terclim by ICS banner
IVES 9 IVES Conference Series 9 MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

Abstract

From the chemical angle, Champagne wines are complex hydro-alcoholic mixtures supersaturated with dissolved carbon dioxide (CO₂). During the pouring process and throughout the several minutes of tasting, the headspace of a champagne glass is progressively invaded by many chemical species, including gas-phase CO₂ in large majority. CO₂ bubbles nucleated in the glass and collapsing at the champagne surface act indeed as a continuous paternoster lift for aromas throughout champagne or sparkling wine tasting [1]. Nevertheless, inhaling a gas space with a concentration of gaseous CO₂ close to 30% and higher triggers a very unpleasant tingling sensation, the so-called “carbonic bite”, which might completely perturb the perception of the wine’s bouquet. Therefore, to enhance the champagne tasting experience, monitoring gas-phase CO₂ in the headspace of champagne glasses has become a topic of interest over the last dozen years [2-5].

Based on the Tunable Diode Laser Absorption Spectroscopy (TDLAS), a CO₂-Diode Laser Sensor (CO₂- DLS) with two distributed feedback (DFB) diode lasers emitting at 4986.0 and 3728.6 cm-1 was deve- loped to allow the fine monitoring of gas-phase CO₂ over a large concentration range from 0.5% to 100%. Moreover, to perform the simultaneous spatial mapping of CO₂ along a multipoint array in the headspace of champagne glasses, two couples of galvanometric mirrors were combined with a couple of parabolic mirrors symmetrically positioned on either side of the glass headspace [4,5]. Thereby, the CO₂-DLS shows a very high temporal resolution thus enabling an accurate monitoring and mapping of gas-phase CO₂ in the headspace of glasses.

Real-time monitoring of gas-phase CO₂ was thus performed with the CO₂-DLS, under static tasting conditions, in the headspace of several types of champagne glasses showing distinct shapes and volume capacities (including the 21 cL INAO glass, a worldwide reference for sensory evaluation). Moreover, a brand-new glass recently proposed as a universal glass for the tasting of still and sparkling wines (the 45 cL ŒnoXpert) was also examined. A kind of CO₂ fingerprint, evolving in space and time, was unveiled for each glass type. After a strong increase of the gas-phase CO₂ concentration observed within the several seconds of the pouring step, a vertical stratification of CO₂ was unveiled in the headspace of glasses, with decreasing CO₂ concentrations while moving away from the champagne surface, and as time elapses.

1. Liger-Belair G., Cilindre C., Cilindre C., Gougeon D. R., Lucio M., Gegefügi I., Jeandet P., Schmitt-Kopplin P., Unraveling different chemical fingerprints between a champagne wine and its aerosols, Proceedings of the National Academy of Sciences of the United States of America, 2009, 106, 16545-16459
2. Cilindre C., Conreux, A., Liger-Belair G., Simultaneous monitoring of gaseous CO₂ and ethanol above champagne glasses via micro-gas chromatography (μGC), Journal of Agricultural and Food Chemistry, 2011, 59, 7317-7323
3. Moriaux A.-L., Vallon R., Cilindre C., Parvitte B., Liger-Belair G. and Zéninari V., Development and validation of a diode laser sensor for gas-phase CO₂ monitoring above champagne and sparkling wines, Sensors and Actuators B: Chemical, 2018, 257, 745-752
4. Moriaux A.-L., Vallon R., Cilindre C., Polak F., Parvitte B., Liger-Belair G. and Zéninari V., A first step towards the mapping of gas-phase CO₂ in the headspace of champagne glasses, Infrared Physics & Technology, 2020, 109, 103437
5. Moriaux A.-L., Vallon R., Lecasse F., Chauvin N., Parvitte B., Zéninari V., Liger-Belair G., Cilindre C., How does gas-phase CO₂ evolve in the headspace of champagne glasses? Journal of Agricultural and Food Chemistry, 2021, 69, 2262-2270

 

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Vincent Alfonso¹, Florian Lecasse¹, Raphaël Vallon¹, Clara Cilindre¹, Bertrand Parvitte¹, Virginie Zéninari¹ And Gé-Rard Liger-Belair¹

1. GSMA, UMR CNRS 7331, Université de Reims Champagne-Ardenne, 51697 Reims Cedex 2, France

Contact the author*

Keywords

TDLAS, Champagne, CO₂, Effervescence

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

ALCOHOLIC FERMENTATION DRIVES THE SELECTION OF OENOCOCCUS OENI STRAINS IN WINE

Oenococcus oeni is the predominant lactic acid bacteria species in wine and cider, where it performs the malolactic fermentation (MLF) (Lonvaud-Funel, 1999). The O. oeni strains analyzed to date form four major genetic lineages named phylogroups A, B, C and D (Lorentzen et al., 2019). Most of the strains isolated from wine, cider, or kombucha belong to phylogroups A, B+C, and D, respectively, although B and C strains were also detected in wine (Campbell-Sills et al., 2015; Coton et al., 2017; Lorentzen et al., 2019;

MAPPING THE CONCENTRATIONS OF GASEOUS ETHANOL IN THE HEADSPACE OF CHAMPAGNE GLASSES THROUGH INFRARED LASER ABSORPTION SPECTROSCOPY

Under standard wine tasting conditions, volatile organic compounds (VOCs) responsible for the wine’s bouquet progressively invade the glass headspace above the wine surface. Most of wines being complex water/ethanol mixtures (with typically 10-15 % ethanol by volume), gaseous ethanol is therefore undoubtedly the most abundant VOC in the glass headspace [1]. Yet, gaseous ethanol is known to have a multimodal influence on wine’s perception [2]. Of particular importance to flavor perception is the effect of ethanol on the release of aroma compounds into the headspace of the beverage [1].

CHARACTERIZATION OF THE VOLATILE COMPOUNDS PROFILE OF COMMERCIAL GRAPPAS OBTAINED FROM THE POMACE OF AMARONE WINES

Grappa is a traditional Italian alcoholic beverage, with an alcohol content generally between 40-60% vol., obtained from the distillation of grape pomace used for the production of wine. Grappa are often aged in wooden barrels. There are various types of grappa: young, aromatic, aged, extra-aged depending on whether the distillate comes from aromatic vines or is aged in wooden barrels for shorter or longer periods. There is also flavored grappa if herbs, fruit or roots are added. All this makes it an extremely heterogeneous product both from an organoleptic and compositional point of view.

ASSESSING THE ROLE OF 27 KNOWN BITTER COMPOUNDS IN COMMERCIAL WHITE WINES COMBINING LC-MS QUANTIFICATION AND SENSORY ANALYSIS

The balance between the different flavours of a wine largely determines its perception and appreciation by the consumers. In white wines, sweetness and sourness are usually the two poles balancing the taste properties. The bitter flavour, on the other hand, is frequently associated with a loss of equilibrium and all white wines (dry and sweet, young and aged) are affected.
Several bitter compounds are already well-described in wines.

AGEING REVEALS THE TERROIR OF AGED RED BORDEAUX WINES REGARDLESS OF THE VINTAGES! TARGETED APPROACH USING ODOROUS COMPOUNDS LEVELS INCLUDING TERPENES AND C13 NORISOPRENOIDS

The chemistry of wine is notably complex and is modified by ageing of the bottles. The composition of wines is the result of vine production (under the influence of vintage, climate and soils); yeast production (under the influence of juice composition and fermentation management); lactic bacteria production (under the influence of young wine composition and malolactic fermentation management); and of the ageing process either in vats, barrels or bottles or both. The composition is linked to the quality perceived by consumers but also to their origin, sometimes associated to the “terroir” concept.