terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Crown procyanidin quantification in red wines, rosé wines and Port wines

Crown procyanidin quantification in red wines, rosé wines and Port wines

Abstract

Condensed grape tannins play a major role in the organoleptic properties and quality of red wine. Recently, a new sub-family of macrocyclic condensed tannins has been identified in red wine and named “crown tannins”. Indeed, the first compound of the family identified and characterised by NMR was the crown procyanidin tetramer which is composed of a macrocyclic structure composed of four (-)-epicatechins link together by B-type interflavanoid linkage in the following an alternative sequences of C4-C8 and C4-C6 linkage. The 3D structure of this unusual crown procyanidin family reveals a central cavity in the molecule [1]. Moreover, this crown procyanidin tetramer has a very specific physicochemical characteristics and properties compared with non-cyclic condensed tannins [2]. Apart from the procyanidin tetramer, many other crown tannins have been detected by UPLC-UV-QTof, such as galloylated tetramers and pentamers. Moreover, recent study showed that these molecules are specifically located in grapes skin and their concentration in red wine depends of the grape varieties.

Thus following or previous work regarding the validation of a quantification method by UPLC-UV-QTof, the evolution kinetics of crown procyanidins family (tetramer, galloylated tetramer and pentamer) during wine aging in bottles over multiple vintages has been investigated. This evolution kinetic has been investigated in various wine matrices, such as red wine, rosé wine and port wine, in order to gain a better understanding of their evolution and impact in the various colloidal matrices. Moreover, this evolution kinetics has been compared with non-cyclic condensed tannins.

References:
1) Zeng, L.et al. (2019) Crown Procyanidin Tetramer: A Procyanidin with an Unusual Cyclic Skeleton with a Potent Protective Effect against Amyloid-β-Induced Toxicity. Molecules24: 1915, DOI 10.3390/molecules24101915

2) Jouin A et al. (2022) Evolution of the Crown Procyanidins’ Tetramer during Winemaking and Aging of Red Wine. Foods, 11: 3194. DOI10.3390/foods11203194

DOI:

Publication date: October 16, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Ferreira M. 1*., Teissedre PL.1, Jourdes M. 1

1 University Bordeaux, Bordeaux INP, Bordeaux Sciences Agro, INRAE, UMR 1366, OENO, ISVV F33140 Villenave d’Ornon, France

Contact the author*

Keywords

wines, condensed tannins, crown tannins, UPLC-UV-QTof

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Grapevine adaptation to drought and resistance to Neofusicoccum parvum, causal agent of Botryosphaeria dieback

The sustainability of viticulture in response to climate change has been addressed mainly considering agronomic impacts, such as water management and diseases, either separately or together.
In grapevines, there is strong evidence that different genotypes respond differently to biotic and abiotic stresses. A screening was conducted on various local cultivars in response to drought and Neofusicoum parvum infection aiming to evaluate their susceptibility to abiotic stress and resistance to fungal diseases.

The use of δ13C as an indicator of water use efficiency for the selection of drought tolerant grapevine varieties

In the context of climate change with increasing evaporative demand, understanding the water use behavior of different grapevine cultivars is of critical importance. Carbon isotope discrimination (δ13C) measurements in wine provide a precise and integrated assessment of the water status of the vines during the sugar accumulation period in grape berries. When collected over multiple vintages on different cultivars, δ13C measurements can also provide insights into the effects of genotype on water use efficiency.

Moderate wine consumption – part of a balanced diet or a health risk?

Consumption of wine/alcoholic beverages remains a topic of great uncertainty and controversy worldwide. The term “no safe level” dominates the media communication and policy ever since population studies in 2018 [1,2] were published, which denied the existence of a J-curve and suggested that ANY consumption of an alcoholic beverage is harmful to health. The scientific evidence accumulated during the past decades about the health benefits of moderate wine consumption, were questioned and drinking guidelines considered to be too loose.

Role of anthocyanins and copigmentation in flavonol solubility in red wines 

Over the last years, due to climate change, several red wines, such as the Sangiovese wines, have been often subjected to loss of clarity due to the formation of deposits of fine needle-shaped crystals. This phenomenon turned out to be due to an excess of quercetin (Q) and its glycosides (Q-Gs) in wines. These compounds are synthesized to a large extent when grapes are excessively exposed to UVB radiations in vineyards[1]. Unfortunately, it is not easy to predict the degree of Q precipitation because its solubility strongly depends on the wine and matrix composition[2].

A sensometabolomic approach to understand wine mouthfeel percepts

Targeted analytical methods can overlook compounds that are a priori unknown to play a role in the mouthfeel sensations. This limitation can be overcome with the information provided by untargeted metabolomic analysis using UPLC‐QTOF-MS. To this end, an untargeted metabolomic approach applied to 42 red wines has allowed development of a model with predictive capacity by cross-validation for the “dry”, “oily” and “unctuous” sensations perceived by a sensory panel. The optimal PLS model for “dry” retained compounds with positive regression coefficients (≥ 0.17) including a trimer procyanidin, a peptide, and four anthocyanins.