Macrowine 2021
IVES 9 IVES Conference Series 9 Oxygen consumption by diferent oenological tanins in a model wine solution

Oxygen consumption by diferent oenological tanins in a model wine solution

Abstract

Oenological tannins are widely used in winemaking to improve some characteristics of wines [1] being the antioxidant properties probably one of the main reasons [2]. However, commercial tannins have different botanical sources and chemical composition [3] which probably determines different antioxidant potential. There are some few references about the antioxidant properties of commercial tannins [4] but none of them have really measured the direct oxygen consumption by them. The aim of this work was to measure the kinetics of oxygen consumption by different commercial tannins in order to determine their real capacities to protect wine against oxygen. MATERIAL AND METHODS: 4 different commercial tannins were used: T1: condensed tannin from grape seeds, T2: gallotannin from chinese gallnuts, T3: ellagitannin from oak and T4: tannin from quebracho containing condensed tannins and ellagitannins. All tannins were dissolved at different concentration in a model wine solution. The samples were placed in clear glass bottles into which a pill had been inserted (PreSens Precision Sensing GmbH) for the non-invasive measurement of dissolved oxygen by luminescence (NomasenseTM O2 Trace Oxigen Analyzer). The different solutions were saturated in oxygen by bubbling with air for 10 minutes. Once the bottles had been closed with a crown cap and bidule, oxygen was measured periodically [5]. RESULTS: The obtained results were used to develop a kinetic model in order to parameterize and compare the oxygen consumption rates of the different oenological tannins. Using this kinetic model it was possible to determine the average initial oxygen consumption rate (OCR) for the different commercial tannins. These results indicate that ellagitannins from oak (T3) are clearly the most effective as antioxidant with an OCR of 193.0 µg of O2/hour. Condensed tannins from grape seeds (T1) showed a OCR quite much lower (27.1 µg of O2/hour). In turn, tannins from quebracho (T4) showed an OCR intermediate between T3 and T1 (66.5 µg of O2/hour) which is quite logical since tannins from this botanical source contains ellagitannins and condensed tannins. Finally, gallotannins from chinese gallnuts (T2) showed the lowest OCR (6.9 µg of O2/hour). CONCLUSIONS: Ellagitannins have a capacity for oxygen consumption far greater than condensed tannins and especially than gallotannins. Consequently, ellagitannins are among the oenological tannins which are better able to protect the wine from oxidation.

REFERENCES: [1] Zamora F. (2003) Enólogos, 25, 26-30 [2] Versari, A., du Toit, W., Parpinello, G.P. (2013). Aust. J. Grape Wine Res., 19, 1-10. [3] Obreque-Slíer ; E., Peña-Neira, A., López-Solís , R., Ramírez-Escudero, C., Zamora, F. (2009) Eur Food Res Technol, 229, 859-866 [4] Magalhaes, L.M., Ramos, I.I., Reis, S., Segundo, M.A. (2014) Aust. J. Grape Wine Res., 20, 72-79. [5]Diéval, J.B., Vidal, S., Aagaard, O. (2011). Packag. Technol. Sci., 24, 375-385.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Fernando Zamora*, Esteban García-Romero, Isidro Hermosín-Gutíerrez, Joan Miquel Canals, Jordi Gombau, María Navarro, Olga Pascual, Sergio Gómez-Alonso

*Universitat Rovira i Virgili

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Chemical markers in wine related to low levels of yeast available nitrogen in the grape

Nitrogen is an important nutrient of yeast and its low content in grape must is a major cause for sluggish fermentations. To prevent problems during fermentation, a supplementation of the must with ammonium salts or more complex nitrogen mixtures is practiced in the cellar. However this correction seems to improve only partially the quality of wine [1]. In fact, yeast is using nitrogen in many of its metabolic pathways and depending of the sort of the nitrogen source (ammonium or amino acids) it produces different flavor active compounds. A limitation in amino acids can lead to a change in the metabolic pathways of yeast and consequently alter wine quality.

Determination of metallic elements in Chilean wines by atomic absorption spectroscopy and inductively coupled plasma–mass spectrometry

The chemical composition of wines depends on series of variables such as the type of grape, edaphoclimatic conditions, and viticulture and winemaking practices employed during production. Metallic elements play a significant role during winemaking (e.g. as catalysts of oxidation reactions) and have been previously employed for the classification of wines according to provenance. In this work, we focused on the analysis of metallic elements (K, Na, Ca, Zn, Cu, Fe, Mg, Mn, Ni, Cr, Al, Pb, Cd, Hg, Se, Co, Sn and As) in 145 Chilean wine samples (102 reds and 43 white wines), of seven grape varieties, and five of the major wine producing regions in Chile.

Impact of industrial-scale serial filtration on macromolecules in red wines

Filtration is a critical step in ensuring the clarity and microbial stability of wine prior to bottling. However the process of filtering potentially reduces red wine quality by removing some of the macromolecules that contribute to the texture of the wine. Commercial red wines, Cabernet Sauvignon (CAS) and Shiraz (SHZ), of two vintages and two grades (premium grade wines from the older vintage: CAS13 and SHZ13; and standard grade wines from a younger vintage: CAS14 and SHZ14) were filtered through industrial-scale commercial filtration units prior to bottling. Samples were taken before and after cross-flow filtration, lenticular filters, 0.65 µm and 0.45 µm pore size nylon membrane filters. The concentration and composition of macromolecules, including tannins and polysaccharides, were measured in all samples as well as particle size distribution and wine colour.

Estimation of chemical age of red wines with the use of Fourier transform infrared spectroscopy (FT-IR) and chemometrics

The color of a red wine is one of the most important parameters of its quality, giving much information on its status, such as the grape variety used or the winemaking style. As the result of a complex equilibrium between different forms of anthocyanins and polymerization reactions which occur over the course of time, color can also serve as an indication of a wines’ age. For this purpose the “chemical age” i and ii indexes have been introduced by Somers in 1977. The chemical age index i measures the color absorbance after the addition of acetaldehyde while chemical index ii provides an indication of how much of the total red pigments are resistant to SO2 bleaching.

Foam characteristics of white, rosé and red sparkling wines elaborated by the champenoise method

Contribution Foam is the characteristic that differentiates sparkling wines from still wines, being the first sensory attribute that tasters and consumers perceive and that determines the final quality of sparkling wines [1]. The foaming properties mainly depend on the chemical composition of wines [2-3], and different factors involved in wine composition will have an effect on foam quality. In Spain, the sparkling wine market focuses on the production of white and rosé sparkling wine, with very low production of red sparkling wines. However, this type of wines is elaborated in countries like Australia, South-Africa, Argentina, Italy or Portugal, with a great acceptance by consumers. No studies on the foaming characteristics of red sparkling wines have been found.