Soil chemistry as a measure of the distinctiveness of american viticultural areas of the Columbia basin, USA

Several classes of flavonoids, such as anthocyanins, flavonols, flavanols and flavones, undergo a slow H/D exchange on aromatic ring A, leading to full deuteration at positions C(6) and C(8). Within the flavanol class, H-C(6) and H-C(8) of catechin and epicatechin are slowly exchanged in D2O to the corresponding deuterated analogues; even quercetin, a relevant flavonol representative, shows the same behaviour in a D2O/DMSOd6 1:1 solution. Detailed kinetic measurements of these H/D scrambling processes are here reported by exploiting the time-dependent changes of their peak areas in the 1H-NMR spectra taken at different temperatures. A unifying reaction mechanism is also proposed based on our detailed kinetic observations, even taking into account pH and solvent effects. Molecular modelling and QM calculations were also carried out to shed more light on several molecular details of the proposed mechanism.

Climate change has varied effects across French vineyards, with marked regional differences in temperature shifts. Fine-scale studies highlight significant local climate variability, emphasizing the need for precise regional characterization to adapt vineyard management at the regional scale.

It is quite common nowadays to carry out analyses which allow to control the ageing of spirits that are aged in wood casks. Many control parameters have been previously studied, such as the concentration of different phenolic compounds or the Total Polyphenol Index, in order to better understand the ageing process of wood aged spirits. On the other hand, it is frequent to analyse as a physical parameter the colour of those spirit samples, by stating them as an array of three coordinates from various colour spaces as CIE L*a*b* or CIE L*C*H*.

In recent years there has been a growth in interest and number of research studies regarding the application of remote optical and thermal sensing by unmanned aerial vehicle (UAV) in agriculture and viticulture. Many papers report on the use of images to map or estimate the growth and water status of plants, or the heterogeneity of different parcels. Most often, NDVI or other similar indices are used.

Climate change, particularly drought stress, threatens viticulture sustainability. Understanding scion-rootstock interactions and their link to the grapevine microbiome is key to improving vine health, productivity, and drought resilience.