Macrowine 2021
IVES 9 IVES Conference Series 9 Oxygen consumption by diferent oenological tanins in a model wine solution

Oxygen consumption by diferent oenological tanins in a model wine solution

Abstract

Oenological tannins are widely used in winemaking to improve some characteristics of wines [1] being the antioxidant properties probably one of the main reasons [2]. However, commercial tannins have different botanical sources and chemical composition [3] which probably determines different antioxidant potential. There are some few references about the antioxidant properties of commercial tannins [4] but none of them have really measured the direct oxygen consumption by them. The aim of this work was to measure the kinetics of oxygen consumption by different commercial tannins in order to determine their real capacities to protect wine against oxygen. MATERIAL AND METHODS: 4 different commercial tannins were used: T1: condensed tannin from grape seeds, T2: gallotannin from chinese gallnuts, T3: ellagitannin from oak and T4: tannin from quebracho containing condensed tannins and ellagitannins. All tannins were dissolved at different concentration in a model wine solution. The samples were placed in clear glass bottles into which a pill had been inserted (PreSens Precision Sensing GmbH) for the non-invasive measurement of dissolved oxygen by luminescence (NomasenseTM O2 Trace Oxigen Analyzer). The different solutions were saturated in oxygen by bubbling with air for 10 minutes. Once the bottles had been closed with a crown cap and bidule, oxygen was measured periodically [5]. RESULTS: The obtained results were used to develop a kinetic model in order to parameterize and compare the oxygen consumption rates of the different oenological tannins. Using this kinetic model it was possible to determine the average initial oxygen consumption rate (OCR) for the different commercial tannins. These results indicate that ellagitannins from oak (T3) are clearly the most effective as antioxidant with an OCR of 193.0 µg of O2/hour. Condensed tannins from grape seeds (T1) showed a OCR quite much lower (27.1 µg of O2/hour). In turn, tannins from quebracho (T4) showed an OCR intermediate between T3 and T1 (66.5 µg of O2/hour) which is quite logical since tannins from this botanical source contains ellagitannins and condensed tannins. Finally, gallotannins from chinese gallnuts (T2) showed the lowest OCR (6.9 µg of O2/hour). CONCLUSIONS: Ellagitannins have a capacity for oxygen consumption far greater than condensed tannins and especially than gallotannins. Consequently, ellagitannins are among the oenological tannins which are better able to protect the wine from oxidation.

REFERENCES: [1] Zamora F. (2003) Enólogos, 25, 26-30 [2] Versari, A., du Toit, W., Parpinello, G.P. (2013). Aust. J. Grape Wine Res., 19, 1-10. [3] Obreque-Slíer ; E., Peña-Neira, A., López-Solís , R., Ramírez-Escudero, C., Zamora, F. (2009) Eur Food Res Technol, 229, 859-866 [4] Magalhaes, L.M., Ramos, I.I., Reis, S., Segundo, M.A. (2014) Aust. J. Grape Wine Res., 20, 72-79. [5]Diéval, J.B., Vidal, S., Aagaard, O. (2011). Packag. Technol. Sci., 24, 375-385.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Fernando Zamora*, Esteban García-Romero, Isidro Hermosín-Gutíerrez, Joan Miquel Canals, Jordi Gombau, María Navarro, Olga Pascual, Sergio Gómez-Alonso

*Universitat Rovira i Virgili

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Moscatel vine-shoot extracts as grapevine biostimulant to increase the varietal aroma of Airén wines

There is a growing interest in the exploitation of vine-shoots waste, since they are often left or burned. Sánchez-Gómez et al. [1] have shown that vines-shoots aqueous extracts have significant contents of bioactive compounds, among which several polyphenols and volatiles are highlighted. Recent studied had demonstrated that the chemical composition of vine-shoots is enhanced when vine-shoots are toasted
[2,3]. The application of vegetable products in the vineyards has led to significant changes towards a more “Sustainable Viticulture”. An innovative foliar application for Airén vine-shoot extracts have been carried out to the vineyard. It has been shown that they act as grape biostimulants, improving certain wine quality characteristics [4].

The challenge of quality in sulphur dioxide free wines: natural polyphenol alternatives

Sulphur dioxide (SO2) seems indispensable in winemaking because of its properties. However, a current increasing concern about its allergies effects in food product has addressed the international research efforts on its replacement. This supposes a sufficient knowledge of its properties and conditions of use. Several studies compared SO2 properties against new alternatives that are supposed to overcome SO2 disadvantages. Firstly, the state of art on SO2 wine replacements is revised, and secondly, the last promising results using natural enriched polyphenol extracts are shown.

Sensory and nephelometric analysis of tannin fractions obtained by ultrafiltration of red wines

The assessment of red wine mouthfeel relies primarily on the sensory description of its tannic properties. This evaluation could be improved by gaining a better understanding of the physicochemical properties of these tannins. Hence, the objectives of the present study were threefold: (1) to gain an insight into the sensory properties of subpopulations of proanthocyanidic tannins of different molecular sizes obtained through several ultrafiltration steps, (2) to quantify the kinetics of haze formation of these proanthocyanidic tannins in a dynamic polyvinylpyrrolidone (PVP) precipitation test, (3) to determine whether a correlation exists between the sensory and the precipitation data.

Micro-meteorological, compositional and transcriptional study of corvina grape color during ripening

Grape anthocyanin content and composition could affect the quality and the production strategies of red wines. Differences in the pigment composition modify the color properties in terms of hue, extractability and stability. Thus, for the production of a highly qualitative wine such as “Amarone”, variations in the pigment composition are not negligible. The aim of this work was the investigation of the anthocyanin profile changes during ripening in Corvina grapes, the main cultivar for the “Amarone” production. The experiment took place in 2015, in two vineyards located in Valpollicella (Italy).

Mean polymerization degree of proanthocyanidins of grape seeds, skins and wines from Agiorgitiko (cv. Vitis vinifera): Differences among vintages

Grape phenolic compounds are very important constituents of red wine because, in addition to their antioxidant properties, they contribute to color, astringency and bitterness, oxidation reactions, interactions with proteins and ageing behavior of wines. The aim of our study was to assess the structural characteristics of grape and wine proanthocyanidins of Agiorgitiko variety and to evaluate the influence of the vintage year. Twelve vineyard locations were designated in the Nemea wine region. For three consecutive years (2012-2014), the grapes were harvested at technological maturity and the method of phloroglucinolysis was employed to determine the mean degree of polymerization (mDP) and subunit composition of the samples.