Macrowine 2021
IVES 9 IVES Conference Series 9 Oxygen consumption by diferent oenological tanins in a model wine solution

Oxygen consumption by diferent oenological tanins in a model wine solution

Abstract

Oenological tannins are widely used in winemaking to improve some characteristics of wines [1] being the antioxidant properties probably one of the main reasons [2]. However, commercial tannins have different botanical sources and chemical composition [3] which probably determines different antioxidant potential. There are some few references about the antioxidant properties of commercial tannins [4] but none of them have really measured the direct oxygen consumption by them. The aim of this work was to measure the kinetics of oxygen consumption by different commercial tannins in order to determine their real capacities to protect wine against oxygen. MATERIAL AND METHODS: 4 different commercial tannins were used: T1: condensed tannin from grape seeds, T2: gallotannin from chinese gallnuts, T3: ellagitannin from oak and T4: tannin from quebracho containing condensed tannins and ellagitannins. All tannins were dissolved at different concentration in a model wine solution. The samples were placed in clear glass bottles into which a pill had been inserted (PreSens Precision Sensing GmbH) for the non-invasive measurement of dissolved oxygen by luminescence (NomasenseTM O2 Trace Oxigen Analyzer). The different solutions were saturated in oxygen by bubbling with air for 10 minutes. Once the bottles had been closed with a crown cap and bidule, oxygen was measured periodically [5]. RESULTS: The obtained results were used to develop a kinetic model in order to parameterize and compare the oxygen consumption rates of the different oenological tannins. Using this kinetic model it was possible to determine the average initial oxygen consumption rate (OCR) for the different commercial tannins. These results indicate that ellagitannins from oak (T3) are clearly the most effective as antioxidant with an OCR of 193.0 µg of O2/hour. Condensed tannins from grape seeds (T1) showed a OCR quite much lower (27.1 µg of O2/hour). In turn, tannins from quebracho (T4) showed an OCR intermediate between T3 and T1 (66.5 µg of O2/hour) which is quite logical since tannins from this botanical source contains ellagitannins and condensed tannins. Finally, gallotannins from chinese gallnuts (T2) showed the lowest OCR (6.9 µg of O2/hour). CONCLUSIONS: Ellagitannins have a capacity for oxygen consumption far greater than condensed tannins and especially than gallotannins. Consequently, ellagitannins are among the oenological tannins which are better able to protect the wine from oxidation.

REFERENCES: [1] Zamora F. (2003) Enólogos, 25, 26-30 [2] Versari, A., du Toit, W., Parpinello, G.P. (2013). Aust. J. Grape Wine Res., 19, 1-10. [3] Obreque-Slíer ; E., Peña-Neira, A., López-Solís , R., Ramírez-Escudero, C., Zamora, F. (2009) Eur Food Res Technol, 229, 859-866 [4] Magalhaes, L.M., Ramos, I.I., Reis, S., Segundo, M.A. (2014) Aust. J. Grape Wine Res., 20, 72-79. [5]Diéval, J.B., Vidal, S., Aagaard, O. (2011). Packag. Technol. Sci., 24, 375-385.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Fernando Zamora*, Esteban García-Romero, Isidro Hermosín-Gutíerrez, Joan Miquel Canals, Jordi Gombau, María Navarro, Olga Pascual, Sergio Gómez-Alonso

*Universitat Rovira i Virgili

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Use of glutathione under different grape processing and winemaking conditions and its impact on the formation of sulfide off-flavors, colour, and sensory characteristics of Riesling, Sauvignon blanc, and Chardonnay

The use of glutathione (GSH) in winemaking has been legitimated recently, according to OIV resolutions OENO 445-2015 and OENO 446-2015 a maximum dose of 20 mg/L is now allowed to use in must and wine. Several studies have proven the benefits of GSH, predominantly in Sauvignon blanc. Thus, oxidative coloration of must and wine is limited, aroma compounds such as volatile thiols are preserved, and the development of ageing flavors such as sotolon and 2-aminoacetophenone is impeded. The protective effect may be explained by the high affinity of GSH to bind o-quinones which are formed during phenolic oxidation and which are known to initiate browning and other oxidative changes. Some researchers have proposed the hydroxycinnamic acid to GSH ratio (HGR) as an indicator of oxidation susceptibility of must and could show that lower ratios yielded lighter musts.

What about oxygen transfer during wine aging in barrels?

During wine aging, several complex phenomena of gas transfer take place in barrels due to the wine/oak contact. The efficiency of this gas transfer varies according to oak wood’s intrinsic physical properties. This research aims to better understand oxygen transfer phenomena through dry oak staves and especially through stave gaps, in order to reevaluate the importance of barrel-making on a barrel’s supply of oxygen. Experimentation was based on the development of an innovative permeameter of laboratory scale, for which the principal operating conditions concerning applied pressure, the choice of liquid phase/gas phase, and the grain type of oak are taken into account and investigated. With a specially developed tightening system, the existing pressure at stave gaps in a barrel could be reproduced on a laboratory scale in order to estimate its influence on oxygen transfer efficiency.

Impact of heating must before fermentation on Chardonnay wines

Prefermentation steps of white winemaking are very important for controlling the stability and the sensory attributes of wines. Usually musts are clarified by cold settling to prevent the start of the fermentation, before racking big lees and thus limiting the appearance of vegetable or reduction off flavour while favouring an aromatic expression with low turbidity. Besides, to reach the protein stability, some white wines further require a bentonite fining, sometimes associated with negative effects on the sensory quality. This study aims to know the impact of musts heating after pressing on a Chardonnay wine in northern conditions by comparison with a classic cold racking of the must.

Study of the colour and phenolic evolution of three different tannin/anthocyanin ratios over time in a model wine

Phenolic compounds are important quality indicators in red wine. A large number of polyphenols play an important role in wine development, contributing to the colour and the sensory perception of the wines. Anthocyanins are the pigments responsible for the colour in young red wines while tannins are the principal contributors to the bitterness and the astringency of the wines. Wine polyphenols are considered more complex molecules than grape phenolics, due to the enormous number of chemical reactions which take place during the entire winemaking process and storage, forming more stable compounds.

Study of the volatil profile of minority white varieties

The genetic material preservation is a priority issue in winemaking research. The recovery of minority grape varieties can control the genetic erosion, contributing also to preserve wine typical characteristics. In D.O.Ca. Rioja (Spain) the number of grown white varieties has been very limited, representing Viura the 91% of the cultivated white grape area in 2005, while the others, Garnacha Blanca and Malvasía riojana, hardly were grown. For this reason, a recovery and characterization study of plant material was carried out in this region. In 2008, the results obtained allowed the authorization of three minority white varieties: Tempranillo Blanco, Maturana Blanca and Turruntés.