Lead levels in fortified wines

Abstract

AIM: The main lead exposure route is the intake of contaminated food, water, and alcoholic beverages, in particular wine. At the gastric level, Pb is transformed into a soluble compound which, when conveyed into the bloodstream, is the long-term cause of saturnism, intoxication with neurotoxic, nephrotoxic and hematopoietic effects, and with the neurological developmental delay of children. Pb is classified by the International Agency for Research on Cancer as a 2A class, possible carcinogenic to humans. In an opinion on possible health risks, CONTAM considered that cereals, vegetables, drinking water, and wine give a greater contribute to dietary exposure to Pb in Europe. Large quantities of wine, beer, and other alcoholic products drinking can increase daily Pb intake above the maximum permitted levels. The JECFA/WHO committee defined a Provisional Tolerable Weekly Intake (PTWI) for lead of 25 µg/kg body weight for all age groups. The presence of lead in grapes, wines and other alcoholic products has been reported for many years and is influenced by a series of factors that characterize wineries (country of origin, different climatic conditions, grape cultivars, soil composition, environmental industrial emissions of lead, historical and present, motor vehicle exhausts gases, metal-based fungicides and insecticides, fertilizers and winemaking processes, including cellar equipment). The aim of this work was to detect the Pb content in fortified wines from central Italy, in particular from Abruzzo.

METHODS: The analysis was performed in ICP-MS. The wine samples were diluted ten times with HNO3 (2%) and analyzed in triplicate. The external standard method and the calibration solutions prepared in 2% ethanol/2% HNO3 were used for the quantification of Pb. The data obtained was analyzed using the ICP-MS ChemStation.

RESULTS: The results of a study conducted on the trace elements presence, including Pb, in Italian fortified wines agree with the literature data relating to the Pb content, which is lower than the limit allowed by current legislation, with the exception of a sample relating to the “Vino cotto”, of artisanal production.

CONCLUSIONS:

These results can contribute to the formation of a database to protect the consumers health. The wines Pb content is established by the Commission regulation (EU) 2015/1005 of 25 June 2015 which defines the maximum admitted value at 0.15 mg/L. The International Organization of Vine and Wine (OIV) in 2020 reduced the limit to 0.10 mg/L for wines and 0.15 mg/L for fortified wines.

DOI:

Publication date: September 15, 2021

Issue: Macrowine 2021

Type: Article

Authors

Angelo Cichelli

Department of Medical, Oral and Biotechnological Sciences – DiSMOB. “G. D’Annunzio” University of Chieti-Pescara – Via dei Vestini, Chieti, Italy.,Laura CASORRI, Department of Technological Innovations and safety of plants, products and anthropic settlements (DIT) – National Institute for Insurance against Accidents at Work (INAIL). Rome, Italy.  Ada CONSALVO Center for Advances Studies and Technologies (CAST) University “G. d’Annunzio” of Chieti-Pescara, Italy.  Marco DI LUIGI, Department of Occupational and Environmental Medicine, Epidemiology and Hygiene – National Institute for Insurance against Accidents at Work (INAIL) – Research Centre Monte Porzio Catone – Rome, Italy.  Massimo DI MARTINO, Ispettorato Centrale della tutela della Qualita’ e della Repressione Frodi dei prodotti agroalimentari (ICQRF). Pescara, Italy.  Barbara FICOCIELLO, Department of Technological Innovations and safety of plants, products and anthropic settlements (DIT) – National Institute for Insurance against Accidents at Work (INAIL). Rome, Italy.  Eva MASCIARELLI, Department of Technological Innovations and safety of plants, products and anthropic settlements (DIT) – National Institute for Insurance against Accidents at Work (INAIL). Rome, Italy.

Contact the author

Keywords

lead, fortified wine, maximum value, oiv

Citation

Related articles…

Organic recycled mulches in sustainable viticulture: assessment of spontaneous plants communities and weed coverage

In recent years, developing more efficient and sustainable viticulture management has been essential due to the impact of climate change in semiarid regions. For this reason, the use of recycled organic mulching (ROM) in the vineyard has become an interesting strategy to cope with water stress, isolated soil from extreme temperatures and improving soil humidity, control the presence of weeds and therefore reduce the inputs of herbicides and improve soil fertility. This work aimed to analyse the effect of three different organic mulches [straw (S), grape pruning debris (GPD) and spent mushroom compost (SMC)] and two traditional soil management techniques [herbicide (H) and interrow (IN)] on weed coverage and the spontaneous plant communities’ presence. Data sampling was collected throughout the vine vegetative cycle of 2021 in La Rioja, Spain. The different soil management techniques had a clear effect on weed coverage and his development during the vine vegetative cycle. SMC and H were the treatments with the highest and the lowest coverage percentage, respectively. IN had a delayed weed emergence at the beginning of the vine vegetative cycle, but finally it reached maximum values nearby SMC. GPD and S had similar effects on weed emergence, reaching 25-30% of the maximum coverage values. A total of 29 herbaceous species were identified during the vegetative cycle, some of them very isolated and occasional. Principal component analysis (PCAs) showed a good association between spontaneous species and treatments, furthermore, specific species-treatment associations were found. Moreover, three clear groups of herbaceous communities were identified by cluster analysis. This study provides interesting information about the effect of different alternative soil management on herbaceous plant coverage and weed species communities which could contribute to making more sustainable viticulture.

Extreme canopy management for vineyard adaptation to climate change: is it a good idea?

Climate change constitutes an enormous challenge for humankind and for all human activities, viticulture not being an exception. Long-term strategic changes are probably needed the most, but growers also need to deal with short-term changes: summers that are getting progressively warmer, earlier harvest dates and higher pH in musts and wines. In the last 10-15 years, a relevant corpus of research is being developed worldwide in order to evaluate to which extent extreme canopy management operations, aimed at reducing leaf area and, thus, limiting the source to sink ratio, could be useful to delay ripening. Although extreme canopy management can result in relevant delays in harvest dates, longer term studies, as well as detailed analysis of their implications on carbohydrate reserves, bud fertility and future yield are desirable before these practices can be recommended.

Local adaptation tools to ensure the viticultural sustainability in a changing climate

[lwp_divi_breadcrumbs home_text="IVES" use_before_icon="on" before_icon="||divi||400" module_id="publication-ariane" _builder_version="4.19.4" _module_preset="default" module_text_align="center" module_font_size="16px" text_orientation="center"...

δ13C : A still underused indicator in precision viticulture  

The first demonstration of the interest of carbon isotope composition of sugars in grapevine, as an integrated indicator of vineyard water status, dates back to 2000 (Gaudillère et al., 1999; Van Leeuwen et al., 2001). Thanks to the isotopic discrimination of Carbon that takes place during plant photosynthesis, under hydric stress conditions, it is possible to accurately estimate the photosynthetic activity. Ever since, δ13C has been widely applied with success to zonation, terroir studies and vine physiology research, but is still not widely used by viticulturists. This is quite astonishing by considering the impact of global warming on viticulture and the need to improve water management, that would justify a widespread use of δ13C.
The lack of private laboratories proposing the analysis, the cost of the technology, as well as the long analytical delays, have been detrimental to its development. Some laboratories tried to overcome the analytical difficulties of isotopic analysis by using fourier transformed infrared spectroscopy, as a fast and cheap alternative to the official OIV method (IRMS). These claimed FTIR models have never been published or peer reviewed and cannot be considered robust. In this work, thanks to the recent acquisition of IRMS technology, new modern and robust applications of δ13C for viticulture are proposed. This includes the use of the analysis to make parcel separations at harvesting, the possibility to increase the precision of hydric stress cartography and the potential cost reduction when compared with Scholander pressure bomb analysis.

Elevational range shifts of mountain vineyards: Recent dynamics in response to a warming climate

Increasing temperatures worldwide are expected to cause a change in spatial distribution of plant species along elevational gradients and there are already observable shifts to higher elevations as a consequence of climate change for many species. Not only naturally growing plants, but also agricultural cultivations are subject to the effects of climate change, as the type of cultivation and the economic viability depends largely on the prevailing climatic conditions. A shift to higher elevations therefore represents a viable adaptation strategy to climate change, as higher elevations are characterized by lower temperatures. This is especially important in the case of viticulture because a certain wine-style can only be achieved under very specific climatic conditions. Although there are several studies investigating climatic suitability within winegrowing regions or longitudinal shifts of winegrowing areas, little is known about how fast vineyards move to higher elevations, which may represent a viable strategy for winegrowers to maintain growing conditions and thus wine-style, despite the effects of climate change. We therefore investigated the change in the spatial distribution of vineyards along an elevational gradient over the past 20 years in the mountainous wine-growing region of Alto Adige (Italy). A dataset containing information about location and planting year of more than 26000 vineyard parcels and 30 varieties was used to perform this analysis. Preliminary results suggest that there has been a shift to higher elevations for vineyards in general (from formerly 700m to currently 850 m a.s.l., with extreme sites reaching 1200 m a.s.l.), but also that this development has not been uniform across different varieties and products (i.e. vitis vinifera vs hybrid varieties and still vssparkling wines). This is important for climate change adaptation as well as for rural development. Mountain areas, especially at mid to high elevations, are often characterized by severe land abandonment which can be avoided to some degree if economically viable and sustainable land management strategies are available.