terclim by ICS banner
IVES 9 IVES Conference Series 9 MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

MAPPING OF GAS-PHASE CO₂ IN THE HEADSPACE OF CHAMPAGNE GLASSES BY USING AN INFRARED LASER SENSOR UNDER STATIC TASTING CONDITIONS

Abstract

From the chemical angle, Champagne wines are complex hydro-alcoholic mixtures supersaturated with dissolved carbon dioxide (CO₂). During the pouring process and throughout the several minutes of tasting, the headspace of a champagne glass is progressively invaded by many chemical species, including gas-phase CO₂ in large majority. CO₂ bubbles nucleated in the glass and collapsing at the champagne surface act indeed as a continuous paternoster lift for aromas throughout champagne or sparkling wine tasting [1]. Nevertheless, inhaling a gas space with a concentration of gaseous CO₂ close to 30% and higher triggers a very unpleasant tingling sensation, the so-called “carbonic bite”, which might completely perturb the perception of the wine’s bouquet. Therefore, to enhance the champagne tasting experience, monitoring gas-phase CO₂ in the headspace of champagne glasses has become a topic of interest over the last dozen years [2-5].

Based on the Tunable Diode Laser Absorption Spectroscopy (TDLAS), a CO₂-Diode Laser Sensor (CO₂- DLS) with two distributed feedback (DFB) diode lasers emitting at 4986.0 and 3728.6 cm-1 was deve- loped to allow the fine monitoring of gas-phase CO₂ over a large concentration range from 0.5% to 100%. Moreover, to perform the simultaneous spatial mapping of CO₂ along a multipoint array in the headspace of champagne glasses, two couples of galvanometric mirrors were combined with a couple of parabolic mirrors symmetrically positioned on either side of the glass headspace [4,5]. Thereby, the CO₂-DLS shows a very high temporal resolution thus enabling an accurate monitoring and mapping of gas-phase CO₂ in the headspace of glasses.

Real-time monitoring of gas-phase CO₂ was thus performed with the CO₂-DLS, under static tasting conditions, in the headspace of several types of champagne glasses showing distinct shapes and volume capacities (including the 21 cL INAO glass, a worldwide reference for sensory evaluation). Moreover, a brand-new glass recently proposed as a universal glass for the tasting of still and sparkling wines (the 45 cL ŒnoXpert) was also examined. A kind of CO₂ fingerprint, evolving in space and time, was unveiled for each glass type. After a strong increase of the gas-phase CO₂ concentration observed within the several seconds of the pouring step, a vertical stratification of CO₂ was unveiled in the headspace of glasses, with decreasing CO₂ concentrations while moving away from the champagne surface, and as time elapses.

1. Liger-Belair G., Cilindre C., Cilindre C., Gougeon D. R., Lucio M., Gegefügi I., Jeandet P., Schmitt-Kopplin P., Unraveling different chemical fingerprints between a champagne wine and its aerosols, Proceedings of the National Academy of Sciences of the United States of America, 2009, 106, 16545-16459
2. Cilindre C., Conreux, A., Liger-Belair G., Simultaneous monitoring of gaseous CO₂ and ethanol above champagne glasses via micro-gas chromatography (μGC), Journal of Agricultural and Food Chemistry, 2011, 59, 7317-7323
3. Moriaux A.-L., Vallon R., Cilindre C., Parvitte B., Liger-Belair G. and Zéninari V., Development and validation of a diode laser sensor for gas-phase CO₂ monitoring above champagne and sparkling wines, Sensors and Actuators B: Chemical, 2018, 257, 745-752
4. Moriaux A.-L., Vallon R., Cilindre C., Polak F., Parvitte B., Liger-Belair G. and Zéninari V., A first step towards the mapping of gas-phase CO₂ in the headspace of champagne glasses, Infrared Physics & Technology, 2020, 109, 103437
5. Moriaux A.-L., Vallon R., Lecasse F., Chauvin N., Parvitte B., Zéninari V., Liger-Belair G., Cilindre C., How does gas-phase CO₂ evolve in the headspace of champagne glasses? Journal of Agricultural and Food Chemistry, 2021, 69, 2262-2270

 

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Vincent Alfonso¹, Florian Lecasse¹, Raphaël Vallon¹, Clara Cilindre¹, Bertrand Parvitte¹, Virginie Zéninari¹ And Gé-Rard Liger-Belair¹

1. GSMA, UMR CNRS 7331, Université de Reims Champagne-Ardenne, 51697 Reims Cedex 2, France

Contact the author*

Keywords

TDLAS, Champagne, CO₂, Effervescence

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

PREVALENCE OF OAK-RELATED AROMA COMPOUNDS IN PREMIUM WINES

Barrel fermentation and barrel-ageing of wine are commonly utilised practices in premium wine production. The wine aroma compounds related to barrel contact are varied and can enhance a range of wine aromas and flavours, such as ‘struck flint’, ‘caramel’, ‘red berry’, ‘toasty’ and ‘nutty’, as well as conventional oaky characters such as ‘vanilla’, ‘spice’, ‘smoky’ and ‘coconut’. A survey of commercially produced premium Shiraz, Cabernet Sauvignon, Pinot Noir and Chardonnay wines was conducted, assessing the prevalence of compounds that have been proposed as barrel-ageing markers¹ including oak lactones, volatile phenols, furanones, aldehydes, thiazoles2,3, phenylmethanethiol⁴ and 2-furylmethanethiol.⁵

YEAST-PRODUCED VOLATILES IN GRAPE BASED SYSTEM MODEL ACTING AS ANTIFUNGAL BIOAGENTS AGAINST PHYTOPATHOGEN BOTRYTIS CINEREA

Botrytis cinerea Pers., the causal agent of grey mould disease, is responsible for substantial economic losses, as it causes reduction of grape and wine quality and quantity. Exploitation of antagonistic yeasts is a promising strategy for controlling grey mould incidence and limiting the usage of synthetic fungicides. In our previous studies, 119 different indigenous yeasts were screened for putative multidimensional modes of action against filamentous fungus B. cinerea [1]. The most promissing biocontrol yeast was Pichia guilliermondii ZIM624, which exhibited several anatagonistic traits (production of cell wall degrading enzymes, chitinase and β-1,3-glucanase; demonstration of in vitro inhibitory effect on B. cinerea mycelia radial growth; production of antifungal volatiles, assimilation of a broad diversity of carbon sources, contributing to its competitivnes in inhabiting grapes in nature).

IMPACT OF CLIMATIC CONDITIONS ON THE SEASONING QUALITY OF OAK WOOD FOR OENOLOGICAL USE (QUERCUS PETRAEA)

For coopers, seasoning and toasting are considered crucial steps in barrel making during which the oak wood develops specific organoleptic properties. Seasoning, carried out in the open air, allows reducing the moisture content of the staves to between 14 and 18% (compared to 70 to 90% after splitting) while modulating the intrinsic composition of the oak wood. Toasting consists of applying different degrees of heat to a barrel for a specific period of time. As the temperature increases, oak wood produces a wide range of chemical compounds through thermal degradation of its intrinsic composition.

Rootstock mediated responses of grapevine (Vitis vinifera L.) metabolism and physiology to combined water deficit and salinity stress in Syrah grafts

Water deficit and salinity are increasingly affecting the viticulture and wine industry. These two stresses are intimately related; understanding the physiological and metabolic responses of grapevines to water deficit, salinity and combined stress is critical for developing strategies to mitigate the nega- tive impacts of these stresses on wine grape production. These strategies can include selecting more tolerant grapevine cultivars and graft combinations, improving irrigation management, and using soil amendments to reduce the effects of salinity. For this purpose, understanding the response of grape- vine metabolism to altered water balance and salinity is of pivotal importance.

SIP and save the planet: a sensory and consumer exploration of australian wines made from potentially drought-tolerant white wine grapes

In order to attenuate the effects of climate change on the ability to cultivate quality wine grape vines in Australia, it is essential to adapt to the projected less favourable Australian climate scenarios. One response may be to convert a portion of the current grapevine plantings to those varieties that demand less water and can tolerate increased heat. This investigation aimed to (i) generate sensory profiles and (ii) obtain knowledge about Australian wine consumers’ preferences and opinions of Australian wines made from potentially drought tolerant, white wine grape varieties not traditionally cultivated in Australia. A Rate-All-That-Apply (RATA) sensory panel (n = 49) generated sensory profiles of 44 commercial white wines made from 7 different white grape varieties (Arinto, Fiano, Garganega, Greco, Verdejo, Verdelho and Vermentino), plus two benchmark examples each of an Australian Riesling, Pinot Gris and Chardonnay wine.