific variables (e.g. grape freezing) could improve the extraction and stability of pigments. The samples were studied from musts up to twelve months in bottle. The study was conducted with independent parallel micro-vinifications (12 = 4 theses x 3 replicates) under strictly-controlled conditions.

EVALUATION OF INDIGENOUS CANADIAN YEAST STRAINS AS WINE STARTER CULTURES ON PILOT SCALE FERMENTATIONS

The interactions between geographical and biotic factors, along with the winemaking process, influence the composition and sensorial characteristics of wine¹. In addition to the primary end products of alcoholic fermentation, many secondary metabolites contribute to wine flavor and aroma and their production depends predominantly on the yeast strain carrying out the fermentation. Commercially available strains of S. cerevisiae help improve the reproducibility and predictability of wine quality. However, most commercial wine strains available on the market have been isolated from Europe, are genetically similar, and may not be the ideal strain to reflect the terroir of Canadian vineyards².

UNRAVELLING THE ROLE OF LACTIC ACID BACTERIA ON SPARKLING WINE ELABORATION THROUGH METABOLOMICS APPROACH

Xinomavro is a red grape variety from Northern Greece (Protected Designation of Origin), known for the nice acidities, perfectly appropriate for sparkling wine production (Rosé and Blanc de Noir). The elabo- ration of sparkling wine requires technical as well as scientific skills. Although the impact of the yeast strains and their metabolites on the final product quality is well documented, the action of bacteria still remains unknown.
The present work focuses (i) on the population diversity of lactic acid bacteria isolated from sparkling wines and (ii) on the technological effect of the species during sparkling wine elaboration.