Macrowine 2021
IVES 9 IVES Conference Series 9 Sensory definition of green aroma concept in red French wines. Evidence for the contribution of novel volatile markers

Sensory definition of green aroma concept in red French wines. Evidence for the contribution of novel volatile markers

Abstract

The aromatic complexity of a wine results from the perception of the association of volatile molecules and each aroma can be categorized into different families. The “green” aromas family in red wines has retained our attention by its close link with the fruity perception. In that study, the “green” olfactory concept of red wines was considered through a strategy combining both sensory analysis and hyphenated chromatographic techniques including HPLC and MDGC (Multidimensional Gas Chromatography). The aromatic space of this concept was specified by lexical generation through a free association task on 22 selected wines by a panel of wine experts. Then, 70 French red wines were scored on the basis of the intensity of their “green” and “fruity” attributes. The relationship between these two families and chemical markers (2-methoxy-3-isobutyl, 3-isopropyl and 3-sec-butyl pyrazines and C6 alcohol compounds) was assessed. Strong anti-correlation between “green” and “fruity” was demonstrated but no significant correlations could be established with known molecular markers associated with fresh green characters. So, the contribution of other aromatic compounds was formulated in particular with the level of grape maturation. Microvinifications of Cabernet-Sauvignon grapes from Medoc vineyard harvested at two ripeness stages were done during 2014 and 2015 vintages. The so-obtained wines were extracted with organic solvents and the concentrated extracts were fractioned by semi-preparative HPLC. Among fifty fractions collected, one was particularly highlighted for its green aromas. The sensory impact of this fraction was first confirmed by omission and reconstitution tests. To determine the molecules responsible for green flavour of this fraction, GC-O (Gas Chromatography coupled with Olfactometry) and MDGC-O/Time-Of-Flight-MS were considered. 2-Methoxy-3-isobutyl-pyrazine well known as IBMP (bell pepper descriptor) was identified as one of the compounds responsible for the aroma of this fraction with two other odoriferous compounds presenting a green aroma. One belongs to terpene family, 1,8-cineole (herbs, fresh and eucalyptus descriptors), usually associated in wines with eucalyptus trees contamination. 1,8-cineole was definitively evidenced as a Vitis vinifera compound with concentrations assayed in wines from unripe grapes and other wines from Carmenet family close or higher to olfactory detection threshold (1 µg/l). 1,8-cineole concentrations were shown to decrease like IBMP during ripeness. The other compound was identified as methyl salicylate (fresh, leafy and wintergreen descriptors), a derivative of salicylic acid, sometimes quantified in wine samples at concentrations much higher than its detection threshold (40 µg/l). Supplementation tests at assayed concentrations in red wines for these two compounds exhibited a sensory impact on green aromas and a synergic effect was noticed with IBMP on the enhancement of the green flavour in red wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Xavier Poitou*, Philippe Darriet

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

A preliminary study of clonal selection in cv. Viura in relation to varietal aroma profile

Viura is a synonym for Macabeo and currently it is the most widely planted white grape variety in D.O.Ca. Rioja, with 3,569 ha, representing 84% of the white grape cultivated area. It is a generous-yielding grape, presenting low values of titratable acidity and with large and compact clusters which makes it susceptible to Botrytis cinerea. Thus, this variety not always satisfies the wine grower’s prospects. Nowadays, the available plant material is scarce, moreover, it was selected on the basis of other quality criteria, not currently requested.

Foam characteristics of white, rosé and red sparkling wines elaborated by the champenoise method

Contribution Foam is the characteristic that differentiates sparkling wines from still wines, being the first sensory attribute that tasters and consumers perceive and that determines the final quality of sparkling wines [1]. The foaming properties mainly depend on the chemical composition of wines [2-3], and different factors involved in wine composition will have an effect on foam quality. In Spain, the sparkling wine market focuses on the production of white and rosé sparkling wine, with very low production of red sparkling wines. However, this type of wines is elaborated in countries like Australia, South-Africa, Argentina, Italy or Portugal, with a great acceptance by consumers. No studies on the foaming characteristics of red sparkling wines have been found.

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way.

Intelligent article to control the internal pressure in continue in bottles

An intelligent packaging might, among others, provide information and allow monitoring of the quality of the packed product or its surrounding environment. A recent project on micro-flow wine bottles closed with aluminium screw cap and tightness liner, highlighted the importance of monitoring the internal overpressure continuously, in real-time and at least for 72 hours, since the internal pressure on the tightness liner and the micro-flow are related. Real-time and continuous measurements are not the standard methods of measurement of the overpressure, yet. The most used equipment for the determination of the pressure in wine bottle is the aphrometer, a destructive device that supplies a single value of pressure.

Identification of green, aggressive and hard character of wines by a chemo-sensory directed methodology

With climate change, it is progressively more often to obtain grapes with an acceptable content in sugars or acids but with immature tannins described as green, aggressive or hard (noted as GAH onwards). During winemaking, the oenologist has to make decisions related to the elaboration of such grapes based mainly on empirical experience, given the lack of objective criteria to this concern. An increase in the chemical and sensory knowledge of immature tannins would allow managing this GAH character of grapes with the maximum possible efficiency during winemaking processes. The present work aims at isolating and identifying the group of compounds responsible for the GAH character present in wines.