terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Abstract

Spain is the country with the largest wine-producing area in the EU and its productivity is largely controlled applying fungicides. However, residues of these compounds can move and contaminate surface and groundwater. The objective of this work was to evaluate the capacity of bioadsorbents from different origin to adsorb and immobilize tetraconazole by themselves or when applied as organic soil amendment, and to prevent soil and water contamination by this fungicide. The adsorption of tetraconazole by 3 organic residues: spent mushroom substrate (SMS), green compost (GC) and vine pruning sawdust (VP), as well as by vineyard soils unamended and amended individually with these residues at 1.5% (w/w) was evaluated using the batch equilibrium technique. Two vineyard soils from La Rioja were selected (S1-sandy loam, 0.26% OC; and S2-clay loam, 0.69% OC). Freundlich Kf adsorption constants of tetraconazole (3.6-19.2) by unamended and amended soils increased in the order: S1 < S2 < S2+GC < S2+VP < S1+VP ≈ S1+GC < S2+SMS < S1+SMS; and for the residues in the order: GC < VP < SMS. The Kf values of amended soils, especially for SMS-amended soils, were higher than those of unamended soils, due to their higher OC content. The application of organic residues to S1 soil increased its Kf value between 3.7-5.4 times, and that of S2 soil up to 2.7 times. However, the Kf values of S1 soil amended with the different organic residues were higher than those of amended S2 soils, despite their lower OC content. Therefore, physicochemical characteristics of soils different from OC (pH, carbonates, clay content, etc.) may also play an important role on the adsorption of tetraconazole by amended soils as observed for other fungicides.

Acknowledgements: We give thanks to Project TED2021-129962B-C41, funded by MCIN/AEI/10.13039/501100011033/ and the European Union (NextGenerationEU/PRTR).

DOI:

Publication date: October 10, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Asier Barrio1, M. Soledad Andrades2, M. Sonia Rodríguez-Cruz1, Jesús M. Marín-Benito1*

Institute of Natural Resources and Agrobiology of Salamanca (IRNASA, CSIC), Cordel de Merinas 40-52, 37008 Salamanca, Spain.
2 Agriculture and Food Department, University of La Rioja, Madre de Dios 51, 26006 Logroño, Spain.

Contact the author*

Keywords

adsorption, fungicide, vineyard soil, conservation, organic amendment

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Sustainable management of grapevine trunk diseases

Grapevine trunk diseases (GTD) occur wherever grapes are grown and are considered the main biotic factor reducing yields and shortening vineyards’ lifespan. Currently, no product is available to eradicate GTD once grapevines are infected. Therefore, prophylactic strategies based on pruning wound protection and ‘remedial surgery’, the only eradication method based on the elimination of infected wood and renewal of the vine by means of new canes or suckers, are the only effective strategies available. The Canadian grape and wine industry focusses on a sustainable production and thus, looking for alternatives to chemicals for disease management is a top priority.

Sparkling wines and atypical aging: investigating the risk of refermentation

Sparkling wine (SW) production entails a two-steps process where grape must undergoes a primary fermentation to produce a base wine (BW) which is then refermented to become a SW. This process allows for the development of a new physicochemical profile characterized by the presence of foam and a different organoleptic profile.

Distribution and sensory impact of new oak wood-derived compounds in wines

Despite the numerous research studies carried out in recent years, the study of wine aroma remains of great interest due to its complexity. Wine maturation in oak barrels is described as an important step in the production of quality wines. In fact, oak wood develops several aromatic nuances through its toasting which can be released into the wine. A great deal of work has been performed in order to identify the wood-derived volatile compounds that contribute to wine aroma (e.g., whisky-lactone, maltol, eugenol, guaiacol, vanillin).

The weak role of organic mulches in shaping bacterial communities in grapevine

The interest in sustainable and ecologic agricultural practices in grapevine has grown significantly in recent years in the context of ecological transition. Organic mulches are treatments that support the circular economy and positively affect the soil and the plant. They are an alternative to herbicides and other conventional practices since they may influence soil moisture, erosion, structure and weed control. However, their effects on the soil and must microbiota remain unknown.

Impact of toasting and botanical origin on oak wood (Q. sp.) volatilome using untargeted GCxGC-ToFMS analysis

Many works have been carried out to identify the key aroma volatile compounds of oak wood (e.g., whisky-lactone, furfural, maltol, eugenol, guaiacol, vanillin) using conventional gas chromatography coupled with olfactometry and mass spectrometry (GC-O-MS). Inspired by recent untargeted approaches in the field of food “omics”, this work aims to extend our knowledge on the impact of cooperage process on the volatile composition of oak wood using two-dimensional comprehensive gas chromatography coupled with time of flight mass spectrometry (GCxGC-ToFMS).