WAC 2022 banner
IVES 9 IVES Conference Series 9 WAC 9 WAC 2022 9 3 - WAC - Oral 9 Dimethyl sulfide: a compound of interest from grape to wine glass

Dimethyl sulfide: a compound of interest from grape to wine glass

Abstract

The overall quality of fine wines is linked to the development of “bouquet” during wine bottle ageing1. Several chemical reactions, occurring in atmosphere protected from oxygen, are favourable to the formation and preservation of sulphur compounds such as dimethyl sulfide (DMS). DMS accumulate in wines thanks to hydrolysis of its precursors (DMSp) mainly constituted by S-methylmethionine (SMM) already identified in grapes2,3. During alcoholic fermentation (AF), a part of SMM is degrade by the action of yeast. Hence, the whole of DMSp is not given to the young wine4. However, the presence of DMS in wines in linked with the expression of bouquet typicity of Bordeaux red wines5 and is implicated to aromatic nuances such as “truffle” and “blackberry”6 notes. Also, it can influence the tasting experience to give sensory polymorphism to wines7. Even if DMS seems to be an essential contributor to aged wine aroma, some points have never been explore. This have invited us complete the knowledge on the modulations of the DMS levels from grapes to the wine service. 

Various experiments were set up to answer at our hypotheses. DMSp was measured on many Bordeaux red musts, also during AF and on wines and wine model solution.

We observed the increase of DMSp levels during merlot and cabernet-sauvignon ripening. Even if a difference of accumulation seems to exist between varieties and localization, the real amount of DMSp accumulated is similar between all samples. Among all studied parameters, a link was measured between DMSp and YAN. Then, winemaking process is a key step because DMSp is consumed at the beginning of the AF and consumption depends of the levels of YAN and sometimes the yeast strain. About wine, DMS volatility is modulated by phenolic matrix. Our study highlight a form of DMS linked with grapes tannins. It sensorial impact have been partially studied but the results suggest that during tasting, a progressive release of DMS from a linked form could be implicated in the generation of many sensorial images perceived and contribute to the complexity of wine bouquet. 

1 Peynaud, E., 1980
2 Loscos, N et al., 2008
https://doi.org/10.1016/j.aca.2007.11.033
3 Segurel et al., 2005
https://doi.org/10.1021/jf048273r
4 Dagan, L., 2006
5 Picard, M. et al., 2015
https://doi.org/10.1021/acs.jafc.5b03977
6 Lytra, G. et al., 2014
https://doi.org/10.20870/oeno-one.2014.48.1.1660
7 Lytra, G. et al., 2016
https://doi.org/10.1016/j.foodchem.2015.07.143

DOI:

Publication date: June 13, 2022

Issue: WAC 2022

Type: Article

Authors

Justine Laboyrie, Marina Bely, Michael Jourdes, Nicolas le Menn, Laurent Riquier, Stéphanie Marchand

Presenting author

Justine Laboyrie – Univ. Bordeaux, INRAE, Bordeaux INP, UR Oenologie, EA 4577, USC 1366, ISVV, F-33140 Villenave d’Ornon, France

Univ. Bordeaux, INRAE, Bordeaux INP, UR Oenologie, EA 4577, USC 1366, ISVV, F-33140 Villenave d’Ornon, France

Contact the author

Keywords

Bordeaux Red wine ageing bouquet, Dimethyl sulfide, DMSp, YAN, Matrix interaction

Tags

IVES Conference Series | WAC 2022

Citation

Related articles…

Adaptation to soil and climate through the choice of plant material

Choosing the rootstock, the scion variety and the training system best suited to the local soil and climate are the key elements for an economically sustainable production of wine. The choice of the rootstock/scion variety best adapted to the characteristics of the soil is essential but, by changing climatic conditions, ongoing climate change disrupts the fine-tuned local equilibrium. Higher temperatures induce shifts in developmental stages, with on the one hand increasing fears of spring frost damages and, on the other hand, ripening during the warmest periods in summer. Expected higher water demand and longer and more frequent drought events are also major concerns. The genetic control of the phenotypes, by genomic information but also by the epigenetic control of gene expression, offers a lot of opportunities for adapting the plant material to the future. For complex traits, genomic selection is also a promising method for predicting phenotypes. However, ecophysiological modelling is necessary to better anticipate the phenotypes in unexplored climatic conditions Genetic approaches applied on parameters of ecophysiological models rather than raw observed data are more than ever the basis for finding, or building, the ideal varieties of the future.

Impact of geographical location on the phenolic profile of minority varieties grown in Spain. II: red grapevines

Because terroir and cultivar are drivers of wine quality, is essential to investigate theirs effects on polyphenolic profile before promoting the implantation of a red minority variety in a specific area. This work, included in MINORVIN project, focuses in the polyphenolic profile of 7 red grapevines minority varieties of Vitis vinifera L. (Morate, Sanguina, Santafe, Terriza Tinta Jeromo Tortozona Tinta) and Tempranillo) from six typical viticulture Spanish areas: Aragón (A1), Cataluña (A2), Castilla la Mancha (A3), Castilla –León (A4), Madrid (A5) and Navarra (A6) of 2020 season. Polyphenolic substances were extracted from grapes. 35 compounds were identified and quantified (mg subtance/kg fresh berry) by HPLC and grouped in anthocyanins (ANT) flavanols (FLAVA), flavonols (FLAVO), hydroxycinnamic (AH), benzoic (BA) acids and stilbenes (ST). Antioxidant activity (AA, mmol TE /g fresh berry) was determined by DPPH method. The results were submitted to a two-way ANOVA to investigate the influence of variety, area and their interaction for each polyphenolic family and cluster analysis was used to construct hierarchical dendrograms, searching the natural groupings among the samples. Sanguina (A3) had the most of total polyphenols while Tempranillo (A5) those of ANT. Sanguina (A2) and (A3) reached the highest values of FLAVO, FLAVA and AA. These two last samples had also the maximum of AA. The effect cultivar and area were significant for all polyphenolic families analyzed. A high variability due to variety (>50%) was observed in FLAVA and the maximum value of variability due to growing area was detected in AA (86.41%), ANT and FLAVO (51%); the interaction variety*zone was significant only for ANT, FLAVO, EST and AA. Finally, dendrograms presented five cluster: i) Sanguina (A2); ii) Sanguina (A3); iii) Tempranillo (A5); iv) Tempranillo (A3); Terriza (A3,A5), Morate (A5,A6); v) Santafé (A1,A6); Tortozona tinta (A1,A3,A6); Tinta Jeromo (A3,A4).

Grape berry size is a key factor in determining New Zealand Pinot noir wine composition

Making high quality but affordable Pinot noir (PN) wine is challenging in most terroirs and New Zealand’s (NZ) situation is no exception. To increase the probability of making highly typical PN wines producers choose to grow grapes in cool climates on lower fertility soils while adopting labour intensive practices. Stringent yield targets and higher input costs necessarily mean that PN wine cost is high, and profitability lower, in line-priced varietal wine ranges. To understand the reasons why higher yielding vines are perceived to produce wines of lower quality we have undertaken an extensive study of PN in NZ. Since 2018, we established a network of twelve trial sites in three NZ regions to find individual vines that produced acceptable commercial yields (above 2.5kg per vine) and wines of composition comparable to “Icon” labels. Approximately 20% of 660 grape lots (N = 135) were selected from within a narrow juice Total Soluble Solids (TSS) range and made into single vine wines under controlled conditions. Principal Component Analysis of the vine, berry, juice and wine parameters from three vintages found grape berry mass to be most effective clustering variable. As berry mass category decreased there was a systematic increase in the probability of higher berry red colour and total phenolics with a parallel increase in wine phenolics, changed aroma fraction and decreased juice amino acids. The influence of berry size on wine composition would appear stronger than the individual effects of vintage, region, vineyard or vine yield. Our observations support the hypothesis that it is possible to produce PN wines that fall within an “Icon” benchmark composition range at yields above 2.5kg per vine provided that the Leaf Area:Fruit Weight ratio is above 12cm2 per g, mean berry mass is below 1.2g and juice TSS is above 22°Brix.

Bioclimatic shifts and land use options for Viticulture in Portugal

Land use, plays a relevant role in the climatic system. It endows means for agriculture practices thus contributing to the food supply. Since climate and land are closely intertwined through multiple interface processes, climate change may lead to significant impacts in land use. In this study, 1-km observational gridded datasets are used to assess changes in the Köppen–Geiger and Worldwide Bioclimatic (WBCS)

Short-term relationships between climate and grapevine trunk diseases in southern French vineyards

[lwp_divi_breadcrumbs home_text="IVES" use_before_icon="on" before_icon="||divi||400" module_id="publication-ariane" _builder_version="4.19.4" _module_preset="default" module_text_align="center" module_font_size="16px" text_orientation="center"...