terclim by ICS banner
IVES 9 IVES Conference Series 9 EFFECTS OF WINEMAKING FACTORS AND AGEING ON THE POLYPHENOLIC AND COLORIMETRIC PROFILES IN RED WINES PRONE TO COLOUR INSTABILITY

EFFECTS OF WINEMAKING FACTORS AND AGEING ON THE POLYPHENOLIC AND COLORIMETRIC PROFILES IN RED WINES PRONE TO COLOUR INSTABILITY

Abstract

The effects of (A) grape freezing, and (B) malolactic fermentation, have been evaluated on the chemical and colorimetric profiles of red wines from Schiava grossa cv. grapes, thus prone to colour instability. The aim was to observe if specific variables (e.g. grape freezing) could improve the extraction and stability of pigments. The samples were studied from musts up to twelve months in bottle. The study was conducted with independent parallel micro-vinifications (12 = 4 theses x 3 replicates) under strictly-controlled conditions. The measured parameters included: 1) sugars, organic acids and %ABV (measured by specific enzymatic methods or by OIV reference methods), 2) dissolved oxygen (measured according to OIV protocols), 3) semi-quantitative determination of pigments, profile of non-anthocyanidin phenols, and profile of condensed tannins (LC-QqQ/MS [1]), spectrophotometric indexes (Hue and Intensity), colorimetric indexes (CIELab parameters), and the volatile profiles (GCxGC-ToF/MS [2]). A striking relation among the abundances of four anthocyanidin monoglucosides (peonidin-3-glu, malvidin-3-glu, petunidin-3-glu, and cyanidin-3-glu) has been observed in the musts from frozen grapes, but not in wines from frozen or non-frozen grapes. Cyclic procyanidins showed neither significant differences in concentration in must and wine due to any specific applied factor, nor due to specific treatments (such as with bentonites), proving again their applicability as markers for the grape variety in wine [3]. A substantial drop in peonidin-3-glu over the vinification (the main anthocyanin in Schiava cv. grapes) was studied in relation to the applied study factors. Grape freezing increased the extraction of peonidin-3-glu in the must, though the rate of its subsequent loss was faster than in wines from non-frozen grapes. Nonethe-less, peonidin-3-glucoside was still more concentrated in the wines from frozen grapes than in wines from non-frozen grapes up to wine bottling. The wines made from frozen grapes and without malolac-tic fermentation had the highest colorimetric parameters a* (green→red), ΔE* (difference in colour), C* (chromaticity), and ΔH* (difference in tone) colorimetric parameters. b* (blue→yellow) was highest in wines from frozen grapes, but regardless of the application or not of the malolactic fermentation.

 

1. C Dupas de Matos, A., Longo, E., et al. (2020). Foods, vol. 9(4), p. 499
2. Poggesi, S., Dupas de Matos, A., Longo, E., et al. (2021). Molecules, vol. 26(20), p. 6245
3. Longo, E., Rossetti, F., Jouin, A., et al. (2019). Food chemistry, vol. 299, p. 125125

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Edoardo Longo1,2,*,†, Aakriti Darnal1,2, Adriana Teresa Ceci1,2, Simone Poggesi1,2,3, Tanja Mimmo², Emanuele Boselli1,2

1. Oenolab, NOI TechPark Alto Adige/Südtirol, Via A. Volta 13/B, 39100 Bolzano (Italy)
2. Faculty of Agricultural, Environmental and Food Sciences, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano (Italy)
3. Food experience and sensory testing laboratory (Feast), Massey University, Private Bag 11222, Palmerston North 4410 (New Zealand)

Contact the author*

Keywords

Colour instability, Grape freezing, Chemical profile, Colorimetry

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

EFFECT OF OXIDATION ON LOW MOLECULAR WEIGHT PHENOLIC FRACTION, SALIVARY PROTEINS PRECIPITATION AND ASTRINGENCY SUBQUALITIES OF RED WINES

Changes in the low molecular weight phenolic fraction, obtained by liquid-liquid microextraction technique, were studied after controlled oxidation of two typologies of Sangiovese wines (Brunello di Montalcino and Chianti Classico) belonging to two vintages (2017 and 2018). The fractions were characterized by LC-MS and quantified by HPLC. The most abundant extracted compounds were the phenolic acids. The effect of oxidation, vintage, and wine typology was stated by a three-ways ANOVA. Gallic and syringic acids significantly increased after oxidation while (–)-epicatechin decreased the most.

ESTIMATING THE INITIAL OXYGEN RELEASE (IOR) OF CORK CLOSURES

Many factors influence aging of bottled wine, oxygen transfer through the closure is included. The maximum uptake of wine before oxidation begins varies from 60 mg.L-¹ to 180 mg.L-1 for white and red wines respectively [1].
The process of bottling may lead to considerable amounts of oxygen. The actual contribution of the transfer through the closure system becomes relevant at the bottle storage, but the amounts are small compared to prepacking operations [2] and to the total oxygen attained during filling.

IDENTIFICATION OF NEW RESVERATROL DERIVATIVES FORMED IN RED WINE AND THEIR BIOLOGICAL PROPERTIES

Stilbenes are natural bioactive polyphenols produced by grapevine. Recently, we have reviewed the na- tural presence of these compounds in wines [1]. This study showed that the resveratrol and its glycoside, the piceid, are the most abundant stilbenes in wines. Resveratrol is a well-known stilbene with a wide range of biological activities. Due to its specific structure, resveratrol can be oxidized in wines to form various derivatives including oligomers [2]. In this study, we investigate the resveratrol and piceid transformation in wines.

HOLISTIC APPROXIMATION OF THE INFLUENCE OF SACCHAROMYCES STRAINS ON WINE AROMA PRECURSORS

Wine varietal aroma is the result of a mixture of compounds formed or liberated from specific grape-aroma precursors. Their liberation/formation from their specific precursors can occur spontaneously by acid catalyzed rearrangements or hydrolysis or by the action of the yeast enzymatic activities. The influence of yeast during fermentation on the production of these volatile compounds has been widely studied however, the effect of this influence during aging is not fully understood. In order to evaluate these processes several indirect strategies have been used to study aroma precursors although they are not useful to understand the chemistry of the process.

IDENTIFICATION AND LEVELS OF PHENOLIC COMPOUNDS (TANINS, ANTHO-CYANS) IN RED VARIETAL WINES (PROKUPAC AND BLACK TAMJANIKA) FROM SERBIA

The phenolic compounds of red wines represent a source of numerous benefits for human health, which is why they are a constant subject of scientific research. Winemaking in Serbia has a growing economic significance, with particularly autochthonous varieties included [1]. This research identifies and quantifies phenolic compounds of Serbian red varietal wines of Prokupac and Black Tamjanika varieties. Quantification of the level of phenolics has been conducted, including molecular tannins [(+)-catechin, (-)-epicatechin, procyanidin dimers B1, B2, B3, B4], molecular anthocyanins, and the mean degree of polymerization of tannins by HPLC by UV detection, total antioxidant capacity via spectrophotometric methods and chromatic characteristics via CIELAB.