terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Abstract

Spain is the country with the largest wine-producing area in the EU and its productivity is largely controlled applying fungicides. However, residues of these compounds can move and contaminate surface and groundwater. The objective of this work was to evaluate the capacity of bioadsorbents from different origin to adsorb and immobilize tetraconazole by themselves or when applied as organic soil amendment, and to prevent soil and water contamination by this fungicide. The adsorption of tetraconazole by 3 organic residues: spent mushroom substrate (SMS), green compost (GC) and vine pruning sawdust (VP), as well as by vineyard soils unamended and amended individually with these residues at 1.5% (w/w) was evaluated using the batch equilibrium technique. Two vineyard soils from La Rioja were selected (S1-sandy loam, 0.26% OC; and S2-clay loam, 0.69% OC). Freundlich Kf adsorption constants of tetraconazole (3.6-19.2) by unamended and amended soils increased in the order: S1 < S2 < S2+GC < S2+VP < S1+VP ≈ S1+GC < S2+SMS < S1+SMS; and for the residues in the order: GC < VP < SMS. The Kf values of amended soils, especially for SMS-amended soils, were higher than those of unamended soils, due to their higher OC content. The application of organic residues to S1 soil increased its Kf value between 3.7-5.4 times, and that of S2 soil up to 2.7 times. However, the Kf values of S1 soil amended with the different organic residues were higher than those of amended S2 soils, despite their lower OC content. Therefore, physicochemical characteristics of soils different from OC (pH, carbonates, clay content, etc.) may also play an important role on the adsorption of tetraconazole by amended soils as observed for other fungicides.

Acknowledgements: We give thanks to Project TED2021-129962B-C41, funded by MCIN/AEI/10.13039/501100011033/ and the European Union (NextGenerationEU/PRTR).

DOI:

Publication date: October 10, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Asier Barrio1, M. Soledad Andrades2, M. Sonia Rodríguez-Cruz1, Jesús M. Marín-Benito1*

Institute of Natural Resources and Agrobiology of Salamanca (IRNASA, CSIC), Cordel de Merinas 40-52, 37008 Salamanca, Spain.
2 Agriculture and Food Department, University of La Rioja, Madre de Dios 51, 26006 Logroño, Spain.

Contact the author*

Keywords

adsorption, fungicide, vineyard soil, conservation, organic amendment

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Exploring intra-vineyard variability with sensor- and molecular-based approaches 

The application of remote and proximal sensing is a fast and efficient method to monitor grapevine vegetative and physiological parameters and is considered valuable to derive information on associated yield and quality traits in the vineyard. Further details can be obtained by the application of molecular analysis at the gene expression level aiming at elucidating how pathways controlling the formation of different grape quality traits are influenced by spatial variability. This work aims at evaluating intra-vineyard variability in grape composition at harvest and at comparing this with remotely sensed canopy vegetation data and molecular-based approaches.

A novel approach for the identification of new biomarkers of wine consumption in human urine using untargeted metabolomics

Wine is one of the most representative components of Mediterranean diet. Moderate wine intake together with food, has been positively correlated with reduced risk of many chronic diseases. This beneficial effect seems to be ascribed to elevated polyphenolic content of wine [1]. Traditional approaches for the identification of wine biomarkers consumption include targeted metabolomics that focuses on the quantification of well-defined metabolites, losing a valuable information about a massive number of compounds. On the other hand, untargeted metabolomics can disclose a large quantity of signals corresponding to potential biomarkers in a single analysis with high sensitivity and resolution.

Sugar accumulation disorder Berry Shrivel – from current knowledge towards novel hypothesis

In contrast to fruit and grape berry ripening, the biological processes causing ripening disorders are often much less understood, although shriveling disorders of fruits are manifold and contribute to yield losses and reduced fruit quality worldwide. Shrinking berries are a common feature for all shriveling disorders in grapevine although their timing of appearance during the berry ripening process and their underlying induction processes distinct them from each other. The sugar accumulation disorder Berry Shrivel (BS) is characterized by a suppression of sugar accumulation short after veraison resulting in berries low in sugar content and anthocyanins in berry skins, while the organic acid content is similar. Recent studies analyzed the biochemical, morphological and molecular processes affected in BS berries and linked early changes to the period of ripening onset [1,2].

Effect of foliar application of Ca, Si and their combination on grape volatile composition

Calcium (Ca) is an important nutrient for plants which plays key signaling and structural roles. It has been observed that exogenous Ca application favors the pectin accumulation and inhibition of polygalacturonase enzymes, minimizing fruit spoilage. Silicon (Si) is a non-essential element which has been found to be beneficial for improving crop yield and quality, as well as plant tolerance to diverse abiotic and biotic stress factors. The effect of Si supply to grapevine has been assessed in few investigations, which reported positive changes in grape quality and must composition.

The weak role of organic mulches in shaping bacterial communities in grapevine

The interest in sustainable and ecologic agricultural practices in grapevine has grown significantly in recent years in the context of ecological transition. Organic mulches are treatments that support the circular economy and positively affect the soil and the plant. They are an alternative to herbicides and other conventional practices since they may influence soil moisture, erosion, structure and weed control. However, their effects on the soil and must microbiota remain unknown.