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IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Hydroxycinnamic acids in grapes and wines made of Tannat, Marselan and Syrah from Uruguay

Hydroxycinnamic acids in grapes and wines made of Tannat, Marselan and Syrah from Uruguay

Abstract

Background: Hydroxycinnamic acids (HCA), present in pulp and skin of grapes, are relevant compounds in red winemaking. They catalyze oxidation reaction, but also participate in the formation of pyranoanthocyanins, thus contributing to the red-wine color stabilization. Aim: the current investigation aimed to study the HCA content and profile in Tannat, Marselan and Syrah Vitis vinifera grapes harvested at different maturation degrees and in the respective wines. A further aim was to study the evolution of these compounds in wine during bottle storage. Material and methods: two vintages were considered, 2015 and 2016. Two harvest dates around technological maturity were evaluated on each grape-cultivar. Winemaking (involving 70kg of grapes each) were made in duplicate by traditional maceration. Skin samples were taken before each vinification, freezed dried, and extracted with a mixture 50:48.5:1.5 of CH3OH/H2O/HCOOH. Hydroxycinnamic acids in skin and in the wines were isolated using SPE PCX cartridges, and injected into an HPLC-ESI-IonTrap-MS/MS system equipped with a C18 column. Wines were analyzed 3 months after winemaking, and during wine storage, up to 24 months after the first analytical determinations. trans-caftaric acid, cis and trans-coutaric acid, trans-fertaric acid, the correspondent free HCA and glucosides of these compounds were identified and quantified. Results: In the skin, caffeic acid-based HCA (Caff.) were the main HCA found (between 60% and 81%). The p-coumaric based HCA (p-coum.) represented the second most important cinnamic acids in 2015 (between 14%-37%) while proportion of Ferulic HCA based compounds (Fer.) represented between 2% and 5%. In 2016, Tannat and Syrah, had a much lower proportion of p-coum. (as low as 5% and 13% respectively), and a much higher proportion of Fer. (21% and 24% respectively), thus, the HCA skin profile could change among vintages. Skin HCA profile also changed among cultivars. Tannat had the highest proportion of Caff. which were much lower in Marselan and particularly in Syrah, and the lowest proportion in p-coum, which reached the highest values in Syrah. Grape ripeness did not modify the skin HCA profile in Syrah and Marselan, but riper grapes of Tannat had higher proportions of p-coum. (increased from 14 to 18%) and lower of Fer. (from 5% to 2%). In wines, Syrah had lower HCA contents (127 mg/l-152 mg/l) than Marselan (252 mg/l-317 mg/l) and Tannat (178 mg/l -328 mg/l). The wines made from the riper grapes had higher HCA contents in Tannat and Syrah, while lower in Marselan. In the 3-month wines, the main HCA was Caff. (more than 70% in all cases), followed by p-coum. (15% in average) and Fer. (between 4%-5%). Syrah wines had lower proportion of Caff. and higher of p-coum. than Marselan and Tannat. During wine storage, p-coum. proportion increased while that of Fer. and particularly Caff. decreased denoting the higher reactivity of the later, consistent with its molecular structure.

DOI:

Publication date: June 24, 2022

Issue: IVAS 2022

Type: Poster

Authors

Favre Guzmán1, Gómez-Alonso Sergio2, Pérez-Navarro José2, Piccardo Diego1 and González-Neves Gustavo1

1Facultad de Agronomía, Universidad de la República (Udelar)
2Instituto Regional de Investigación Científica Aplicada (IRICA), Universidad de Castilla-La Mancha

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Hydroxycinnamic acids, Tannat, Marselan, Syrah

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IVAS 2022 | IVES Conference Series

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Grapevine varietal diversity as mitigation tool for climate change: Agronomic and oenologic potential of 14 foreign varieties grown in Languedoc region (France)

Climate change effects in Languedoc include an expected rise in temperatures, increased evapotranspiration as well as more severe and frequent climatic hazards, such as frost, drought periods and heat waves. For winegrowers theses phenomena impact both yield and quality, resulting in more frequent unbalanced wines. Research on identified mitigation tools for vineyard management is necessary to improve resilience of grapevine agrosystems. Varietal assortment is one of them. This study focuses on agronomic and oenologic potential of 14 foreign varieties grown in Languedoc French region. Fourteen grapevine varieties were monitored during 2021 from June until harvest on eight different sites, some of which occurring on more than one site adding up to 21 different modalities: 7 white varieties Alvarinho B, Assyrtiko B (2), Malvasia Istriana B, Parellada B, Verdejo B, Verdelho B, Xarello B, and 7 black varieties Saperavi N (2), Touriga nacional N, Baga N, Aleatico N, Montepulciano N (2), Primitivo N (3), Calabrese N (3). Varietals were compared through the following parameters: phenology was assessed by using the information collected in the Database Network of French Vine Conservatories (INRAE-SupAgro-IFV, 2005-2015). The number of inflorescences for shoots from secondary buds and bourillons and suckers were observed to assess post-bud break frost tolerance potential. Grapevine water status was studied through stem water potential measurement, observation of foliage symptoms of drought, and 𝛿13C on must. Frequencies and intensities of downy mildew, powdery mildew, and black rot attacks were estimated before harvest on leaves and clusters and botrytis at harvest to assess disease susceptibilities. Berry composition was monitored from end of veraison until harvest. Yield and mean bunch weight were also calculated. Varieties were then ranked on a 1-4 scale for each parameter and compared through PCA. Forty two stations of the Mediterranean basin were compared by PCA with the Multicriteria Climatic Classification indicators in order to confront the collected information during 2021 campaign to the hypothesis that plants coming from dry and hot regions are genetically adapted to such climatic conditions.

Underpinning terroir with data: rethinking the zoning paradigm

Agriculture, natural resource management and the production and sale of products such as wine are increasingly data-driven activities. Thus, the use of remote and proximal crop and soil sensors to aid management decisions is becoming commonplace and ‘Agtech’ is proliferating commercially; mapping, underpinned by geographical information systems and complex methods of spatial analysis, is widely used. Likewise, the chemical and sensory analysis of wines draws on multivariate statistics; the efficient winery intake of grapes, subsequent production of wines and their delivery to markets relies on logistics; whilst the sales and marketing of wines is increasingly driven by artificial intelligence linked to the recorded purchasing behaviour of consumers. In brief, there is data everywhere!

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IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Hydroxycinnamic acids in grapes and wines made of Tannat, Marselan and Syrah from Uruguay

Hydroxycinnamic acids in grapes and wines made of Tannat, Marselan and Syrah from Uruguay

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Publication date: June 24, 2022

Issue: IVAS 2022

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The aim of this study was to explore the effects of different soil characteristics combined with several deficit irrigation strategies, managed throughout ETc references and predawn leaf water potentials thresholds, on physiology, yield, and qualitative attributes on the Touriga Nacional variety under years of mild to severe water and heat stress.
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