Terroir 2008 banner
IVES 9 IVES Conference Series 9 Rare earth elements in grapes and soil: study of different soil extraction methods

Rare earth elements in grapes and soil: study of different soil extraction methods

Abstract

Lanthanides, together with scandium and yttrium, make up the group of Rare Earth Elements (REEs). An official method for analysis of the bioavailable REEs accumulated by plants, depending mainly on soil characteristics, chemical speciation in soil and the specific ability of the plant, is still lacking.
In this study we analysed the content of 13 REEs (yttrium, Y; lanthanum, La; cerium, Ce; praseodymium, Pr; neodymium, Nd; samarium, Sm; europium Eu; gadolinium, Gd; dysprosium, Dy; holmium, Ho; erbium, Er; thulium, Tm; ytterbium, Yb) in Chardonnay grapes in relation to the content in the soil, extracted using different methods in order to assess which of the extractants used could best reflect the amount of elements taken up by the plant.
The vineyard, located in north-eastern Italy, is characterised by a silt loam, calcareous, alkaline soil. Four different extraction methods were tested: (1) aqua regia microwave digestion; (2) with DTPA, CaCl2 and TEA; (3) with ammonium acetate and (4) with ammonium nitrate.
The amount of REEs extracted followed the order: aqua regia > DTPA > CH3COONH4 > NH4NO3. Compared to the “so-called total” content in soil, the sum of the REEs extracted with DTPA, ammonium acetate and ammonium nitrate was roughly 0.80%, 0.065% and 0.002% and each individual element was extracted in amounts of <2.9%, <0.5% and <0.2% respectively. Only 7 elements (Y, La, Sm, Eu, Dy, Er, Tm) were found in quantifiable amounts after extraction with ammonium nitrate.
The concentration of individual REEs in berries would seem to correspond best to the concentrations extracted using aqua regia.

DOI:

Publication date: December 8, 2021

Issue: Terroir 2008

Type : Article

Authors

Daniela BERTOLDI (1,2),Roberto LARCHER (1),Giorgio NICOLINI (1),Massimo BERTAMINI (1), Giuseppe CONCHERI (2)

(1) IASMA Research Centre. Via E.Mach, 1. 38010 San Michele all’Adige (TN) Italy
(2) Agricultural Biotechnology Department, University of Padova. Viale dell’Università, 16. 35020 Legnaro (PD) Italy

Contact the author

Keywords

Rare Earth Elements, berries, soil, soil extraction, ICP-MS

Tags

IVES Conference Series | Terroir 2008

Citation

Related articles…

Studio dell’ambiente viticolo attraverso la parametrazione (punto di incrocio) delle curve di maturazione delle uve (pinot nero, oltrepo’ pavese pv italia settentrionale – 45° parallelo Nord)

Sono stati presi in considerazione alcuni dati agrometeorologici dell’Oltrepò Pavese (temperature e piovosità degli ultimi 80 anni) e gli studi delle curve di maturazione condotti in zona sul Pinot nero da spumante negli anni (1988-1991, 1999-2000, 2006-2008), si nota che l’aumento progressivo negli anni delle temperature attive (indice di Winkler) ha determinato un anticipo dell’invaiatura, definita dal parametro “punto di incrocio” (intersezione delle funzioni di zuccheri ed acidità nel tempo), con conseguente anticipo della data di vendemmia di circa 12-15 gg.

Présentation d’une méthodologie de caractérisation des terroirs et valorisation par l’étude de l’effet terroir sur la typicité et l’originalité du produit vin dans la région des Côtes du Rhône

In the global economic context, an Appellation d’Origine Contrôlée must now more than ever control the typicity and originality of the wines it produces. It is in this spirit that the Côtes du Rhône have decided to acquire the means necessary for this control.

Soil variability effects on vine rootzones and available water

Aim: The aim of this work is educating people about soil variability, vine rootzone depth and readily available water holding capacity. The concept of terroir is readily discussed in the wine industry but many people involved are unable to describe a soil profile and interpret its limitations that impact on vine growth, fruit quality and wine produced. This paper discusses soil physical characteristics important to vine root growth and readily available water holding capacity (RAW).

The impact of sustainable management regimes on amino acid profiles in grape juice, grape skin flavonoids, and hydroxycinnamic acids

One of the biggest challenges of agriculture today is maintaining food safety and food quality while providing ecosystem services such as biodiversity conservation, pest and disease control, ensuring water quality and supply, and climate regulation. Organic farming was shown to promote biodiversity and carbon sequestration, and is therefore seen as one possibility of environmentally friendly production. Consumers expect organically grown crops to be free from chemical pesticides and mineral fertilizers and often presume that the quality of organically grown crops is different or higher compared to conventionally grown crops. Integrated, organic, and biodynamic viticulture were compared in a replicated field trial in Geisenheim, Germany (Vitis vinifera L. cv. Riesling). Amino acid profiles in juice, grape skin flavonoids, and hydroxycinnamic acids were monitored over three consecutive seasons beginning 7 years after conversion to organic and biodynamic viticulture, respectively. In addition, parameters such as soil nutrient status, yield, vigor, canopy temperature, and water stress were monitored to draw conclusions on reasons for the observed changes. Results revealed that the different sustainable management regimes highly differed in their amino acid profiles in juice and also in their skin flavonol content, whereas differences in the flavanol and hydroxycinnamic acid content were less pronounced. It is very likely that differences in nutrient status and yield determined amino acid profiles in juice, although all three systems showed similar amounts of mineralized nitrogen in the soil. Canopy structure and temperature in the bunch zone did not differ among treatments and therefore cannot account for the observed differences in favonols. A different light exposure of the bunches in the respective systems due to differences in vigor together with differences in berry size and a different water status of the vines might rather be responsible for the increase in flavonol content under organic and biodynamic viticulture.

Contribution to the sensory and volatile characterization of four traditional Galician red varieties

Galicia, a region sited in the northwest of Spain, is one of the most important wine production area, with five Appellations of Origin Controlled (AOC).