Lead levels in fortified wines

Abstract

AIM: The main lead exposure route is the intake of contaminated food, water, and alcoholic beverages, in particular wine. At the gastric level, Pb is transformed into a soluble compound which, when conveyed into the bloodstream, is the long-term cause of saturnism, intoxication with neurotoxic, nephrotoxic and hematopoietic effects, and with the neurological developmental delay of children. Pb is classified by the International Agency for Research on Cancer as a 2A class, possible carcinogenic to humans. In an opinion on possible health risks, CONTAM considered that cereals, vegetables, drinking water, and wine give a greater contribute to dietary exposure to Pb in Europe. Large quantities of wine, beer, and other alcoholic products drinking can increase daily Pb intake above the maximum permitted levels. The JECFA/WHO committee defined a Provisional Tolerable Weekly Intake (PTWI) for lead of 25 µg/kg body weight for all age groups. The presence of lead in grapes, wines and other alcoholic products has been reported for many years and is influenced by a series of factors that characterize wineries (country of origin, different climatic conditions, grape cultivars, soil composition, environmental industrial emissions of lead, historical and present, motor vehicle exhausts gases, metal-based fungicides and insecticides, fertilizers and winemaking processes, including cellar equipment). The aim of this work was to detect the Pb content in fortified wines from central Italy, in particular from Abruzzo.

METHODS: The analysis was performed in ICP-MS. The wine samples were diluted ten times with HNO3 (2%) and analyzed in triplicate. The external standard method and the calibration solutions prepared in 2% ethanol/2% HNO3 were used for the quantification of Pb. The data obtained was analyzed using the ICP-MS ChemStation.

RESULTS: The results of a study conducted on the trace elements presence, including Pb, in Italian fortified wines agree with the literature data relating to the Pb content, which is lower than the limit allowed by current legislation, with the exception of a sample relating to the “Vino cotto”, of artisanal production.

CONCLUSIONS:

These results can contribute to the formation of a database to protect the consumers health. The wines Pb content is established by the Commission regulation (EU) 2015/1005 of 25 June 2015 which defines the maximum admitted value at 0.15 mg/L. The International Organization of Vine and Wine (OIV) in 2020 reduced the limit to 0.10 mg/L for wines and 0.15 mg/L for fortified wines.

DOI:

Publication date: September 15, 2021

Issue: Macrowine 2021

Type: Article

Authors

Angelo Cichelli

Department of Medical, Oral and Biotechnological Sciences – DiSMOB. “G. D’Annunzio” University of Chieti-Pescara – Via dei Vestini, Chieti, Italy.,Laura CASORRI, Department of Technological Innovations and safety of plants, products and anthropic settlements (DIT) – National Institute for Insurance against Accidents at Work (INAIL). Rome, Italy.  Ada CONSALVO Center for Advances Studies and Technologies (CAST) University “G. d’Annunzio” of Chieti-Pescara, Italy.  Marco DI LUIGI, Department of Occupational and Environmental Medicine, Epidemiology and Hygiene – National Institute for Insurance against Accidents at Work (INAIL) – Research Centre Monte Porzio Catone – Rome, Italy.  Massimo DI MARTINO, Ispettorato Centrale della tutela della Qualita’ e della Repressione Frodi dei prodotti agroalimentari (ICQRF). Pescara, Italy.  Barbara FICOCIELLO, Department of Technological Innovations and safety of plants, products and anthropic settlements (DIT) – National Institute for Insurance against Accidents at Work (INAIL). Rome, Italy.  Eva MASCIARELLI, Department of Technological Innovations and safety of plants, products and anthropic settlements (DIT) – National Institute for Insurance against Accidents at Work (INAIL). Rome, Italy.

Contact the author

Keywords

lead, fortified wine, maximum value, oiv

Citation

Related articles…

Impact of climate change on the viticultural climate of the Protected Designation of Origin “Jumilla” (SE Spain)

Protected Designation of Origin “Jumilla” (PDO Jumilla) is located in the Spanish provinces of Albacete and Murcia, in the South-eastern part of the Iberian Peninsula, where most of the models predict a severe impact of climate change in next decades. PDO Jumilla covers an area of 247,054 hectares, of which more than 22,000 hectares

Local adaptation tools to ensure the viticultural sustainability in a changing climate

[lwp_divi_breadcrumbs home_text="IVES" use_before_icon="on" before_icon="||divi||400" module_id="publication-ariane" _builder_version="4.19.4" _module_preset="default" module_text_align="center" module_font_size="16px" text_orientation="center"...

Impact of climate variability and change on grape yield in Italy

Viticulture is entangled with weather and climate. Therefore, areas currently suitable for grape production can be challenged by climate change. Winegrowers in Italy already experiences the effect of climate change, especially in the form of warmer growing season, more frequent drought periods, and increased frequency of weather extremes.
The aim of this study is to investigate the impact of climate variability and change on grape yield in Italy to provide winegrowers the information needed to make their business more sustainable and resilient to climate change. We computed a specific range of bioclimatic indices, selected by the International Organisation of Vine and Wine (OIV), and correlated them to grape yield data. We have worked in collaboration with some wine consortiums in northern and central Italy, which provided grape yield data for our analysis.
Using climate variables from the E-OBS dataset we investigate how the bioclimatic indices changed in the past, and the impact of this change on grape productivity in the study areas. The climate impact on productivity is also investigated by using high-resolution convection-permitting models (CPMs – 2.2 horizontal resolution), with the purpose of estimating productivity in future emission scenarios. The CPMs are likely the best available option for this kind of impact studies since they allow a better representation of small-scale processes and features, explicitly resolve deep convection, and show an improved representation of extremes. In our study, we also compare CPMs with regional climate models (RCMs – 12 km horizontal resolution) to assess the added value of high-resolution models for impact studies. Further development of our study will lead to assessing the future suitability for vine cultivation and could lead to the construction of a statistical model for future projection of grape yield.

Second pruning as a strategy to delay maturation in cv. ‘Touriga nacional’ in the Portuguese Douro region

The advance in maturation of wine grapes is an important climate change risk related effect that could affect warm regions like Portuguese Douro Wine Region. Indeed, the climate analysis over the past years registered a decrease in the precipitation, significant higher average temperatures, and a more frequent occurrence of extreme weather events, including heat waves. In these conditions the length from anthesis until maturation is shortened and the uncoupling of technical and phenolic maturity results in berries with higher sugar concentration (and lower acidity), but lower anthocyanins, tannins, and total phenolic concentration, which produce unbalanced wines.
In this work, an innovative strategy of crop forcing, based on forcing vine regrowth after a second pruning of green shoots, was tested, aimed at delaying ripening until the temperature becomes lower and, therefore, preventing acidity loss and increasing anthocyanin-to-sugar ratio. The experiments were conducted in 2019 and 2020 in a commercial vineyard of ‘Touriga Nacional’ located in the Douro Region. Crop forcing was conducted 15 (CF1) to 30 (CF2) days after fruit set. Vines pruned with conventional methods were used as control (CF0). Results confirmed that fruit ripening was shifted from the hot season (August/September), until a cooler period (October through early-November). At harvest, grapevine berries from CF1 and CF2 presented lower pH and higher acidity, than control, with no significant differences in colour intensity and phenolic levels composition. Sugar content was lower in CF2-treated vines in both seasons. However, in CF-treated vines the number and size of clusters were significantly lower (up to 88% reduction) than in control plants. A metabolomics analysis of mature berries from CF-treated vines and control is underway. Crop forcing was indeed effective in producing a more balance berry composition but severely reduced grapevine yield,

Postveraison shoot trimming in Tannat and Merlot: preliminary results on yield components, plant balance and berry composition

There is currently a trend towards the production of wines with low alcohol content. To achieve this, grapes with low sugar content must be used. There are techniques at the vineyard level that can delay ripening and avoid excessive sugar accumulation without, a priori, affecting the final polyphenol content. Postveraison shoot trimming (PVST) is experimentally evaluated for these purposes, but its impact under Uruguayan climatic conditions with high interannual variability is not known. The aim of this work is to assess the PVST in Tannat and Merlot cultivars and their impact on yield components, plant balance and berry primary composition. In this study, two commercial vineyards of 10 years old Tannat and Merlot (grafted on SO4) at Canelones Department were selected. During the 2020-201 growing season, grapevines were submitted to PVST when grapes reached 15º Brix. In a randomized block, trimmed (T) and control (C) plants were evaluated with three repetitions each cultivar. Evaluation of the evolution of primary berry composition during ripening, measurement of yield components and plant balance were performed. For both cultivars, PVST did not affect yield components. Merlot reached 5.4 kg per plant and Tannat 7.1 kg, with not statistical significance between treatments. However, statistical differences were observed in terms of plant balance. In Merlot Ravaz Index reached a difference of 5.3 (12.0 in T and 6.7 in C) meanwhile Tannat reached 3.5 of statistical difference (13.7 in T and 10.2 in C). The tendency to imbalance for the treated plants had an impact on the final grape composition. Merlot grapes showed statistical difference in final total acidity (0.3 g of difference between treatments) while treatments impact final sugar content on Tannat grapes (10.0 g of difference between treatments). Further studies are needed to assess the impact of different canopy management techniques in our conditions.