Macrowine 2021
IVES 9 IVES Conference Series 9 Oxygen consumption by diferent oenological tanins in a model wine solution

Oxygen consumption by diferent oenological tanins in a model wine solution

Abstract

Oenological tannins are widely used in winemaking to improve some characteristics of wines [1] being the antioxidant properties probably one of the main reasons [2]. However, commercial tannins have different botanical sources and chemical composition [3] which probably determines different antioxidant potential. There are some few references about the antioxidant properties of commercial tannins [4] but none of them have really measured the direct oxygen consumption by them. The aim of this work was to measure the kinetics of oxygen consumption by different commercial tannins in order to determine their real capacities to protect wine against oxygen. MATERIAL AND METHODS: 4 different commercial tannins were used: T1: condensed tannin from grape seeds, T2: gallotannin from chinese gallnuts, T3: ellagitannin from oak and T4: tannin from quebracho containing condensed tannins and ellagitannins. All tannins were dissolved at different concentration in a model wine solution. The samples were placed in clear glass bottles into which a pill had been inserted (PreSens Precision Sensing GmbH) for the non-invasive measurement of dissolved oxygen by luminescence (NomasenseTM O2 Trace Oxigen Analyzer). The different solutions were saturated in oxygen by bubbling with air for 10 minutes. Once the bottles had been closed with a crown cap and bidule, oxygen was measured periodically [5]. RESULTS: The obtained results were used to develop a kinetic model in order to parameterize and compare the oxygen consumption rates of the different oenological tannins. Using this kinetic model it was possible to determine the average initial oxygen consumption rate (OCR) for the different commercial tannins. These results indicate that ellagitannins from oak (T3) are clearly the most effective as antioxidant with an OCR of 193.0 µg of O2/hour. Condensed tannins from grape seeds (T1) showed a OCR quite much lower (27.1 µg of O2/hour). In turn, tannins from quebracho (T4) showed an OCR intermediate between T3 and T1 (66.5 µg of O2/hour) which is quite logical since tannins from this botanical source contains ellagitannins and condensed tannins. Finally, gallotannins from chinese gallnuts (T2) showed the lowest OCR (6.9 µg of O2/hour). CONCLUSIONS: Ellagitannins have a capacity for oxygen consumption far greater than condensed tannins and especially than gallotannins. Consequently, ellagitannins are among the oenological tannins which are better able to protect the wine from oxidation.

REFERENCES: [1] Zamora F. (2003) Enólogos, 25, 26-30 [2] Versari, A., du Toit, W., Parpinello, G.P. (2013). Aust. J. Grape Wine Res., 19, 1-10. [3] Obreque-Slíer ; E., Peña-Neira, A., López-Solís , R., Ramírez-Escudero, C., Zamora, F. (2009) Eur Food Res Technol, 229, 859-866 [4] Magalhaes, L.M., Ramos, I.I., Reis, S., Segundo, M.A. (2014) Aust. J. Grape Wine Res., 20, 72-79. [5]Diéval, J.B., Vidal, S., Aagaard, O. (2011). Packag. Technol. Sci., 24, 375-385.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Fernando Zamora*, Esteban García-Romero, Isidro Hermosín-Gutíerrez, Joan Miquel Canals, Jordi Gombau, María Navarro, Olga Pascual, Sergio Gómez-Alonso

*Universitat Rovira i Virgili

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The effect of Nitrogen and Sulphur foliar applications in hot climates

ine nitrogen deficiency can negatively influence the aroma profile and ageing potential of white wines. Canopy management can alter vine microclimate, affect the nitrogen availability and influence the response of leaf senescence. Increasing the nitrogen availability to vines can increase the Yeast Assimilable Nitrogen (YAN) levels in harvested fruit and wine. Studies show that foliar nitrogen and sulphur applications at véraison, on low YAN Sauvignon blanc grapes have an effect on the level of amino acids (Jreij et al. 2009) and on S-containing compounds such as glutathione and thiols (Lacroux et al. 2008), which in turn can influence the formation of major volatiles and the aroma profile of the wine.

A combination of biotechnology tools and coopers elements for an alternative the addition of SO2 at the end of the malolactic fermentation in red wines or at the “mutage” for the “liquoreux” wines

In red wines the post-MLF SO2 addition is an essential event. It is also the case for the “mutage” during the elaboration of the “liquoreux”. At these moments SO2 plays an antimicrobial action and an antioxidant effect. But at current pH of wines, ensuring a powerful molecular SO2 has become very difficult. Recent work on Brettanomyces strains have also shown that some strains are resistant up to 1.2 mg / L of molecular SO2. It’s also the case of the some Saccharomuces or Zygosaccharomyces strains suitable to re-ferment “liquoreux” wines after the “mutage”.

Simultaneous monitoring of dissolved CO2 and collar from Rosé sparkling wine glasses: the impact of yeast macromolecules

Champagne or sparkling wines elaborated through the same traditional method, which consists in two major yeast-fermented steps, typically hold about 10 to 12 g/L of dissolved CO2 after the second fermentation in a closed bottle. Hundreds of molecules and macromolecules originating from grape and yeast cohabit with dissolved CO2; they are essential compounds contributing to many organoleptic characteristics (effervescence, foam, aroma, taste, colour…). Indeed, the second alcoholic fermentation and the maturation on lees (which may last from 12 months up to several years) both induce various quantitative and qualitative changes in the wine through the action of yeast, as listed hereafter: development of aromas during aging on lees, release of nitrogen compounds during autolysis and release of macromolecules (polysaccharides, lipids, nucleic acids) in wine.

Effect of mixed Torulaspora delbrueckii-Saccharomyces cerevisiae culture on rose quality wine

Alcoholic fermentation using no Saccharomyces wine is an effective means of modulating wine aroma. This study investigated the impact of coinoculating Torulaspora delbruecki with two Saccharomyces cerevisiae commercial yeast (QA23, Lallemand; Red Fruit, Sepsa-Enartis) on enological quality parameters, volatile composition and sensory analysis. The following assays were performed on Tempranillo variety: Saccharomyces QA23 (CTQA), Saccharomyces Red Fruit (CTRF), coinoculated T. delbrueckii + S.cerevisiae QA23 (CIQA) and coinoculated T. delbrueckii + S.cerevisiae (CIRF).

Glutathione content evolution during spontaneous alcoholic fermentations of Sangiovese grapes

Glutathione is a tripeptide (γ-Glu-Cys-Gly), which can occur in grapes, in must and in wine prevalently in the reduced form as well as in the oxidized form as glutathione disulfide. The importance of the reduced form of glutathione lies in its antioxidant activity. In must, it limits browning by reducing o-quinones produced by polyphenol oxidase activity on hydroxycinnamic acids; in wine, it exerts a protective effect on various aromatic compounds. Glutathione concentration in wine is lower than in grape juice and variable as it depends on several factors, ranging from the native content of grapes to winemaking technique.